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    • 6. 发明授权
    • Method for producing olefin-substituted aromatic or heteroaromatic compounds
    • 制备烯烃取代芳族或杂芳族化合物的方法
    • US07402717B2
    • 2008-07-22
    • US10343291
    • 2001-08-01
    • Hubert SpreitzerPhilipp StösselHeinrich Becker
    • Hubert SpreitzerPhilipp StösselHeinrich Becker
    • C07C2/72C07C2/64C07C2/68
    • C07C29/44C07B37/04C07C1/26C07C2603/18C07C2603/94C07C13/72C07C33/28
    • Both low molecular weight and high molecular weight aromatic and heteroaromatic compounds which are substituted by olefins play an important role in industry, for instance as assistants and additives in cosmetic preparations, for example in sunscreens, various fine and electronics chemicals, and precursors for pharmaceuticals and agrochemicals. Also, particularly in the rapidly growing field of organic semiconductors (for example applications in organic or polymeric light emitting diodes, organic solar cells, organic ICs), precisely these compounds are of outstanding significance.The present invention relates to a process for preparing such olefin-substituted aromatics or heteroaromatics by reacting a functional aryl or heteroaryl compound with an olefin derivative which has at least one hydrogen atom on the double bond in the presence of a simple palladium compound, optionally in the presence of a nitrogen additive, and of a base in a solvent, to form a C—C bond and formally cleave off the functional group of the aryl or heteroaryl derivative and a hydrogen atom of the olefin compound, characterized by the presence of at least one metal additive other than palladium.
    • 由烯烃取代的低分子量和高分子量芳族和杂芳族化合物在工业中起重要作用,例如作为化妆品制剂中的助剂和添加剂,例如防晒剂,各种精细和电子化学品以及用于药物和 农药。 此外,特别是在快速增长的有机半导体领域(例如有机或聚合物发光二极管中的应用,有机太阳能电池,有机IC)中,精确地这些化合物具有突出的意义。 本发明涉及通过使官能的芳基或杂芳基化合物与单键钯化合物存在下在双键上具有至少一个氢原子的烯烃衍生物反应来制备这种烯烃取代芳族化合物或杂芳族化合物的方法,任选地 在溶剂中存在氮添加剂和碱,以形成CC键并正式地断开芳基或杂芳基衍生物的官能团和烯烃化合物的氢原子,其特征在于存在至少一种 除钯以外的金属添加剂。
    • 10. 发明授权
    • Substituted poly(arylenevinylenes), process for their preparation, and their use in electroluminescent elements
    • 取代的聚(亚芳基亚乙烯基),其制备方法及其在电致发光元件中的应用
    • US06638646B2
    • 2003-10-28
    • US10185061
    • 2002-06-28
    • Hubert SpreitzerWilli KreuderHeinrich BeckerHermann SchenkNu Yu
    • Hubert SpreitzerWilli KreuderHeinrich BeckerHermann SchenkNu Yu
    • H05B3300
    • H01L51/0038C08G61/02C09K11/06H01B1/128H01L51/5012H05B33/14Y10S428/917
    • Poly(arylenevinylenes) comprising at least 20% of recurring units of the formula (I), where the symbols and indices have the following meanings: Aryl: is an aryl group having 4 to 14 carbon atoms; R′: is a substituent which is either in the labeled phenylene position 5 or 6 and is CN, F, Cl, N(R1R2) or a straight-chain, branched or cyclic alkyl, alkoxy or thioalkoxy group having 1 to 20 carbon atoms, in which, in addition, one or more H atoms may be replaced by F; R″: are identical or different and are CN, F, Cl or a straight-chain, branched or cyclic alkyl or alkoxy group having 1 to 20 carbon atoms, where one or more non-adjacent CH2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR1—, —(NR2R3)+—A− or —CONR4—, and where one or more H atoms may be replaced by F, or an aryl group having 4 to 14 carbon atoms, which may be substituted by one or more non-aromatic radicals R′; R1, R2, R3, R4 are identical or different and are H or an aliphatic or aromatic hydrocarbon radical having 1 to 20 carbon atoms; A−: is a singly charged anion or an equivalent thereof; and n: is 0, 1, 2, 3, 4 or 5, are suitable as electroluminescent material.
    • 包含至少20%式(I)的重复单元的聚(亚芳基亚乙烯基烯烃),其中符号和指数具有以下含义:芳基:具有4至14个碳原子的芳基; R'是 在标记的亚苯基位置5或6中,是CN,F,Cl,N(R 1 R 2)或具有1至20个碳原子的直链,支链或环烷基,烷氧基或硫代烷氧基, 其中,另外一个或多个H原子可被F取代; R“:相同或不同,为CN,F,Cl或具有1至20个碳的直链,支链或环状烷基或烷氧基 原子,其中一个或多个不相邻的CH 2基团可被-O - , - S - , - CO - , - COO - , - O-CO - , - NR 1 - , - (NR 2) R 3)+ - 或-CONR 4 - ,并且其中一个或多个H原子可以被F取代,或者可以被4〜14个碳原子的芳基取代,可以被 一个或多个非芳族基团R'; R 1,R 2,R 3,R 4相同或不同,为H或脂族或芳族氢 具有1至20个碳原子的羰基; A 1是单电荷阴离子或其等同物; 和n为0,1,2,3,4或5,适合作为电致发光材料。