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1. 发明授权

US6114420A Triazine derivatives containing 2,2,6,6-tetramethyl-4-piperidyl groups 失效
标题翻译：含有2,2,6,6-四甲基-4-哌啶基的三嗪衍生物
公开(公告)号：US6114420A
公开(公告)日：2000-09-05
申请号：US84681
申请日：1998-05-26
申请人： Alessandro Zedda , Gianluca Ferri
发明人： Alessandro Zedda , Gianluca Ferri
IPC分类号： C07D401/14 , C08K5/3492 , C08K5/3435
CPC分类号： C07D401/14
摘要： A compound of the formula (I) ##STR1## wherein n is an integer from 1 to 4; the radicals R.sub.1 are for example a group of the formula ##STR2## R.sub.3 is for example hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.5 -C.sub.12 cycloalkoxy; Z and R.sub.2 are for example a group ##STR3## the radicals A and E are, for example, independently of one another --N(R.sub.11)(R.sub.12) or a group of the formula ##STR4## R.sub.11 and R.sub.12 are for example C.sub.1 -C.sub.12 alkyl; R.sub.13 has for example one of the meanings given for R.sub.3 ; E* has for example one of the meanings given for A or is a group of the formula ##STR5## The compounds of the formula (I) are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers such as polyolefins.
摘要翻译：式（I）的化合物，其中n为1至4的整数; 基团R 1是例如式R 3的基团是例如氢，C 1 -C 8烷基或C 5 -C 12环烷氧基; Z和R 2是例如基团A和E例如彼此独立的基团-N（R 11）（R 12）或式R 11和R 12的基团是例如C 1 -C 12烷基; R13具有例如R3给出的含义之一; E *具有例如A给出的含义之一或者是一组式。式（I）的化合物可用作有机材料的光稳定剂，热稳定剂和氧化稳定剂，特别是合成聚合物如聚烯烃。

2. 发明授权

US06677451B2 Preparation of sterically hindered amine ethers 有权
标题翻译：空间位阻胺醚的制备
公开(公告)号：US06677451B2
公开(公告)日：2004-01-13
申请号：US09996400
申请日：2001-11-20
申请人： Alessandro Zedda , Gianluca Ferri , Massimiliano Sala
发明人： Alessandro Zedda , Gianluca Ferri , Massimiliano Sala
IPC分类号： C08K535
CPC分类号： C07D401/14 , C07D211/94 , C08K5/3435 , C08K5/34926 , C09K15/30
摘要： A new process is described for the preparation of a compound of the formula I wherein R1, R2, R3 and R4, independently of each other, are C1-C8alkyl or C1-C5hydroxyalkyl, or R1 and R2 together with the carbon atom they are attached to are C5-C12cycloalkyl, or R3 and R4 together with the carbon atom they are attached to are C5-C12cycloalkyl; R5, R6, R7, R8 and R9, independently of each other, are H, C1-C8alkyl, C2-C8alkenyl, C5-C12aryl, C1-C4haloalkyl, an electron withdrawing group, or C6-C12aryl which is substituted by a residue selected from C1-C4alkyl, C1-C4alkoxy, halogen; and R7 and R8 together may also form a chemical bond; and R is an organic linking group containing 2-500 carbon atoms and forming, together with the carbon atoms it is directly connected to and the nitrogen atom, a substituted, 5-, 6 or 7-membered cyclic ring structure; characterized in that a compound of the formula II is oxidized. The compound of the formula I can be hydrogenated and/or halogenated by conventional methods. Compounds of the formula I and the corresponding hydrogenated and/or halogenated compounds are well suitable as stabilizers for organic material against degradation by light, oxygen and/or heat or yellowing; some are also active as flame retardants.
摘要翻译：描述了制备式I化合物的新方法，其中R 1，R 2，R 3和R 4彼此独立地为C 1 -C 8烷基或C 1 -C 5羟烷基，或者R 1和R 2与它们所连接的碳原子一起是 C5-C12环烷基或R3和R4与它们所连接的碳原子一起为C5-C12环烷基; R5，R6，R7，R8和R9彼此独立地为H，C1-C8烷基，C2-C8链烯基，C5- C 12芳基，C 1 -C 4卤代烷基，吸电子基团或被选自C 1 -C 4烷基，C 1 -C 4烷氧基，卤素的残基取代的C 6 -C 12芳基; 并且R7和R8一起也可以形成化学键; 并且R是含有2-500个碳原子的有机连接基团，并且与碳原子一起直接连接到氮原子上，形成取代的5，6或7元环环结构; 其特征在于式II的化合物被氧化。式I的化合物可以通过常规方法氢化和/或卤化。式I和相应的氢化和/或卤代化合物的化合物非常适合用作有机材料的稳定剂，以防止光，氧和/或热的降解，发黄一些也作为阻燃剂起作用。

3. 发明授权

US06420462B1 Preparation of sterically hindered amine ethers 有权
标题翻译：空间位阻胺醚的制备
公开(公告)号：US06420462B1
公开(公告)日：2002-07-16
申请号：US09594273
申请日：2000-06-15
申请人： Alessandro Zedda , Gianluca Ferri , Massimiliano Sala
发明人： Alessandro Zedda , Gianluca Ferri , Massimiliano Sala
IPC分类号： C08K535
CPC分类号： C07D401/14 , C07D211/94 , C08K5/3435 , C08K5/34926 , C09K15/30
摘要： A new process is described for the preparation of a compound of the formula I wherein R1, R2, R3 and R4, independently of each other, are C1-C8alkyl or C1-C5hydroxyalkyl, or R1 and R2 together with the carbon atom they are attached to are C5-C12cycloalkyl or R3 and R4 together with the carbon atom they are attached to are C5-C12cycloalkyl; R5, R6, R7, R8 and R9, independently of each other, are H, C1-C8alkyl, C2-C8alkenyl, C5-C12aryl, C1-C4haloalkyl, an electron withdrawing group, or C1-C12aryl which is substituted by a residue selected from C1-C4alkyl, C1-C4alkoxy, halogen; and R7 and R8 together may also form a chemical bond; and R is an organic linking group containing 2-500 carbon atoms and forming, together with the carbon atoms it is directly connected to and the nitrogen atom, a substituted, 5-, 6 or 7-membered cyclic ring structure; characterized in that a compound of the formula II is oxidized. The compound of the formula I can be hydrogenated and/or halogenated by conventional methods. Compounds of the formula I and the corresponding hydrogenated and/or halogenated compounds are well suitable as stabilizers for organic material against degradation by light, oxygen and/or heat or yellowing; some are also active as flame retardants.
摘要翻译：描述了制备式I化合物的新方法，其中R 1，R 2，R 3和R 4彼此独立地为C 1 -C 8烷基或C 1 -C 5羟烷基，或者R 1和R 2与它们所连接的碳原子一起是 C5-C12环烷基或R3和R4与它们所连接的碳原子一起为C 5 -C 12环烷基; R 5，R 6，R 7，R 8和R 9彼此独立地为H，C 1 -C 8烷基，C 2 -C 8烯基，C 5 -C 12芳基，C 1 -C 4卤代烷基，吸电子基团或被选自C 1 -C 4烷基，C 1 -C 4烷氧基，卤素的残基取代的C 1 -C 12芳基; 并且R7和R8一起也可以形成化学键; 并且R是含有2-500个碳原子的有机连接基团，并且与碳原子一起直接连接到氮原子上，形成取代的5，6或7元环环结构; 其特征在于式II的化合物被氧化。式I的化合物可以通过常规方法氢化和/或卤化。式I和相应的氢化和/或卤代化合物的化合物非常适合用作有机材料的稳定剂，以防止光，氧和/或热的降解，发黄一些也作为阻燃剂起作用。

4. 发明授权

US6117995A Preparation of sterically hindered amine ethers 有权
标题翻译：空间位阻胺醚的制备
公开(公告)号：US6117995A
公开(公告)日：2000-09-12
申请号：US253161
申请日：1999-02-19
申请人： Alessandro Zedda , Gianluca Ferri , Massimiliano Sala
发明人： Alessandro Zedda , Gianluca Ferri , Massimiliano Sala
IPC分类号： C07D211/94 , C07D401/14 , C08G73/06 , C08K5/3435 , C08K5/3492 , C08L23/06 , C08L23/12 , C09D133/06 , C09D167/00 , C09K15/30 , C07D403/00 , C07D211/36 , C07D237/00 , C07D241/02 , C08L5/48
CPC分类号： C07D401/14 , C07D211/94 , C08K5/3435 , C08K5/34926 , C09K15/30
摘要： A new process is described for the preparation of a compound of the formula I ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of each other, are C.sub.1 -C.sub.8 alkyl or C.sub.1 -C.sub.5 hydroxyalkyl, or R.sub.1 and R.sub.2 together with the carbon atom they are attached to are C.sub.5 -C.sub.2 cycloalkyl, or R.sub.3 and R.sub.4 together with the carbon atom they are attached to are C.sub.5 -C.sub.12 cycloalkyl; R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9, independently of each other, are H, C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.8 alkenyl, C.sub.5 -C.sub.12 aryl, C.sub.1 -C.sub.4 haloalkyl, an electron withdrawing group, or C.sub.6 -C.sub.12 aryl which is substituted by a residue selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen; and R.sub.7 and R.sub.8 together may also form a chemical bond; and R is an organic linking group containing 2-500 carbon atoms and forming, together with the carbon atoms it is directly connected to and the nitrogen atom, a substituted, 5-, 6 or 7-membered cyclic ring structure; characterized in that a compound of the formula II ##STR2## is oxidized. The compound of the formula I can be hydrogenated and/or halogenated by conventional methods.Compounds of the formula I and the corresponding hydrogenated and/or halogenated compounds are well suitable as stabilizers for organic material against degradation by light, oxygen and/or heat or yellowing; some are also active as flame retardants.
摘要翻译：描述了制备式I化合物的新方法，其中R 1，R 2，R 3和R 4彼此独立地为C 1 -C 8烷基或C 1 -C 5羟烷基，或者R 1和R 2与它们所连接的碳原子一起为C5-C2环烷基，或R3和R4与它们连接的碳原子一起为C5-C12环烷基; R 5，R 6，R 7，R 8和R 9彼此独立地为H，C 1 -C 8烷基，C 2 -C 8烯基，C 5 -C 12芳基，C 1 -C 4卤代烷基，吸电子基团或被选定的残基取代的C 6 -C 12芳基 C 1 -C 4烷基，C 1 -C 4烷氧基，卤素; 并且R7和R8一起也可以形成化学键; 并且R是含有2-500个碳原子的有机连接基团，并且与碳原子一起直接连接到氮原子上，形成取代的5，6或7元环环结构; 其特征在于式II化合物被氧化。式I的化合物可以通过常规方法氢化和/或卤化。式I化合物和相应的氢化和/或卤代化合物非常适合作为有机材料的稳定剂，防止光，氧和/或热或黄化降解; 一些也作为阻燃剂起作用。

5. 发明授权

US07034069B2 High molecular weight hydroxyphenylbenzotriazole uv-absorbers for thin film applications 失效
标题翻译：用于薄膜应用的高分子量羟基苯基苯并三唑紫外线吸收剂
公开(公告)号：US07034069B2
公开(公告)日：2006-04-25
申请号：US10482522
申请日：2002-06-24
申请人： Dario Lazzari , Gianluca Ferri , Massimiliano Sala , Michela Bonora , Manuele Vitali
发明人： Dario Lazzari , Gianluca Ferri , Massimiliano Sala , Michela Bonora , Manuele Vitali
IPC分类号： C08K5/3492 , C08K5/34 , C09K15/30 , A61J1/10 , C07D251/50
CPC分类号： C07D403/14 , A23L3/3436 , A61K8/4966 , A61Q17/04 , C07D403/12 , C08K5/34926 , C09K15/30
摘要： The present invention relates to highly compatible, high molecular weight hydroxyphenylbenzotriazole UV-absorbers and for their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible, high molecular weight hydroxyphenylbenzotriazole UV-absorbers are especially effective towards this end when incorporated in the containers or films in which such materials are stored.
摘要翻译：本发明涉及高度相容的高分子量羟基苯基苯并三唑紫外线吸收剂，并且用于保护温室中的植物和保护食品，饮料，药物，化妆品，个人护理产品，洗发剂等免受有害影响紫外线辐射。已经发现，某些高度相容性的高分子量羟基苯基苯并三唑UV吸收剂在结合到容纳这些材料的容器或薄膜中时尤其有效。

6. 发明授权

US07638626B2 Highly compatible hydroxyphenyltriazine UV-absorbers 失效
标题翻译：高度相容的羟基苯基三嗪紫外线吸收剂
公开(公告)号：US07638626B2
公开(公告)日：2009-12-29
申请号：US11904511
申请日：2007-09-27
申请人： Dario Lazzari , David George Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
发明人： Dario Lazzari , David George Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
IPC分类号： C07D251/24 , C08K5/3467
CPC分类号： C08K5/3492 , C07D251/24 , C08F8/30 , Y10T428/1352
摘要： The present invention relates to highly compatible hydroxyphenyltriazine UV-absorbers and to their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible tris-aryl-s-triazines are especially effective towards this end when incorporated in the containers or films in which such materials are stored.
摘要翻译：本发明涉及高度相容的羟基苯基三嗪紫外线吸收剂及其在保护温室中植物和保护食品，饮料，药物，化妆品，个人护理产品，洗发剂等方面的用途，从紫外线辐射的有害作用。已经发现，某些高度相容的三 - 芳基-s-三嗪在结合到其中存储这些材料的容器或薄膜中时特别有效。

7. 发明授权

US07294714B2 Highly compatible hydroxyphenyltriazine UV-absorbers 失效
标题翻译：高度相容的羟基苯基三嗪紫外线吸收剂
公开(公告)号：US07294714B2
公开(公告)日：2007-11-13
申请号：US11525267
申请日：2006-09-22
申请人： Dario Lazzari , David George Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
发明人： Dario Lazzari , David George Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
IPC分类号： C07D251/24 , C08K5/3467
CPC分类号： C08K5/3492 , C07D251/24 , C08F8/30 , Y10T428/1352
摘要： The present invention relates to highly compatible hydroxyphenyltriazine UV-absorbers and to their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible tris-aryl-s-triazines are especially effective towards this end when incorporated in the containers or films in which such materials are stored.
摘要翻译：本发明涉及高度相容的羟基苯基三嗪紫外线吸收剂及其在保护温室中植物和保护食品，饮料，药物，化妆品，个人护理产品，洗发剂等方面的用途，从紫外线辐射的有害作用。已经发现，某些高度相容的三 - 芳基-s-三嗪在结合到其中存储这些材料的容器或薄膜中时特别有效。

8. 发明申请

US20070161726A1 Highly compatible hydroxyphenyltriazine UV-absorbers 失效
公开(公告)号：US20070161726A1
公开(公告)日：2007-07-12
申请号：US11525267
申请日：2006-09-22
申请人： Dario Lazzari , David Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
发明人： Dario Lazzari , David Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
IPC分类号： C08K5/34 , C07D253/00
CPC分类号： C08K5/3492 , C07D251/24 , C08F8/30 , Y10T428/1352
摘要： The present invention relates to highly compatible hydroxyphenyltriazine UV-absorbers and to their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible tris-aryl-s-triazines are especially effective towards this end when incorporated in the containers or films in which such materials are stored.

9. 发明申请

US20080032078A1 Highly compatible hydroxyphenyltriazine UV-absorbers 失效
标题翻译：高度相容的羟基苯基三嗪紫外线吸收剂
公开(公告)号：US20080032078A1
公开(公告)日：2008-02-07
申请号：US11904511
申请日：2007-09-27
申请人： Dario Lazzari , David Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
发明人： Dario Lazzari , David Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
IPC分类号： B32B1/02 , C07D251/14 , F21V9/06
CPC分类号： C08K5/3492 , C07D251/24 , C08F8/30 , Y10T428/1352
摘要： The present invention relates to highly compatible hydroxyphenyltriazine UV-absorbers and to their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible tris-aryl-s-triazines are especially effective towards this end when incorporated in the containers or films in which such materials are stored.
摘要翻译：本发明涉及高度相容的羟基苯基三嗪紫外线吸收剂及其在保护温室中植物和保护食品，饮料，药物，化妆品，个人护理产品，洗发剂等方面的用途，从紫外线辐射的有害作用。已经发现，某些高度相容的三 - 芳基-s-三嗪在结合到其中存储这些材料的容器或薄膜中时特别有效。

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