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1. 发明授权

US5605680A Photostable cosmetic composition containing a UV-A screen and a UV-B screen and a process for stabilizing the UV-A screen with the UV-B screen 失效
标题翻译：含有UV-A屏幕和UV-B屏幕的光稳定化妆品组合物和用UV-B屏幕稳定UV-A屏幕的方法
公开(公告)号：US5605680A
公开(公告)日：1997-02-25
申请号：US487484
申请日：1995-06-07
申请人： Andre Deflandre , Serge Forestier , Gerard Lang , Jean F. Grollier , Jean Cotteret
发明人： Andre Deflandre , Serge Forestier , Gerard Lang , Jean F. Grollier , Jean Cotteret
IPC分类号： A61K8/00 , A61K20060101 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/37 , A61K8/92 , A61K9/02 , A61K9/06 , A61K9/08 , A61K9/10 , A61K9/107 , A61K9/12 , A61Q17/04 , C07C45/86 , C07C49/683 , C07C49/84 , A61K7/42
CPC分类号： A61K8/35 , A61Q17/04 , A61K2800/52 , A61K2800/59
摘要： The invention relates to a photostable screening cosmetic composition for protecting human skin against UV rays, comprising, in a cosmetically acceptable substrate containing at least one fatty phase, 1 to 3% by weight of 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane and at least 4.5% by weight of p-methylbenzylidenecamphor, the weight ratio of p-methylbenzylidenecamphor to 4-(1,1-dimethyl-ethyl)-4'-methoxydibenzoylmethane being higher than or equal to 3.It also relates to a process for protecting the skin against UV radiation and to a process for stabilizing 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane against UV radiation.
摘要翻译：本发明涉及一种用于保护人体皮肤免受紫外线影响的光稳定屏蔽化妆品组合物，其包含在含有至少一种脂肪相的化妆品可接受的底物中，1-3重量％的4-（1,1-二甲基乙基）-4' - 甲氧基二苯甲酰甲烷和至少4.5重量％的对甲基亚苄基樟脑，对甲基亚苄基樟脑与4-（1,1-二甲基 - 乙基）-4'-甲氧基二苯甲酰甲烷的重量比高于或等于3.还涉及用于保护皮肤免受紫外线辐射的方法和用于稳定4-（1,1-二甲基乙基）-4'-甲氧基二苯甲酰甲烷以抵抗UV辐射的方法。

2. 发明授权

US4668505A Sunscreen method containing polyisobutylene for the protection of human epidermis against ultraviolet radiations 失效
标题翻译：含有聚异丁烯以防止人体表皮紫外线照射的防晒方法
公开(公告)号：US4668505A
公开(公告)日：1987-05-26
申请号：US721673
申请日：1985-04-10
申请人： Jean F. Grollier , Jean Cotteret
发明人： Jean F. Grollier , Jean Cotteret
IPC分类号： C09K3/00 , A61K20060101 , A61K8/00 , A61K8/31 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/37 , A61K8/39 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/81 , A61K8/92 , A61K8/97 , A61K8/98 , A61K9/12 , A61K31/12 , A61Q17/04 , A61K7/42 , A61K7/44
CPC分类号： A61K8/8111 , A61K8/466 , A61Q17/04 , Y10S424/05 , Y10S514/844 , Y10S514/937 , Y10S514/938 , Y10S514/944 , Y10S514/947
摘要： The present invention relates to a sunscreen composition containing at least one oil-soluble agent absorbing UV rays as well as at least one polyisobutylene which is liquid at ambient temperature, with a viscosity-average molecular weight of between 8,000 and 65,000, in a cosmetically acceptable medium incorporating at least one fatty phase.Such a suncreen composition, applied on the skin, has an improved protection index.
摘要翻译：本发明涉及一种防晒组合物，其含有至少一种吸收紫外线的油溶性剂以及在环境温度下为液体的至少一种聚异丁烯，其粘均分子量在8,000至65,000之间，在化妆品上可接受至少含有一个脂肪相的培养基。施用在皮肤上的这种遮光组合物具有改进的保护指数。

3. 发明授权

US5180399A Process for dyeing keratinous fibres with oxidation bases combined with an iodide and dyeing composition employed 失效
标题翻译：用氧化碱与碘化物和染色组合物结合染色角质纤维的方法
公开(公告)号：US5180399A
公开(公告)日：1993-01-19
申请号：US717253
申请日：1991-06-18
申请人： Jean F. Grollier , Jean Cotteret , Didier Garoche
发明人： Jean F. Grollier , Jean Cotteret , Didier Garoche
IPC分类号： A61K8/20 , A61K8/41 , A61K8/49 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/20 , A61K8/411 , A61K8/415 , A61K8/492 , A61K8/4926
摘要： A process for dyeing keratinous fibers employs a dye composition containing an oxidation base selected from a paraphenylenediamine, an N,N'-diphenylalkylene diamine, a para-aminophenol, an ortho-aminophenol, an ortho-phenylenediamine or a heterocyclic oxidation base, in combination with iodide ions. The application of this dyeing composition to the keratinous fibers is preceded or followed by the application to the fibers of a composition containing hydrogen peroxide.
摘要翻译：用于染色角质纤维的方法使用含有选自对苯二胺，N，N'-二苯基亚烷基二胺，对氨基苯酚，邻氨基苯酚，邻苯二胺或杂环氧化碱的氧化碱的组合物的染料组合物与碘离子。这种染色组合物在角质纤维中的应用在含有过氧化氢的组合物的纤维之前或之后。

4. 发明授权

US5032382A Light-stable screening cosmetic composition containing bixin combined with a lipid-soluble UV filter and its use for protecting the human epidermis against ultra-violet radiation 失效
标题翻译：含有bixin与脂溶性紫外线过滤器结合的轻稳定筛选化妆品组合物及其用于保护人体表皮免受紫外线辐射的作用
公开(公告)号：US5032382A
公开(公告)日：1991-07-16
申请号：US244746
申请日：1988-09-14
申请人： Jean F. Grollier , Jean Cotteret , Georges Rosenbaum
发明人： Jean F. Grollier , Jean Cotteret , Georges Rosenbaum
IPC分类号： A61K8/00 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/37 , A61K8/92 , A61K8/97 , A61K36/736 , A61Q17/04
CPC分类号： A61K8/37 , A61K8/35 , A61K8/922 , A61K8/97 , A61Q17/04 , Y10S424/05 , Y10S514/847 , Y10S514/873 , Y10S514/937 , Y10S514/938
摘要： The invention relates to a light-stable cosmetic composition for protecting the human epidermis against UV radiation, containing at least 0.0025% by weight of bixin combined with at least 1% by weight of one or more lipid-soluble agents screening UV radiation, chosen from 3-benzylidene-dl-camphor, its derivatives and benzophenone derivatives, in a cosmetically acceptable vehicle comprising at least one fatty phase.The bixin takes the form of an oily extract of annatto containing at least 0.1% by weight of bixin.
摘要翻译：本发明涉及一种用于保护人类表皮免受紫外线辐射的光稳定化妆品组合物，其含有至少0.0025％（重量）的二辛基与至少1％（重量）的一种或多种筛选紫外线辐射的脂溶性试剂， 3-亚苄基-d1-樟脑，其衍生物和二苯甲酮衍生物，在包含至少一种脂肪相的化妆品可接受的载体中。 bixin采取含有至少0.1％（重量）bixin的胭脂红油状提取物的形式。

5. 发明授权

US5000937A Transparent cosmetic composition that reflects infrared radiation and its use for protecting the human epidermis against infrared radiation 失效
标题翻译：反射红外辐射的透明化妆品组合物及其用于保护人体表皮免受红外辐射的用途
公开(公告)号：US5000937A
公开(公告)日：1991-03-19
申请号：US263423
申请日：1988-10-27
申请人： Jean F. Grollier , Georges Rosenbaum , Jean Cotteret
发明人： Jean F. Grollier , Georges Rosenbaum , Jean Cotteret
IPC分类号： A61K8/02 , A61K20060101 , A61K8/00 , A61K8/04 , A61K8/19 , A61K8/29 , A61K8/30 , A61K8/31 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/368 , A61K8/37 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61K8/92 , A61K9/12 , A61Q1/02 , A61Q17/04
CPC分类号： A61Q17/04 , A61K8/0254 , A61K8/044 , A61K8/29 , A61K8/31 , A61K2800/262 , A61K2800/412 , Y10S424/05 , Y10S514/844 , Y10S514/847 , Y10S514/937 , Y10S514/944 , Y10S514/969
摘要： Transparent cosmetic composition that reflects infrared radiation and its use for protecting the human epidermis against infrared radiation.The invention relates to a transparent cosmetic composition comprising, by way of an agent that reflects infrared radiation for protecting the human epidermis, a substance which is dispersible in the cosmetic medium used, possessing a reflectance (R) of infrared radiation equal to at least 45%, and of which a 2% strength dispersion in vaseline possesses an optical transmission in the visible of at least 85%, chosen from a diatom of particle size less than 100 microns, hollow glass microspheres of size less than 100 microns, a bismuth oxychloride of particle size less than 75 microns and zirconium powder covered ceramic microparticles of particle size less than 8 microns.This cosmetic composition can also contain 0.5 to 20% by weight of UV-A, UV-B or broad-band screening agents.
摘要翻译：反射红外辐射的透明化妆品组合物及其用于保护人体表皮免受红外辐射的用途。本发明涉及一种透明化妆品组合物，其包含通过反射用于保护人表皮的红外辐射的试剂，所述物质可分散在所使用的化妆品介质中，具有等于至少45的红外辐射的反射率（R）％，其中凡士林的2％强度分散体具有至少85％的可见光透射率，选自粒度小于100微米的硅藻，尺寸小于100微米的中空玻璃微球，氯氧化铋粒径小于75微米的锆粉末覆盖的陶瓷微粒，粒度小于8微米。该化妆品组合物还可以含有0.5-20重量％的UV-A，UV-B或宽带筛选剂。

6. 发明授权

US4875902A Alkyl derivatives of hydroquinone as antioxidants in oxidation dyeing compositions 失效
标题翻译：在氧化染色组合物中作为抗氧化剂的氢醌的烷基衍生物
公开(公告)号：US4875902A
公开(公告)日：1989-10-24
申请号：US110107
申请日：1987-10-16
申请人： Jean F. Grollier , Jean Cotteret
发明人： Jean F. Grollier , Jean Cotteret
IPC分类号： A61K8/00 , A61K8/23 , A61K8/33 , A61K8/41 , A61K8/49 , A61Q5/10 , C09K15/08 , D06P1/32 , D06P1/651
CPC分类号： A61Q5/10 , A61K8/347 , C09K15/08 , A61K2800/522
摘要： The invention relates to the use of a compound of the formula: ##STR1## in which R denotes an alkyl radical having 1 to 4 carbon atoms, as an antioxidant in oxidation dyeing compositions.
摘要翻译：本发明涉及在氧化染色组合物中作为抗氧化剂使用下式化合物：其中R表示具有1至4个碳原子的烷基。

7. 发明授权

US4602913A Use of hydroxyanthraquinones for the coloration of human keratin fibres 失效
标题翻译：使用羟基蒽醌来染色人角蛋白纤维
公开(公告)号：US4602913A
公开(公告)日：1986-07-29
申请号：US630681
申请日：1984-07-13
申请人： Jean F. Grollier , Georges Rosenbaum , Jean Cotteret
发明人： Jean F. Grollier , Georges Rosenbaum , Jean Cotteret
IPC分类号： A61K8/00 , A61K20060101 , A61K8/35 , A61K8/40 , A61K8/46 , A61K8/60 , A61K8/73 , A61K8/97 , A61Q5/10 , C07C50/18 , C09B20060101 , C09B1/02 , C09B1/08 , C09B1/10 , C09B1/12 , C09B1/14 , A61K7/13
CPC分类号： A61Q5/065 , A61K8/355
摘要： Use of hydroxyanthraquinones for the coloration of human keratin fibres, and process and composition in which they are used.The composition contains, in a cosmetically acceptable medium, at least one hydroxyanthraquinone of the formula: ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 independently of one another denote a hydrogen atom, a hydroxyl group, an alkyl group, an alkyl group substituted, for example, by a hydroxyl, amino or acyl group, an alkoxy group, a nitro group, a halogen group, a group SO.sub.3 H, CHO, CO.sub.2 H or SO.sub.3 Na, or a group --CO.sub.2 R', in which R' denotes alkyl or an alkali metal, with the proviso that: at least two of the groups R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 denote hydroxyl, and that if R.sub.1 and R.sub.2 denote OH, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 denoting hydrogen, then at least one of the two groups R.sub.3 and R.sub.4 is different from hydrogen, or alternatively if R.sub.1 and R.sub.3 denote OH, R.sub.2 and R.sub.4 denoting hydrogen and one or two of the substituents R.sub.5, R.sub.6, R.sub.7 and R.sub.8 denoting hydroxyl, then at least one of the substituents R.sub.5, R.sub.6, R.sub.7 and R.sub.8 is different from hydrogen, alkyl or halogen.
摘要翻译：使用羟基蒽醌来染色人角蛋白纤维，以及使用它们的方法和组成。所述组合物在化妆品可接受的介质中含有至少一种下式的羟基蒽醌：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8彼此独立地表示氢原子，羟基烷基，被羟基，氨基或酰基取代的烷基，烷氧基，硝基，卤素基，SO 3 H，CHO，CO 2 H或SO 3 Na或基团-CO 2 R' ，其中R'表示烷基或碱金属，条件是：R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8中的至少两个表示羟基，并且如果R 1和R 2表示OH， R 5，R 6，R 7和R 8表示氢，则两个基团R 3和R 4中的至少一个不同于氢，或者如果R 1和R 3表示OH，则R 2和R 4表示氢和一个或两个取代基R 5，R 6 ，R7和R8表示羟基，则至少一个取代基R5，R6，R7和R8不同于氢，烷基或卤素。

8. 发明授权

US4391603A Hydroxyl derivatives of benzaldehyde for coloring keratin fibres in the absence of oxidizing agent 失效
标题翻译：在不存在氧化剂的情况下着色角蛋白纤维的苯甲醛的羟基衍生物
公开(公告)号：US4391603A
公开(公告)日：1983-07-05
申请号：US254514
申请日：1981-04-15
申请人： Georges Rosenbaum , Jean F. Grollier , Jean Cotteret
发明人： Georges Rosenbaum , Jean F. Grollier , Jean Cotteret
IPC分类号： A61K8/00 , A61K8/33 , A61K8/34 , A61Q5/02 , A61Q5/06 , A61Q5/10 , C07C47/56 , C09B69/10 , D06P3/04 , D06P3/14 , D06P3/30 , A61K7/13
CPC分类号： A61K8/347 , A61Q5/065 , D06P3/305
摘要： The invention discloses the use of hydroxyl derivatives of benzaldehyde for coloring keratin fibres without an oxidizing agent. These derivatives are of the type which correspond to the formula: ##STR1## in which R denotes a linear or branched lower alkyl group which is optionally substituted by one or two OH groups, n is equal to 1, 2 or 3, m is equal to 0, 1 or 2 and the sum n+m is equal to 2 or 3.
摘要翻译：本发明公开了苯甲醛的羟基衍生物在没有氧化剂的情况下着色角蛋白纤维的用途。这些衍生物类型对应于下式：其中R表示任选被一个或两个OH基取代的直链或支链低级烷基，n等于1,2或3，m相等到0，1或2，并且和n + m等于2或3。

9. 发明授权

US5478360A Process for preserving the dyeing capacity of 5, 6-dihydroxyindole and of its derivatives in an aqueous medium, composition and dyeing process 失效
标题翻译：维持水性介质中5,6,6-二羟基吲哚及其衍生物的染色能力的方法，组合物和染色方法
公开(公告)号：US5478360A
公开(公告)日：1995-12-26
申请号：US390742
申请日：1995-02-17
申请人： Jean F. Grollier , Marie F. Bosq , Jean Cotteret , Arnaud De Labbey
发明人： Jean F. Grollier , Marie F. Bosq , Jean Cotteret , Arnaud De Labbey
IPC分类号： C07D209/08 , A61K8/00 , A61K8/24 , A61K8/34 , A61K8/36 , A61K8/365 , A61K8/37 , A61K8/41 , A61K8/49 , A61Q5/10 , C09B67/42 , D06P3/04 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/492 , D06P3/08
摘要： Process for preserving the dyeing capacity of 5,6-dihydroxyindole or of its derivatives corresponding to the formula (I): ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which are identical or different, denote hydrogen or a C.sub.1 -C.sub.4 lower alkyl, R.sub.1, R.sub.2 and R.sub.3 denoting hydrogen when R.sub.4 denotes alkyl in an aqueous medium, characterized in that the pH of the aqueous medium is adjusted to a value pH.sub.C of between 5 and 10 by employing a pH-regulating agent containing two components (A) and (B), the component (A) being chosen from pH-regulating agents which have a dissociation constant K.sub.CA in aqueous solution at 25.degree. C., such as pk.sub.CA, that is:0
摘要翻译：保护对应于式（I）的5,6-二羟基吲哚或其衍生物的染色能力的方法：其中相同或不同的R 1，R 2，R 3和R 4表示氢或当R 4表示在水性介质中的烷基时，表示氢的C1-C4低级烷基，R1，R2和R3表示氢，其特征在于通过使用包含以下组分的pH调节剂将含水介质的pH调节至5至10的pH值组分（A）和（B），组分（A）选自pH调节剂，其在25℃的水溶液中具有解离常数KCA，例如pkCA，即：0

10. 发明授权

US5135544A Process for dyeing keratinous fibres based on monohydroxyindole and 5,6-disubstituted hydroxyindole and composition employed 失效
标题翻译：基于单羟基吲哚和5,6-取代的羟基吲哚的染色剂的制备方法和使用的组合物
公开(公告)号：US5135544A
公开(公告)日：1992-08-04
申请号：US545558
申请日：1990-06-29
申请人： Jean F. Grollier , Jean Cotteret
发明人： Jean F. Grollier , Jean Cotteret
IPC分类号： A61K8/00 , A61K8/20 , A61K8/49 , A61Q5/10 , D06P3/08
CPC分类号： A61Q5/10 , A61K8/492
摘要： The invention relates to a process for dyeing keratinous fibres, comprising the application on these fibres,in a first stage, of a composition (A) containing, in a medium suitable for dyeing:(i) at least one monohydroxyindole corresponding to the formula (I): ##STR1## in which: R.sub.1 denotes hydrogen or alkyl; andR.sub.2 and R.sub.3 denote hydrogen, NH.sub.2, OH, COOH, CH.sub.2 COOH, CONH.sub.2, alkyl optionally substituted with OH or NH.sub.2, alkoxy, CONHR.sub.4, CON(R.sub.5)(R.sub.6) or CO.sub.2 R.sub.4, in which R.sub.4, R.sub.5 and R.sub.6 denote alkyl; halogen, and(ii) at least one 5,6-disubstituted hydroxyindole of formula (II): ##STR2## in which: R.sub.6 denotes hydrogen or acetyl;R.sub.4 denotes hydrogen, methyl, carboxy or ethoxycarbonyl; andR.sub.5 denotes hydrogen or methyl, with the proviso that, when R.sub.6 denotes acetyl, R.sub.4 and R.sub.5 represent a hydrogen atom; and its salts;in a second stage, a rinsing of the treated fibres is performed; andin a third stage, a composition (B) containing periodic acid or one of its salts in an aqueous medium is applied.
摘要翻译：本发明涉及染色角质纤维的方法，其包括在第一阶段在这些纤维上施用组合物（A）的方法，所述组合物（A）在适于染色的培养基中含有：（i）至少一种对应于式（1）的单羟基吲哚 I）：其中：R 1表示氢或烷基; 并且R 2和R 3表示氢，NH 2，OH，COOH，CH 2 COOH，CONH 2，任选被OH或NH 2取代的烷基，烷氧基，CONHR 4，CON（R 5）（R 6）或CO 2 R 4，其中R 4，R 5和R 6表示烷基; 卤素，和（ii）式（II）的至少一种5,6-二取代羟基吲哚：其中：R6表示氢或乙酰基; R4表示氢，甲基，羧基或乙氧基羰基; 并且R 5表示氢或甲基，条件是当R 6表示乙酰基时，R 4和R 5表示氢原子; 及其盐类在第二阶段中，进行经处理的纤维的漂洗; 并且在第三阶段中，施加在含水介质中含有高碘酸或其盐之一的组合物（B）。

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