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1. 发明授权

US06437063B1 Process for preparing polypropylene 有权
标题翻译：制备聚丙烯的方法
公开(公告)号：US06437063B1
公开(公告)日：2002-08-20
申请号：US09530689
申请日：2000-06-23
申请人： Amir Karbasi , Pauli Leskinen , Pirjo J{umlaut over (aa)}skeläinen , Bo Malm , Päivi Pitkänen , Mika Härkönen , John Haugen
发明人： Amir Karbasi , Pauli Leskinen , Pirjo J{umlaut over (aa)}skeläinen , Bo Malm , Päivi Pitkänen , Mika Härkönen , John Haugen
IPC分类号： C08F3200
CPC分类号： C08F10/06 , C08F4/65916 , C08F4/65927 , C08F110/06 , C08L23/0823 , C08L23/0838 , C08L23/10 , C08L2207/02 , C08L2314/06 , Y02P20/52 , Y10S526/904 , Y10S526/943 , C08F4/6492 , C08F4/6465 , C08F4/65912 , C08L2666/04 , C08F2500/15 , C08F2500/17 , C08F2500/07 , C08F2500/12
摘要： The present invention concerns a process for producing a propylene polymer nucleated with a polymeric nucleating agent containing vinyl compound units. The method comprises modifying a catalyst by polymerizing a vinyl compound in the presence of said catalyst in a medium, which does not essentially dissolve the polymerized vinyl compound, and by continuing the polymerization of the vinyl compound until the concentration of unreacted vinyl compounds is less than about 0.5 wt-%. The thus obtained modified catalyst composition is used for polymerizing propylene optionally together with comonomers to produce in the presence of said modified catalyst composition. Modification of the catalyst according to the present invention will reduce production costs and provide highly reliable catalyst activity.
摘要翻译：本发明涉及用含有乙烯基化合物单元的聚合物成核剂成核的丙烯聚合物的制备方法。所述方法包括通过在所述催化剂存在下在介质中聚合乙烯基化合物来改性催化剂，该介质基本上不溶解聚合的乙烯基化合物，并且继续乙烯基化合物的聚合直到未反应的乙烯基化合物的浓度小于约0.5wt％。由此获得的改性催化剂组合物用于任选与共聚单体一起聚合丙烯，以在所述改性催化剂组合物存在下制备。根据本发明的催化剂的改性将降低生产成本并提供高度可靠的催化剂活性。

2. 发明授权

US06300420B1 Polypropylene composition with broad MWD 失效
标题翻译：具有广泛MWD的聚丙烯组合物
公开(公告)号：US06300420B1
公开(公告)日：2001-10-09
申请号：US08817210
申请日：1997-05-12
申请人： Pirjo J{umlaut over (aa)}skeläinen , Amir Karbasi , Bo Malm , Päivi Pitkänen
发明人： Pirjo J{umlaut over (aa)}skeläinen , Amir Karbasi , Bo Malm , Päivi Pitkänen
IPC分类号： C08L2314
CPC分类号： C08F297/08 , C08F210/06 , C08L23/142 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08L2314/02 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F2500/12 , C08F2500/04 , C08F2500/01 , C08F2500/19 , C08F2500/21
摘要： The invention relates to a copolymer composition prepared from copolymers of propene and &agr;-olefin having 2 to 12 carbon atoms, having high molecular weight, a broad molecular weight distribution and an improved comonomer distribution. The invention relates also to a process for producing the composition and the use of the composition in pipes, fittings, profiles, films and foams. The composition is a so-called reactor mixture of copolymers of said monomers comprising a first copolymer having a higher molecular weight, an &agr;-olefin content of 3 to 10 wt. % and a melt flow rate MFR2 of 0,005 to 0,8, and a second copolymer having a lower molecular weight, thus the final composition has a comonomer content of 2 to 10 wt. %, a melt flow rate MFR2 of 0,05 to 2,5 wt. %, a melt flow ratio MFR10/MFR2 of 6 to 15, and the split of the copolymers in the composition between the higher molecular weight copolymer and the lower molecular weight copolymer is from 40/60 to 70/30.
摘要翻译：本发明涉及由具有2至12个碳原子的丙烯和α-烯烃的共聚物制备的具有高分子量，宽分子量分布和改进的共聚单体分布的共聚物组合物。本发明还涉及一种生产该组合物的方法和该组合物在管道，配件，型材，膜和泡沫中的用途。所述组合物是所述单体的共聚物的所谓反应混合物，其包含具有较高分子量，3-10重量％的α-烯烃含量的第一共聚物。％，熔体流动速率MFR 2为0.005至0.8，第二共聚物具有较低的分子量，因此最终组合物的共聚单体含量为2-10wt。％，熔体流动速率MFR2为0.05至2.5wt。％，熔体流动比MFR 10 / MFR 2为6〜15，高分子量共聚物与低分子量共聚物的组成中共聚物的分裂为40/60〜70/30。

3. 发明授权

US06365682B1 Process for the production of propylene terpolymers 有权
标题翻译：制备丙烯三元共聚物的方法
公开(公告)号：US06365682B1
公开(公告)日：2002-04-02
申请号：US09446503
申请日：2000-02-22
申请人： Kauno Alastalo , Bo Malm , Päivi Pitkänen , Mika Meller , Anne Britt Bjåland , Nina Ackermans , Kshama Motha
发明人： Kauno Alastalo , Bo Malm , Päivi Pitkänen , Mika Meller , Anne Britt Bjåland , Nina Ackermans , Kshama Motha
IPC分类号： C08F234
CPC分类号： C08F297/08 , B01J2219/00128 , B01J2219/00162 , B01J2219/00164 , B01J2219/00184 , C08F10/06 , C08F210/06 , C08F210/16 , Y10S526/905 , Y10S526/916 , C08F2/14 , C08F2/06 , C08F2/001 , C08F210/08 , C08F2500/12 , C08F2500/18 , C08F2500/26
摘要： A process for producing terpolymers of propylene, comprising a) feeding into a slurry reactor a reaction mixture containing 50-85 w-% of propylene, 1-10 w-% of ethylene, 15-40 w-% of another C4-C8 alpha-olefin, a catalyst system maintaining olefin polymerization at said temperature conditions, and optionally hydrogen, b) polymerizing said reaction mixture at a temperature of lower than 70° C. a sufficient time to obtain a propylene terpolymer amounting to 50-99 w-% of the end product, c) transferring said reaction mixture into a gas phase reactor operating at a pressure of higher than 5 bars, preferably higher than 10 bars, optionally adding 0-30 w-% of ethylene, 0-10 w-% of another C4-C8 alpha-olefin, 0-40 w-% of propylene and optionally hydrogen, and d) continuing polymerization in said gas phase reactor for obtaining a propylene terpolymer amounting to 1-50 wt-% of the end product. The terpolymer has a melting temperature a less than 135° C., preferably less than 132° C., and it can be used for manufacturing films having good sealing properties.
摘要翻译：一种生产丙烯三元共聚物的方法，包括：a）向淤浆反应器中加入含有50-85％（重量）丙烯，1-10％乙烯，15-40％（重量）另一种C 4 -C 8α- 烯烃，在所述温度条件下保持烯烃聚合的催化剂体系，以及任选的氢气，b）在低于70℃的温度下将所述反应混合物聚合足够的时间以获得总共为50-99w-％的丙烯三元共聚物的最终产物，c）将所述反应混合物转移到在高于5巴，优选高于10巴的压力下操作的气相反应器，任选地加入0-30重量％的乙烯，0-10重量％的乙烯，另外的C 4 -C 8α-烯烃，0-40％（重量）的丙烯和任选的氢，和d）在所述气相反应器中连续聚合，得到总共1-50％（重量）最终产物的丙烯三元共聚物。三元共聚物的熔融温度小于135℃，优选小于132℃，可用于制造具有良好密封性能的膜。

4. 发明授权

US06552149B2 Propylene terpolymers 有权
标题翻译：丙烯三元共聚物
公开(公告)号：US06552149B2
公开(公告)日：2003-04-22
申请号：US10036728
申请日：2001-12-21
申请人： Kauno Alastalo , Bo Malm , Päivi Pitkänen , Mika Meller , Anne Britt Bjåland , Nina Ackermans , Kshama Motha
发明人： Kauno Alastalo , Bo Malm , Päivi Pitkänen , Mika Meller , Anne Britt Bjåland , Nina Ackermans , Kshama Motha
IPC分类号： C08F21006
CPC分类号： C08F297/08 , B01J2219/00128 , B01J2219/00162 , B01J2219/00164 , B01J2219/00184 , C08F10/06 , C08F210/06 , C08F210/16 , Y10S526/905 , Y10S526/916 , C08F2/14 , C08F2/06 , C08F2/001 , C08F210/08 , C08F2500/12 , C08F2500/18 , C08F2500/26
摘要： A process for producing terpolymers of propylene, comprising a) feeding into a slurry reactor a reaction mixture containing 50-85 w-% of propylene, 1-10 w-% of ethylene, 15-40 w-% of another C4-C8 alpha-olefin, a catalyst system maintaining olefin polymerization at said temperature conditions, and optionally hydrogen, b) polymerizing said reaction mixture at a temperature of lower than 70° C. a sufficient time to obtain a propylene terpolymer amounting to 50-99 w-% of the end product, c) transferring said reaction mixture into a gas phase reactor operating at a pressure of higher than 5 bars, preferably higher than 10 bars, optionally adding 0-30 w-% of ethylene, 0-10 w-% of another C4-C8 alpha-olefin, 0-40 w-% of propylene and optionally hydrogen, and d) continuing polymerization in said gas phase reactor for obtaining a propylene terpolymer amounting to 1-50 wt-% of the end product. The terpolymer has a melting temperature a less than 135° C., preferably less than 132° C., and it can be used for manufacturing films having good sealing properties.
摘要翻译：一种生产丙烯三元共聚物的方法，包括：a）向淤浆反应器中加入含有50-85％（重量）丙烯，1-10％乙烯，15-40％（重量）另一种C 4 -C 8α- 烯烃，在所述温度条件下保持烯烃聚合的催化剂体系，以及任选的氢气，b）在低于70℃的温度下将所述反应混合物聚合足够的时间以获得总共为50-99w-％的丙烯三元共聚物的最终产物，c）将所述反应混合物转移到在高于5巴，优选高于10巴的压力下操作的气相反应器，任选地加入0-30重量％的乙烯，0-10重量％的乙烯，另外的C 4 -C 8α-烯烃，0-40％（重量）的丙烯和任选的氢，和d）在所述气相反应器中连续聚合，得到总共1-50％（重量）最终产物的丙烯三元共聚物。三元共聚物的熔融温度小于135℃，优选小于132℃，可用于制造具有良好密封性能的膜。

5. 发明授权

US07452953B2 Propylene random copolymer and process for the production thereof 失效
标题翻译：丙烯无规共聚物及其制备方法
公开(公告)号：US07452953B2
公开(公告)日：2008-11-18
申请号：US11836657
申请日：2007-08-09
申请人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
发明人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
IPC分类号： C08F210/16
CPC分类号： C08F297/083 , C08F10/00 , C08F210/06 , C08F210/16 , C08F297/08 , C08F4/6465 , C08F2/001 , C08F2500/12 , C08F2500/26 , C08F2500/17
摘要： The present invention relates to a process for preparing a propylene random copolymer comprising polymerization of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerization of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerization product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerizations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerization product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process. Furthermore, the invention relates to a propylene random copolymer prepared by copolymerization of propylene with a comonomer wherein the distribution of the comonomer determined according to the TREF method is multimodal, preferably bimodal, a propylene random copolymer prepared by copolymerization of propylene with a comonomer wherein the copolymer is having an elution interval determined according to the TREF method of 50° C. or more, a propylene random copolymer prepared by copolymerization of propylene with a comonomer, wherein the random copolymer is a unimodal polymer and the elution interval determined by the TREF method is given by the equation Y≦4.5·m+16 wherein Y is the elution interval in ° C. and m is the percentage of ethylene in the copolymer in wt. %, and to the use of such a copolymers for the production of a film, of an article by blow moulding or injection moulding, of a fiber or of a pipe.
摘要翻译：本发明涉及一种制备丙烯无规共聚物的方法，其包括丙烯与共聚单体的聚合，所述共聚单体是乙烯或包含至少四个碳原子的α-烯烃，在催化剂存在下以多阶段方法包括聚合丙烯与第一反应区中的共聚单体包括至少一个淤浆反应器以产生第一聚合产物，将所述第一产物转移到包含至少一个气相反应器的第二反应区，并且在所述气相反应器中聚合丙烯与共聚单体在所述第一聚合产物的存在下，其中气相反应器中的温度高于浆料反应器中的至少10℃，并且可通过该方法获得的聚合物。此外，本发明涉及通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中根据TREF法测定的共聚单体的分布是多峰的，优选双峰的，丙烯与共聚单体共聚制备的丙烯无规共聚物，其中，共聚物的洗脱间隔根据TREF法测定为50℃以上，通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中无规共聚物是单峰聚合物，并且通过TREF法测定的洗脱间隔由方程Y <= 4.5.m + 16给出，其中Y是以℃计的洗脱间隔，m是共聚物中乙烯的百分比。以及使用这种共聚物来制造纤维或管子的通过吹塑或注射成型的制品的薄膜，制品。

6. 发明授权

US07449534B2 Polymerization process for producing propylene copolymers 有权
标题翻译：用于生产丙烯共聚物的聚合方法
公开(公告)号：US07449534B2
公开(公告)日：2008-11-11
申请号：US11543117
申请日：2006-10-05
申请人： Petri Lehmus , Kimmo Hakala , Päivi Pitkänen , Manfred Arnold , Andreas Meinecke , Udo Manfred Stehling
发明人： Petri Lehmus , Kimmo Hakala , Päivi Pitkänen , Manfred Arnold , Andreas Meinecke , Udo Manfred Stehling
IPC分类号： C08F210/06 , C08F210/14
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F2/14 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F210/08 , C08F2500/03 , C08F2500/20
摘要： The invention provides a process for the preparation of a propylene polymer in which proplylene and a comonomer copolymerizable therewith and of greater molecular weight than propylene are polymerized in a single site catalyst catalized polymerization reaction, characterized in that said polymerization reaction is effected at least in part at a temperature of at least 70° C.
摘要翻译：本发明提供一种制备丙烯聚合物的方法，其中将丙烯和可与其共聚并且具有比丙烯更大的分子量的共聚单体在单中心催化剂催化聚合反应中聚合，其特征在于所述聚合反应至少部分地进行在至少70℃的温度下

7. 发明授权

US07157534B2 Polymerization process for producing copolymers 有权
标题翻译：制备共聚物的聚合方法
公开(公告)号：US07157534B2
公开(公告)日：2007-01-02
申请号：US10476646
申请日：2002-05-03
申请人： Petri Lehmus , Kimmo Hakala , Päivi Pitkänen , Manfred Arnold , Andreas Meinecke , Udo Manfred Stehling
发明人： Petri Lehmus , Kimmo Hakala , Päivi Pitkänen , Manfred Arnold , Andreas Meinecke , Udo Manfred Stehling
IPC分类号： C08F6/6292 , C08F6/44 , C08F210/06
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F2/14 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F210/08 , C08F2500/03 , C08F2500/20
摘要： The invention provides a process for the preparation of a propylene polymer in which propylene and a comonomer copolymerizable therewith and of greater molecular weight than propylene are polymerized in a single site catalyst catalized polymerization reaction, characterised in that said polymerization reaction is effected at least in part at a temperature of at least 70° C.
摘要翻译：本发明提供一种制备丙烯聚合物的方法，其中丙烯和可共聚合并且具有比丙烯更大的分子量的共聚单体在单中心催化剂催化聚合反应中聚合，其特征在于所述聚合反应至少部分地进行在至少70℃的温度下

8. 发明授权

US07470756B2 Propylene random copolymer and process for the production thereof 有权
标题翻译：丙烯无规共聚物及其制备方法
公开(公告)号：US07470756B2
公开(公告)日：2008-12-30
申请号：US10482271
申请日：2002-06-26
申请人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
发明人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
IPC分类号： C08F2/02 , C08F2/06 , C08F2/14 , C08F2/34 , C08F210/06 , C08F210/16
CPC分类号： C08F297/083 , C08F10/00 , C08F210/06 , C08F210/16 , C08F297/08 , C08F4/6465 , C08F2/001 , C08F2500/12 , C08F2500/26 , C08F2500/17
摘要： The present invention relates to a process for preparing a propylene random copolymer comprising polymerisation of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a muiltistage process comprising polymerisation of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerisation product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerisation product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process. Furthermore, the invention relates to a propylene random copolymer prepared by copolymerisation of propylene with a comonomer wherein the distribution of the comonomer determined according to the TREF method is multimodal, preferably bimodal, a peopylene radom copolymer prepared by copolymerisation of propylene with a comonomer wherein the copolymer is having an elution interval determined according to the TREF method of 50° C. or more, a propylene random copolymer prepared by copolymerisation of propylene with a comonomer, wherein the random copolymer is a unimodal polymer and the elution interval determined by the TREF method is given by the equation Y≦4.5.m+16 wherein Y is the elution interval in ° C. and m is the percentage of ethylene in the copolymer in wt. %, and to the use of such a copolymers for the production of a film, of an article by blow moulding or injection moulding, of a fibre or of a pipe.
摘要翻译：丙烯无规共聚物的制备方法技术领域本发明涉及一种制备丙烯无规共聚物的方法，其包括丙烯与共聚单体的聚合，所述共聚单体是乙烯或包含至少四个碳原子的α-烯烃，在催化剂存在下，丙烯与第一反应区中的共聚单体包括至少一个浆料反应器以产生第一聚合产物，将所述第一产物转移到包含至少一个气相反应器的第二反应区和丙烯与所述气相反应器中的共聚单体聚合在所述第一聚合产物存在下，其中气相反应器中的温度高于浆料反应器中的至少10℃，并且可通过该方法获得的聚合物。此外，本发明涉及通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中根据TREF方法测定的共聚单体的分布是多峰的，优选双峰的，通过丙烯与共聚单体共聚制备的聚二苯基共聚物共聚物，其中共聚物具有根据TREF法测定的洗脱间隔为50℃以上，通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中无规共聚物是单峰聚合物，并且通过TREF方法测定的洗脱间隔由方程Y <= 4.5.m + 16给出，其中Y是以℃计的洗脱间隔，m是共聚物中乙烯的百分比。以及使用这种共聚物来制造纤维或管子的通过吹塑或注射成型的制品的薄膜，制品。

9. 发明授权

US07323525B2 Process for the production of propylene copolymers 失效
标题翻译：制备丙烯共聚物的方法
公开(公告)号：US07323525B2
公开(公告)日：2008-01-29
申请号：US10492276
申请日：2002-10-02
申请人： Kauno Alastalo , Päivi Pitkänen , Marita Sutela , Lucas Pelckmans , Harri Hokkanen
发明人： Kauno Alastalo , Päivi Pitkänen , Marita Sutela , Lucas Pelckmans , Harri Hokkanen
IPC分类号： C08F4/02 , C08F4/642
CPC分类号： C08F210/16 , C08F210/06 , C08F4/022 , C08F4/651 , C08F4/6543 , C08F210/08 , C08F2500/12 , C08F2500/26
摘要： Polymers of propylene with one or two olefin comonomers are produced through the use of a polymerization catalyst supported on a carrier produced by spray crystallization and having a maximum dimension of 55 μm. Copolymers of superior properties are obtained, and the production process is de-snagged.
摘要翻译：丙烯与一种或两种烯烃共聚单体的聚合物通过使用负载在由喷雾结晶产生的载体上并具有55μm最大尺寸的载体上的聚合催化剂制备。获得优异性能的共聚物，并且生产过程脱钩。

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