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    • 5. 发明授权
    • Scavenger free photographic silver halide print media
    • 清道夫免费摄影卤化银印刷媒体
    • US06268116B1
    • 2001-07-31
    • US09472578
    • 1999-12-27
    • Michael R. RobertsGary J. McSweeneyAlphonse D. Camp
    • Michael R. RobertsGary J. McSweeneyAlphonse D. Camp
    • G03C146
    • G03C7/3029G03C7/3041
    • The invention relates to a multilayer photographic element comprising a reflective support wherein the color record 1 adjacent to the support comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; and wherein color record 2 above said color record 1 comprises at least one light sensitive layer and at least two non-light sensitive dye-forming interlayers and wherein color record 3 comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; an optional UV dye containing interlayer and a top overcoat; and wherein each interlayer is completely or substantially scavenger free, silver halide grains comprising greater than 90% silver chloride, and wherein the reciprocity characteristics of the silver halide grains are such that for a separation exposure of 1 microsecond and 0.4 sec, each color record develops to a density of at least 2.0 within a log exposure range of 1.2 or less relative to the exposure point producing a density 0.04 above Dmin.
    • 本发明涉及一种包括反射支撑体的多层照相元件,其中邻近支撑体的彩色记录1包括至少一个光敏层和非光敏染料形成中间层; 并且其中所述彩色记录1上方的色彩记录2包括至少一个光敏层和至少两个非光敏染料形成中间层,并且其中彩色记录3包括至少一个光敏层和非光敏染料形成 中间层 含有中间层的UV染料和顶部外涂层; 并且其中每个中间层是完全或基本上无清除的,包含大于90%氯化银的卤化银颗粒,并且其中卤化银颗粒的互易特性使得对于1微秒和0.4秒的分离曝光,每个颜色记录产生 在相对于曝光点的1.2或更小的对数曝光范围内的密度至少为2.0,产生高于Dmin的浓度0.04。
    • 8. 发明授权
    • Preparation of low viscosity small particle photographic dispersions in
gelatin
    • 在明胶中制备低粘度小颗粒照相分散体
    • US5135844A
    • 1992-08-04
    • US653912
    • 1991-02-12
    • Pranab BagchiGary J. McSweeneySteven J. Sargeant
    • Pranab BagchiGary J. McSweeneySteven J. Sargeant
    • B01F17/00G03C1/005G03C1/38G03C7/388
    • G03C1/005B01F17/0021B01F17/0028B01F17/0042B01F17/005B01F17/0085G03C1/38G03C7/388Y10S516/922
    • The invention is generally accomplished by utilization of a surfactant for very small particle photographic dispersions. Three types of such surfactants that have been identified are as follows:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycedyl ether groups that may or may not be terminated with a negative charge such as a sulfate group.Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A--B--A, B--A--B, A--B, (A--B).sub.n .tbd.G.tbd.(B--A), or (B--A).sub.n .tbd.G.tbd.(A--B).sub.n, where G is a connective organic moiety and n is between 1 and 3.Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.The preferred colloid chemical criterion of the photographic dispersion material in this invention is that they are formed with particle diameters between about 5 nm and 100 nm that have been prepared by precipitation from solution by a solvent and/or pH shift.
    • 本发明通常通过利用表面活性剂来实现非常小的颗粒照相分散体。 已经鉴定的三种类型的这种表面活性剂如下:A型表面活性剂,其包含6至22个碳原子的疏水尾部,其具有一个或多个附着的亲水链,其包含至少8个氧化乙烯和/或亚乙基醚基团,其可以或可以不被终止 带负电荷如硫酸根。 包含以ABA,BAB,AB,(AB)n 3BOND G 3BOND(BA)或(BA)n 3BOND G 3BOND的方式连接的疏水性聚氧丙烯嵌段(A)和亲水性聚氧乙烯嵌段(B)的B型低聚表面活性剂 (AB)n,其中G是连接性有机部分,n在1和3之间。C型糖表面活性剂,包含1至3个6至22个碳原子的疏水尾部与一个或多个连接的亲水单糖或寡糖链, 或者不能被带负电的基团如硫酸根基团终止。 本发明的照相分散体材料优选的胶体化学标准是它们通过溶剂通过溶剂沉淀和/或pH漂移制备的粒径在约5nm至100nm之间。
    • 9. 发明授权
    • Preparation of low viscosity small-particle photographic dispersions in
gelatin
    • 在明胶中制备低粘度小颗粒照相分散体
    • US5013640A
    • 1991-05-07
    • US366397
    • 1989-06-15
    • Pranab BagchiGary J. McSweeneySteven J. Sargeant
    • Pranab BagchiGary J. McSweeneySteven J. Sargeant
    • B01F17/42B01F17/00B01J13/00G03C1/005G03C1/043G03C1/06G03C1/38G03C7/388
    • G03C1/38B01F17/0021B01F17/0028B01F17/0042B01F17/005B01F17/0085G03C1/005G03C7/388Y10S516/922
    • The invention is generally accomplished by utilization of a surfactant for very small particle photographic dispersions. Three types of such surfactants that have been identified are as follows:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycedyl ether groups that may or may not be terminated with a negative charge such as a sulfate group.Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A-B-A, B-A-B, A-B, (A-B).sub.n .tbd.G.tbd.(B-A), or (B-A).sub.n .tbd.G.tbd.(A-B).sub.n, where G is a connective organic moiety and n is between 1 and 3.Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.The preferred colloid chemical criterion of the photographic dispersion material in this invention is that they are formed with particle diameters between about 5 nm and 100 nm that have been prepared by precipitation from solution by a solvent and/or pH shift.
    • 本发明通常通过利用表面活性剂来实现非常小的颗粒照相分散体。 已经鉴定的三种类型的这种表面活性剂如下:A型表面活性剂,其包含6至22个碳原子的疏水尾部,其具有一个或多个附着的亲水链,其包含至少8个氧化乙烯和/或亚乙基醚基团,其可以或可以不被终止 带负电荷如硫酸根。 包含以ABA,BAB,AB,(AB)n 3BOND G 3BOND(BA)或(BA)n 3BOND G 3BOND的方式连接的疏水性聚氧丙烯嵌段(A)和亲水性聚氧乙烯嵌段(B)的B型低聚表面活性剂 (AB)n,其中G是连接性有机部分,n在1和3之间。C型糖表面活性剂,包含1至3个6至22个碳原子的疏水尾部与一个或多个连接的亲水单糖或寡糖链, 或者不能被带负电的基团如硫酸根基团终止。 本发明的照相分散体材料优选的胶体化学标准是它们通过溶剂通过溶剂沉淀和/或pH漂移制备的粒径在约5nm至100nm之间。