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1. 发明授权

US5145483A Substituted ortho-aminophenols, process for preparing them and their use for the oxidatin dyeing of keratinous fibres 失效
标题翻译：取代的羟基苯丙胺，其制备方法及其用于氧化皮肤染色剂的研究
公开(公告)号：US5145483A
公开(公告)日：1992-09-08
申请号：US427474
申请日：1989-10-27
申请人： Alex Junino , Herve Andrean , Gerard Lang
发明人： Alex Junino , Herve Andrean , Gerard Lang
IPC分类号： A61K8/00 , A61K8/22 , A61K8/33 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/49 , A61Q5/10 , C07C231/12 , C07C233/43 , C07C233/44 , C07C271/28 , C07C271/58 , C09B53/00 , D06P3/08
CPC分类号： A61K8/42 , A61Q5/10 , C07C233/43 , C07C233/44 , C07C271/28
摘要： 5-Substituted ortho-aminophenols of formula: ##STR1## in which: R.sub.1 denotes a hydrogen atom, an alkyl radical having 1 to 4 carbon atoms or a hydroxyalkyl radical having 1 to 4 carbon atoms; andR.sub.2 denotes, independently of R.sub.1, an alkyl radical having 1 to 4 carbon atoms, an alkoxy radical having 1 to 4 carbon atoms or a benzyl radical;the addition salts with an acid and the phenates, anddyeing composition containing a compound of formula (I) or a salt or a phenate of such a compound.The 5-substituted ortho-aminophenols enable hair to be dyed in a rich spectrum of hues having good durability.
摘要翻译： 5-取代的下式：其中：R 1表示氢原子，具有1至4个碳原子的烷基或具有1至4个碳原子的羟烷基; 并且R 2表示与R 1独立地为具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基或苄基; 与酸和酚盐的加成盐，以及含有式（I）化合物或这种化合物的盐或酚盐的染色组合物。 5-取代的邻氨基苯酚使毛发能够在具有良好耐久性的色调丰富的色调中染色。

2. 发明授权

US4692166A Use of halogenated 4,5-methylenedioxyphenol in the dyeing of keratinous fibres 失效
标题翻译：卤代4,5-亚甲二氧基苯酚在角质纤维染色中的应用
公开(公告)号：US4692166A
公开(公告)日：1987-09-08
申请号：US841813
申请日：1986-03-20
申请人： Alex Junino , Gerard Lang , Herve Andrean , Jean Cotteret
发明人： Alex Junino , Gerard Lang , Herve Andrean , Jean Cotteret
IPC分类号： A61K8/00 , A61K8/33 , A61K8/34 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/73 , A61Q5/10 , C07D317/48 , C07D317/52 , C07D317/54 , D06P1/32 , D06P1/64 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/4973
摘要： Use for dyeing keratinous fibres, and especially human hair, on a compound corresponding to the formula: ##STR1## in which X denotes a bromine or chlorine atom.
摘要翻译：用于将角质纤维特别是人发染色在对应于下式的化合物：其中X表示溴或氯原子。

3. 发明授权

US5202487A 2-substituted para-aminophenols and their use for dyeing keratinous fibres 失效
标题翻译： 2-取代对氨基苯酚及其用于染色角质纤维的用途
公开(公告)号：US5202487A
公开(公告)日：1993-04-13
申请号：US933583
申请日：1992-08-24
申请人： Alex Junino , Gerard Lang , Alain Genet
发明人： Alex Junino , Gerard Lang , Alain Genet
IPC分类号： C07C217/76 , C07C323/29
CPC分类号： A61K8/415 , A61Q5/10 , C07C217/76 , C07C323/29
摘要： 2-Substituted para-aminophenols of general formula: ##STR1## where Y denotes oxygen or sulphur and R denotes a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl or C.sub.1 -C.sub.6 haloalkyl or a C.sub.2 -C.sub.6 polyhydroxyalkyl, provided that when Y=O, R is not methyl or ethyl and when Y=S, R is not ethyl; anddye composition containing one or more compounds of formula (I) where Y denotes an oxygen or sulphur atom and R is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.2 -C.sub.6 polyhydroxyalkyl.
摘要翻译： 2-取代的具有下式的对氨基苯酚：其中Y表示氧或硫，R表示C 1 -C 6烷基，C 1 -C 6羟基烷基或C 1 -C 6卤代烷基或C 2 -C 6多羟基烷基， Y = O，R不是甲基或乙基，当Y = S时，R不是乙基; 和含有一种或多种式（I）的化合物的染料组合物，其中Y表示氧或硫原子，R是C 1 -C 6烷基，C 1 -C 6羟基烷基，C 1 -C 6卤代烷基或C 2 -C 6多羟基烷基。

4. 发明授权

US5053052A 2-substituted para-aminophenols and their use for dyeing keratinous fibres 失效
标题翻译： 2-取代的对氨基苯酚及其用于染色卡介苗的用途
公开(公告)号：US5053052A
公开(公告)日：1991-10-01
申请号：US633190
申请日：1990-12-28
申请人： Alex Junino , Gerard Lang , Alain Genet
发明人： Alex Junino , Gerard Lang , Alain Genet
IPC分类号： A61K8/00 , A61K8/33 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C217/76 , C07C217/84 , C07C321/06 , C07C323/29 , C09B53/00 , C09B57/00 , C09B67/42 , D06P3/08
CPC分类号： A61K8/415 , A61Q5/10 , C07C217/76 , C07C323/29
摘要： 2-Substituted para-aminophenols of general formula: ##STR1## where Y denotes oxygen or sulphur and R denotes a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl or C.sub.1 -C.sub.6 haloalkyl or a C.sub.2 -C.sub.6 polyhydroxyalkyl, provided that when Y=O, R is not methyl or ethyl and when Y=S, R is not ethyl; and dye composition containing one or more compounds of formula (I) where Y denotes an oxygen or sulphur atom and R is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.2 -C.sub.6 polyhydroxyalkyl.
摘要翻译： 2-取代的具有下式的对氨基苯酚：其中Y表示氧或硫，R表示C 1 -C 6烷基，C 1 -C 6羟基烷基或C 1 -C 6卤代烷基或C 2 -C 6多羟基烷基， Y = O，R不是甲基或乙基，当Y = S时，R不是乙基; 和含有一种或多种式（I）的化合物的染料组合物，其中Y表示氧或硫原子，R是C 1 -C 6烷基，C 1 -C 6羟基烷基，C 1 -C 6卤代烷基或C 2 -C 6多羟基烷基。

5. 发明授权

US5002585A Trialkoxy-substituted meta-phenylenediamines, a process for their preparation, and their use as couplers for the oxidation dyeing of keratinous fibres and in particular of human hair 失效
标题翻译：三烷氧基取代的间苯二胺，其制备方法，以及它们作为角质纤维，特别是人发的氧化染色的成色剂的用途
公开(公告)号：US5002585A
公开(公告)日：1991-03-26
申请号：US439673
申请日：1989-11-22
申请人： Alex Junino , Jean J. Vandenbossche , Herve Borowiak , Gerard Lang
发明人： Alex Junino , Jean J. Vandenbossche , Herve Borowiak , Gerard Lang
IPC分类号： B01J23/44 , A61K8/00 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , B01J23/745 , C07B61/00 , C07C209/10 , C07C209/36 , C07C211/52 , C07C213/02 , C07C217/84
CPC分类号： A61K8/411 , A61Q5/10 , C07C217/84
摘要： Trialkoxy-substituted meta-phenylenediamines, a process for their preparation, and their use as couplers for oxidation dying of keratinous fibres and in particulate of human hair.1,3,5-trialkoxy-meta-phenylenediamine of formula: ##STR1## in which: R.sub.1 and R.sub.2 denote, independently of each other, a hydrogen atom, an alkyl radical containing 1 to 4 carbon atoms or a mono- or polyhydroxyalkyl radical containing 2 or 3 carbon atoms,Z denotes an alkyl radical containing from 1 to 4 carbon atoms, provided that, when R.sub.1 and R.sub.2 simultaneously denote a hydrogen atom, Z does not denote the methyl radical, and the addition salts of this compound with an acid.Process for the preparation of these compounds and their use as coupler in oxidation dying compositions for hair.
摘要翻译：三烷氧基取代的间苯二胺，它们的制备方法，以及它们作为角质纤维氧化染色和人类头发颗粒的成色剂的用途。式（I）的1,3,5-三烷氧基 - 间苯二胺，其中：R 1和R 2彼此独立地表示氢原子，含有1至4个碳原子的烷基或单 - 或含有2或3个碳原子的多羟基烷基，Z表示含有1至4个碳原子的烷基，条件是当R 1和R 2同时表示氢原子时，Z不表示甲基，并且这些的加成盐与酸混合。用于制备这些化合物的方法及其作为头发氧化染色组合物中偶联剂的用途。

6. 发明授权

US4979961A p-phenylenediamines, process for preparation thereof, dyeing composition containing them and corresponding dyeing process 失效
标题翻译：对苯二胺，其制备方法，含有它们的染色组合物和相应的染色方法
公开(公告)号：US4979961A
公开(公告)日：1990-12-25
申请号：US342578
申请日：1989-04-24
申请人： Alex Junino , Alain Genet , Gerard Lang
发明人： Alex Junino , Alain Genet , Gerard Lang
IPC分类号： A61K8/00 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C319/20 , C07C323/25 , C09B53/00 , D06P3/08
CPC分类号： A61Q5/10 , A61K8/411 , C07C323/25
摘要： The invention relates to p-phenylenediamines of formula: ##STR1## in which R.sub.1 denotes an alkyl, hydroxyalkyl or polyhydroxyalkyl radical and R.sub.2 denotes a hydrogen atom or an alkyl radical, as well as the corresponding salts with acids, and to the compositions and the process for dyeing keratinous fibers, especially hair, employing them.
摘要翻译：本发明涉及下式的对苯二胺：其中R 1表示烷基，羟烷基或多羟基烷基，R 2表示氢原子或烷基，以及与酸的相应盐，组合物和用于染色角质纤维，特别是头发的方法。

7. 发明授权

US4888445A New 2,4-dinitro- or 2-amino-4-nitro- or 2-nitro-4-amino-6-hydroxyalkylanilines, the process for preparation thereof and their use in dyeing keratinous fibres, and especially human hair 失效
标题翻译：新的2,4-二硝基或2-氨基-4-硝基 - 或2-硝基-4-氨基-6-羟基烷基苯胺，其制备方法及其在染色角质纤维，特别是人类头发中的用途
公开(公告)号：US4888445A
公开(公告)日：1989-12-19
申请号：US119083
申请日：1987-11-10
申请人： Alex Junino , Gerard Lang , Nicole Jehanno
发明人： Alex Junino , Gerard Lang , Nicole Jehanno
IPC分类号： A61K8/41 , A61Q5/06 , A61Q5/10 , C07C215/68 , C09B51/00
CPC分类号： A61K8/418 , A61Q5/065 , A61Q5/10
摘要： The invention relates to a compound of formula ##STR1## in which: X denotes a branched or unbranched alkylene radical containing 2 to 6 carbon atoms, optionally being able to be substituted with one or more hydroxyl radicals;R denotes a hydrogen atom, an alkyl or a mono- or polyhydroxyalkyl radical or an aminoalkyl radical in which the amine group can be mono- or disubstituted with an alkyl radical or with a mono- or polyhydroxyalkyl radical, the nitrogen atom also being able to form part of a heterocyclic system and the alkyl radicals containing 1 to 4 carbon atoms;R' denotes a hydrogen atom or a C.sub.1 to C.sub.4 alkyl radical;Y and Z denote a nitro and/or --NHR.sub.1 radical, R.sub.1 and R, which may be identical or different, having the meanings given above for R, with the proviso that when Y and Z are identical, they necessarily denote nitro radicals,and the cosmetically acceptable salts of the compounds containing a salifiable amine group, and also the process for preparing it and its use in dyeing keratinous fibres, and especially human hair.
摘要翻译：本发明涉及式（I）的化合物，其中：X表示含有2至6个碳原子的支链或非支链亚烷基，任选地可被一个或多个羟基取代; R表示氢原子，烷基或单羟基或多羟基烷基或氨基烷基，其中胺基可以被烷基或与单羟基或多羟基烷基单体或二取代，氮原子也可以形成杂环体系的一部分和含有1至4个碳原子的烷基; R'表示氢原子或C1〜C4烷基; Y和Z表示硝基和/或-NHR 1基团，R 1和R可以相同或不同，具有上面对R给出的含义，条件是当Y和Z相同时，它们必须表示硝基，并且含有可成胺基团的化合物的化妆品可接受的盐，以及其制备方法及其在染色角质纤维，特别是人类头发中的用途。

8. 发明授权

US4865618A New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said 失效
标题翻译：新的氯代间苯二胺，它们用作角质纤维的氧化染色中的成色剂，含有这些化合物的头发的染色组合物和使用所述
公开(公告)号：US4865618A
公开(公告)日：1989-09-12
申请号：US200399
申请日：1988-05-31
申请人： Alex Junino , Jean J. Vandenbossche , Herve Borowiak , Gerard Lang
发明人： Alex Junino , Jean J. Vandenbossche , Herve Borowiak , Gerard Lang
IPC分类号： A61K8/00 , A61K20060101 , A61K8/41 , A61Q5/10 , C07C20060101 , C07C215/20 , C07C217/84 , C09B53/02 , D06P1/32 , D06P3/04 , D06P3/14
CPC分类号： A61K8/411 , A61Q5/10
摘要： New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said compositions.The invention relates to the compounds of formula: ##STR1## in which Z and Z' denote, independently of one another, an alkyl radical having from 1 to 4 carbon atoms or a hydroxyalkyl radical having from 2 to 4 carbon atoms, andR.sub.1 and R.sub.2 denote, independently of one another, a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms or a mono- or polyhydroxyalkyl radical having 2 or 3 carbon atoms, to their addition salts with an acid, and to their use by way of couplers for the oxidation dyeing of keratinous fibres, especially human hair.These compounds, when they are combined with paraphenylenediamines, surprisingly give beige to light brown hues or purple hues of greater or lesser redness, depending on the substitution of the 5-amino group of the chlorobenzene.
摘要翻译：新的氯代间苯二胺，它们用作角质纤维的氧化染色中的成色剂，含有这些化合物的头发的染色组合物和使用所述组合物的染色方法。本发明涉及下式的化合物：其中Z和Z'彼此独立地表示具有1至4个碳原子的烷基或具有2至4个碳原子的羟烷基，并且R 1和R 2彼此独立地表示氢原子，具有1至4个碳原子的烷基或具有2或3个碳原子的单羟基或多羟基烷基，与它们与酸的加成盐，以及它们通过成色剂用于角质纤维，特别是人类头发的氧化染色。这些化合物当与对苯二胺结合时，令人惊讶的是，由于取代氯苯的5-氨基，令人惊讶的是，它使浅棕色色调或更多或更少发红的紫色色调发亮。

9. 发明授权

US5503640A 3-substituted para-aminophenols, process for preparing them, their use for dyeing keratinous fibres and the intermediate compounds used in the preparation process 失效
标题翻译： 3-取代对氨基苯酚，其制备方法，用于染色角质纤维的用途和制备过程中使用的中间体化合物
公开(公告)号：US5503640A
公开(公告)日：1996-04-02
申请号：US249923
申请日：1994-05-26
申请人： Alex Junino , Alain Genet , Gerard Lang
发明人： Alex Junino , Alain Genet , Gerard Lang
IPC分类号： A61K8/00 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C205/37 , C07C217/26 , C07C217/84 , C07C323/36 , D06P3/00 , A61K7/13 , C07C211/00
CPC分类号： A61K8/415 , A61Q5/10 , C07C205/37 , C07C217/84 , C07C323/36
摘要： 3-Substituted para-aminophenols of general formula: ##STR1## where X=H, halogen; Y=O--, --S--; R=alkyl, hydroxyalkyl, C.sub.1-4 aminoalkyl or C.sub.3 -C.sub.6 polyhydroxyalkyl;with the proviso that, when X=H, R is not methyl, and when X=H and Y=O, R is not ethyl;process for preparing them, intermediate compounds of formula: ##STR2## where X.sub.1 =halogen, Y and R have the meaning stated above; with the proviso that, when Y=O, R is not methyl, and when R=aminoalkyl, X.sub.1 can also denote hydrogen;dyeing compositions containing one or more compounds of formula (I), and a process For dyeing human hair.
摘要翻译： 3-取代的对位氨基苯酚，其通式如下：其中X = H，卤素; Y = O-，-S-; R =烷基，羟基烷基，C 1-4氨基烷基或C 3 -C 6多羟基烷基; 条件是当X = H时，R不是甲基，当X = H且Y = O时，R不是乙基; 制备它们的方法，式中的中间体化合物：其中X1 =卤素，Y和R具有上述含义; 条件是当Y = O时，R不是甲基，当R =氨基烷基时，X1也可以表示氢; 含有一种或多种式（I）化合物的染色组合物和用于染色人发的方法。

10. 再颁专利

USRE34300E Chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said compositions 失效
公开(公告)号：USRE34300E
公开(公告)日：1993-07-06
申请号：US566109
申请日：1990-08-13
申请人： Alex Junino , Jean J. Vandenbossche , Herve Borowiak , Gerard Lang
发明人： Alex Junino , Jean J. Vandenbossche , Herve Borowiak , Gerard Lang
IPC分类号： A61K8/00 , A61K20060101 , A61K8/41 , A61Q5/10 , C07C20060101 , C07C215/20 , C07C217/84 , C09B53/02 , D06P1/32 , D06P3/04 , D06P3/14
CPC分类号： A61K8/411 , A61Q5/10
摘要： New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said compositions.The invention relates to the compounds of formula: ##STR1## in which Z and Z' denote, independently of one another, an alkyl radical having from 1 to 4 carbon atoms or a hydroxyalkyl radical having from 2 to 4 carbon atoms, andR.sub.1 and R.sub.2 denote, independently of one another, a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms or a mono- or polyhydroxyalkyl radical having 2 or 3 carbon atoms, to their addition salts with an acid, and to their use by way of couplers for the oxidation dyeing of keratinous fibres, especially human hair.These compounds, when they are combined with paraphenylenediamines, surprisingly give beige to light brown hues or purple hues of greater of lesser redness, depending on the substitution of the 5-amino group of the chlorobenzene.

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