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    • 3. 发明授权
    • Substituted thiazolidinones useful as plant growth regulators
    • 用作植物生长调节剂的取代的噻唑烷酮
    • US4664694A
    • 1987-05-12
    • US726533
    • 1985-04-24
    • Walter G. BrouwerAllen R. Blem
    • Walter G. BrouwerAllen R. Blem
    • A01N43/78C07D277/14C07D277/24C07F9/653C07D277/04C07D277/06
    • C07D277/14
    • A compound is disclosed having the structural formula ##STR1## where R is hydrogen, chlorine, bromine, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CH.sub.2 COOH, --CH.sub.2 COO (C.sub.1 -C.sub.4 alkyl), --CH.sub.2 CONHN (C.sub.1 -C.sub.2 alkyl).sub.2, --CH.sub.2 CONR.sup.4 R.sup.5, --SPS(C.sub.1 -C.sub.4 alkoxy).sub.2 or --SPO(C.sub.1 -C.sub.4 alkoxy).sub.2 (C.sub.1 -C.sub.4 alkylthio).sub.2 ;R.sup.1, R.sup.2 and R.sup.3 are the same or different and are hydrogen, hydroxy, fluorine, chlorine, bromine, iodine, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.6 fluoroalkyl, C.sub.1 -C.sub.6 chloroalkyl, C.sub.1 -C.sub.6 fluoroalkoxy, C.sub.1 -C.sub.6 chloroalkoxy, C.sub.1 -C.sub.6 fluoroalkylthio, C.sub.1 -C.sub.6 chloroalkylthio, C.sub.7 -C.sub.9 aralkyl, phenyl, phenoxy, phenylthio, C.sub.2 -C.sub.5 alkoxycarbonyl, carboxy, nitro or cyano; andR.sup.4 and R.sup.5 are the same or different and are hydrogen or C.sub.1 -C.sub.6 alkyl; alternativelyR.sup.4 and R.sup.5 together are C.sub.4 -C.sub.6 alkylene or C.sub.4 -C.sub.6 oxydialkylene; andn is 0, 1 or 2.This compound is useful in regulating the growth of plants and can be formed int a composition, useful in this application. The composition comprises the compound having the structural formula given above and an inert carrier therefor. A process for forming the compound set forth above is also taught.
    • 公开了具有结构式为“IMAGE”的化合物,其中R是氢,氯,溴,C1-C4烷基,C1-C4烷氧基,-CH2COOH,-CH2COO(C1-C4烷基),-CH2CONHN(C1-C2烷基) 2,-CH 2 CONR 4 R 5,-SPS(C 1 -C 4烷氧基)2或-SPO(C 1 -C 4烷氧基)2(C 1 -C 4烷硫基)2; R1,R2和R3相同或不同,为氢,羟基,氟,氯,溴,碘,C1-C6烷基,C1-C6烷氧基,C1-C6烷硫基,C1-C4烷基磺酰基,C1-C6氟烷基,C1 C 1-6氯烷基,C 1 -C 6氟烷氧基,C 1 -C 6氯烷氧基,C 1 -C 6氟代烷硫基,C 1 -C 6氯代烷硫基,C 7 -C 9芳烷基,苯基,苯氧基,苯硫基,C 2 -C 5烷氧基羰基,羧基,硝基或氰基; 且R 4和R 5相同或不同,为氢或C 1 -C 6烷基; 或者R4和R5一起是C4-C6亚烷基或C4-C6氧基二亚烷基; 并且n为0,1或2.该化合物可用于调节植物的生长并且可以形成为在本申请中有用的组合物。 组合物包含具有上述结构式的化合物和其惰性载体。 还教导了用于形成上述化合物的方法。
    • 10. 发明授权
    • Azole derivatives of spiroheterocycles
    • 螺杂环的唑衍生物
    • US4943311A
    • 1990-07-24
    • US191932
    • 1988-05-09
    • Hoi K. LaiRobert A. DavisAllen R. Blem
    • Hoi K. LaiRobert A. DavisAllen R. Blem
    • A01N43/50A01N43/653A01N43/78A01N43/90C07D495/10C07D513/10C07D521/00A01N43/28C07D405/14C07D409/14C07D411/14
    • C07D231/12A01N43/50A01N43/653A01N43/78A01N43/90C07D233/56C07D249/08C07D495/10C07D513/10
    • A compound having the structural formula ##STR1## where R is C.sub.2 -C.sub.8 alkylene having 2 to 4 carbon atoms linking X and Y;R.sup.1 is C.sub.1 -C.sub.8 linear or branched alkylene, C.sub.1 -C.sub.6 oxyalkylene, C.sub.1 -C.sub.6 thioalkylene or C.sub.1 -C.sub.6 aminoalkylene;R.sup.2 and R.sup.3 are the same or different and are hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.1 -C.sub.6 alkylsulfonyl, phenyl, substituted phenyl, phenoxy, substituted phenoxy, cyano, nitro, --OCOR.sup.4, --COOR.sup.5, --CH.sub.m Q.sub.3-m or --OCH.sub.m Q.sub.3-m ;R.sup.4 is C.sub.1 -C.sub.4 alkyl;R.sup.5 is hydrogen or C.sub.1 -C.sub.4 alkyl;Q is halogen;X and Y are the same or different and are oxygen, sulfur, sulfinyl, sulfonyl or if one is NH, the other is sulfur;Z is nitrogen or CH; andm is 1, 2 or 3;and physiologically acceptable salts thereof,is disclosed. A process for synthesizing the compound of this invention is also set forth. This process involves reacting a compound having the structural formula ##STR2## where R.sup.1, R.sup.2, R.sup.3 and Z have the meanings given for the compound of this invention with a compound having the structural formulaHX--R--YHwhere R, X and Y have the meanings given for the compound of the present invention. The compounds of this invention find utility as fungicides and plant growth regulants. Thus, the instant invention is also directed to processes for controlling fungi and regulating plant growth by utilizing effective amounts of the compound of the present invention to effectuate these goals. Finally, fungicidal and plant growth regulant compositions comprising effective amounts of the compound of this invention and carriers therefor is within the contemplation of the present invention.