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1. 发明申请

US20150321139A1 PROCESS FOR ABSORPTION OF CO2 FROM A GAS MIXTURE USING AN AQUEOUS SOLUTION OF A DIAMINE 审中-公开
标题翻译：使用氨水溶液从气体混合物中吸收二氧化碳的方法
公开(公告)号：US20150321139A1
公开(公告)日：2015-11-12
申请号：US14649068
申请日：2013-11-13
申请人： Alexander SCHRAVEN , Jochen NIEMEYER , Manfred NEUMANN , Stefanie RINKER , Rolf SCHNEIDER , Jörn ROLKER
发明人： Alexander Schraven , Jochen Niemeyer , Manfred Neumann , Stefanie Rinker , Rolf Schneider , Jörn Rolker
IPC分类号： B01D53/14
CPC分类号： B01D53/1475 , B01D53/1425 , B01D53/1493 , B01D53/62 , B01D2252/103 , B01D2252/2041 , B01D2252/20426 , B01D2252/20431 , B01D2257/504 , B01D2258/0283 , B01D2258/05 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorption medium comprising water and at least one amine of formula (I) R1R2NCH2CH2CHR4NHR3, (I) where R1, R2 and R3 are, independently of one another, C1-C3-alkyl radicals, R4 is hydrogen, methyl or ethyl and the radicals R1, R2, R3 and R4 together comprise not more than 5 carbon atoms.
摘要翻译：通过使气体混合物与包含水和至少一种式（I）的胺R 1 R 2 NCH 2 CH 2 CHR 4 NHR 3（I）的吸收介质接触，从气体混合物中吸收CO 2，其中R 1，R 2和R 3彼此独立地为C1- C 3 - 烷基，R 4是氢，甲基或乙基，基团R 1，R 2，R 3和R 4一起包含不超过5个碳原子。

2. 发明申请

US20110189742A1 METHOD FOR THE PRODUCTION OF FREE CARBOXYLIC ACIDS 失效
标题翻译：生产游离羧酸的方法
公开(公告)号：US20110189742A1
公开(公告)日：2011-08-04
申请号：US13002519
申请日：2009-04-29
申请人： Thomas Haas , Thomas Tacke , Achim Marx , Alexander Schraven , Olivier Zehnacker , Eva Maria Wittmann
发明人： Thomas Haas , Thomas Tacke , Achim Marx , Alexander Schraven , Olivier Zehnacker , Eva Maria Wittmann
IPC分类号： C12P7/40
CPC分类号： C12P7/40 , C07C51/02 , C07C51/41 , C07C51/47 , C12P7/42 , C07C59/01 , C07C59/06 , C07C59/255 , C07C59/08 , C07C59/265
摘要： A process for the preparation of free carboxylic acids including: A) preparation of carboxylic acid by a biological cell located in an aqueous medium with addition of an amine of formula (I) where R1, R2 and R3, independently of one another, are identical or different, branched or unbranched, optionally substituted hydrocarbon radicals or H; B) for cases where the added amine A) is water-soluble, addition of a water-insoluble amine of formula (I), where, in A) or B), a multiphase system is obtained and the corresponding ammonium carboxylate is formed from the water-insoluble amine and the carboxylic acid; C) removal of the water-insoluble phase; and D) heating of the water-insoluble phase with release of free carboxylic acid.
摘要翻译：一种制备游离羧酸的方法，包括：A）通过加入式（I）的胺的位于水性介质中的生物细胞制备羧酸，其中R1，R2和R3彼此独立地相同或不同的支链或非支链的任选取代的烃基或H; B）对于添加的胺A）是水溶性的，加入式（I）的水不溶性胺，其中在A）或B）中获得多相体系，并且相应的羧酸铵由水不溶性胺和羧酸; C）去除水不溶性相; 和D）释放游离羧酸时加热水不溶性相。

3. 发明申请

US20110257429A1 METHOD FOR PRODUCING A FREE ACID FROM THE SALT THEREOF 有权
标题翻译：从其盐生产游离酸的方法
公开(公告)号：US20110257429A1
公开(公告)日：2011-10-20
申请号：US13141456
申请日：2010-02-01
申请人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
发明人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
IPC分类号： C07F9/30 , C07C51/42 , C07C51/43 , C07C51/44 , C07C51/02 , C07C303/02
CPC分类号： C07C51/02 , C07C59/00 , C07C55/10 , C07C59/01 , C07C55/00 , C07C65/00 , C07C59/08 , C07C63/00
摘要： The invention relates to an improved method for releasing an organic acid, preferably a carbon, sulfone or phosphone acid, particularly an alpha or beta hydroxycarbon acid, from the ammonia salt thereof by releasing and removing ammoniac and simultaneous extraction of the released acid, having an amine as a suitable extraction means from the aqueous phase. This method corresponds to a reactive extraction. The reactive extraction of an organic acid from the aqueous ammonia salt solution thereof can be significantly improved by the use of a strip medium or carrier gas, such as nitrogen, air, water vapor or inert gases such as argon. The released ammoniac is removed from the aqueous solution by the continuous gas flow and can be resupplied into a production process. The free acid can be obtained by a method such as distillation, rectification, crystallization, reextraction, chromatography, adsorption or by a membrane method from the extraction means.
摘要翻译：本发明涉及通过释放和除去氨和同时提取释放的酸的有机酸，优选碳，砜或膦酸，特别是α或β羟基碳酸从其氨盐释放的改进方法，其具有胺作为来自水相的合适的提取方法。该方法对应于反应萃取。通过使用带状介质或载气如氮气，空气，水蒸汽或惰性气体如氩气，可以显着地改善有机酸从其氨水溶液中的反应萃取。通过连续气流将释放的氨水从水溶液中除去，并且可以再供给到生产过程中。游离酸可以通过蒸馏，精馏，结晶，再萃取，色谱法，吸附法或从提取方法通过膜法等方法得到。

4. 发明授权

US08809576B2 Method for producing a free acid from the salt thereof 有权
标题翻译：从其盐生产游离酸的方法
公开(公告)号：US08809576B2
公开(公告)日：2014-08-19
申请号：US13141456
申请日：2010-02-01
申请人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
发明人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
IPC分类号： C07F9/22
CPC分类号： C07C51/02 , C07C59/00 , C07C55/10 , C07C59/01 , C07C55/00 , C07C65/00 , C07C59/08 , C07C63/00
摘要： The invention relates to an improved method for releasing an organic acid, preferably a carbon, sulfone or phosphone acid, particularly an alpha or beta hydroxycarbon acid, from the ammonia salt thereof by releasing and removing ammoniac and simultaneous extraction of the released acid, having an amine as a suitable extraction means from the aqueous phase. This method corresponds to a reactive extraction. The reactive extraction of an organic acid from the aqueous ammonia salt solution thereof can be significantly improved by the use of a strip medium or carrier gas, such as nitrogen, air, water vapor or inert gases such as argon. The released ammoniac is removed from the aqueous solution by the continuous gas flow and can be resupplied into a production process. The free acid can be obtained by a method such as distillation, rectification, crystallization, reextraction, chromatography, adsorption or by a membrane method from the extraction means.
摘要翻译：本发明涉及通过释放和除去氨和同时提取释放的酸的有机酸，优选碳，砜或膦酸，特别是α或β羟基碳酸从其氨盐中释放的改进方法，其具有胺作为来自水相的合适的提取方法。该方法对应于反应萃取。通过使用带状介质或载气如氮气，空气，水蒸汽或惰性气体如氩气，可以显着地改善有机酸从其氨水溶液中的反应萃取。通过连续气流将释放的氨水从水溶液中除去，并且可以再供给到生产过程中。游离酸可以通过蒸馏，精馏，结晶，再萃取，色谱法，吸附法或从提取方法通过膜法等方法得到。

5. 发明授权

US08703451B2 Method for the production of free carboxylic acids 失效
标题翻译：游离羧酸生产方法
公开(公告)号：US08703451B2
公开(公告)日：2014-04-22
申请号：US13002519
申请日：2009-04-29
申请人： Thomas Haas , Thomas Tacke , Achim Marx , Alexander Schraven , Olivier Zehnacker , Eva Maria Wittmann
发明人： Thomas Haas , Thomas Tacke , Achim Marx , Alexander Schraven , Olivier Zehnacker , Eva Maria Wittmann
IPC分类号： C12P7/40 , C07C51/47 , C07C51/41 , C12P7/42
CPC分类号： C12P7/40 , C07C51/02 , C07C51/41 , C07C51/47 , C12P7/42 , C07C59/01 , C07C59/06 , C07C59/255 , C07C59/08 , C07C59/265
摘要： A process for the preparation of free carboxylic acids including: A) preparation of carboxylic acid by a biological cell located in an aqueous medium with addition of an amine of formula (I) where R1, R2 and R3, independently of one another, are identical or different, branched or unbranched, optionally substituted hydrocarbon radicals or H; B) for cases where the added amine A) is water-soluble, addition of a water-insoluble amine of formula (I), where, in A) or B), a multiphase system is obtained and the corresponding ammonium carboxylate is formed from the water-insoluble amine and the carboxylic acid; C) removal of the water-insoluble phase; and D) heating of the water-insoluble phase with release of free carboxylic acid.
摘要翻译：一种制备游离羧酸的方法，包括：A）通过加入式（I）的胺的位于水性介质中的生物细胞制备羧酸，其中R1，R2和R3彼此独立地相同或不同的支链或非支链的任选取代的烃基或H; B）对于添加的胺A）是水溶性的，加入式（I）的水不溶性胺，其中在A）或B）中获得多相体系，并且相应的羧酸铵由水不溶性胺和羧酸; C）去除水不溶性相; 和D）释放游离羧酸时加热水不溶性相。

6. 发明申请

US20110118504A1 THERMAL SALT SPLITTING OF AMMONIUM CARBOXYLATES 审中-公开
公开(公告)号：US20110118504A1
公开(公告)日：2011-05-19
申请号：US13054002
申请日：2009-05-27
申请人： Thomas Haas , Thomas Tacke , Alexander Schraven , Hans-Joachim Schleef , Oliver Zehnacker
发明人： Thomas Haas , Thomas Tacke , Alexander Schraven , Hans-Joachim Schleef , Oliver Zehnacker
IPC分类号： C07C51/347
CPC分类号： C07C51/02 , C07C59/01
摘要： The present invention relates to a process for preparing hydroxycarboxylic acids, preferably α- and β-hydroxycarboxylic acids, from ammonium carboxylates of the general formula in which R1, R2 and R3 are each independently H, OH, (C1-C6)-alkyl optionally substituted by a hydroxyl group, (C1-C6)-alkenyl optionally substituted by a hydroxyl group, (C1-C6)-alkoxy optionally substituted by a hydroxyl group, (C1-C6) -alkylthio-(C1-C6)-alkyl optionally substituted by a hydroxyl group, (C6-C10)-aryl optionally substituted by a hydroxyl group, (C7-C12)-aralkyl optionally substituted by a hydroxyl group, (C3-C5)-heteroaryl optionally substituted by a hydroxyl group, with the proviso that at least one hydroxyl group is present in at least one R1, R2 and R3 radical, preferably R1═H, CH3, CH2CH3, C6H5, (CH2)2SCH3 and R2═H, CH3 and R3═OH, equally preferably R1═CH2OH, CHOHCH3 and R2═R3═H, CH3, more preferably R1═R2═CH3 and R3═OH, equally more preferably R1═CH2OH, R2═CH3 and R3═H, comprising the following step: heating an aqueous starting solution comprising the ammonium carboxylate to form, by thermal decomposition of the ammonium carboxylate, the hydroxycarboxylic acid and ammonia, and simultaneously to remove at least a portion of the free water and of the ammonia formed from the solution and thus to obtain a product fraction comprising the hydroxycarboxylic acid, characterized in that the content of the ammonium salt in the starting solution is less than 60% by weight, the thermal decomposition of the ammonium salt and the removal of the free water and of the ammonia formed are effected in one process step, the conversion of the ammonium salt being more than 20 mol %, preferably more than 30 mol %, more preferably more than 50 mol %, especially preferably more than 75 mol %, very especially preferably more than 90 mol % and especially more than 95 mol %, and no ether, alcohol or hydrocarbon is used as an entraining agent.

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