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    • 3. 发明授权
    • Continuous process for the manufacture of calcium magnesium acetate
deicer
    • 连续生产醋酸镁醋酸除冰机
    • US4606836A
    • 1986-08-19
    • US693664
    • 1985-01-22
    • Alan B. Gancy
    • Alan B. Gancy
    • C09K3/18
    • C09K3/185
    • Finely divided lime, at any degree of slaking, is introduced in a steady stream into an agitated reactor designed to produce pellets or aggregates. Concentrated acetic acid is simultaneously introduced in a steady stream at a rate equal to the chemical combining rate required to produce calcium magnesium acetate. Water content of the reaction stream is critical; the mol ratio of water, including water of neutralization, to the calcium magnesium acetate product must fall in the range 3.3-7.0 in order to form the desired pellets and to avoid sticking, caking, and dust emanation from the reactor. Product pellets are drawn off in a stream from the reactor and dried for use as a non-polluting roadway and walkway deicer. Traction agent is optionally incorporated into the deicer pellets by introducing a steady stream of traction agent to the reactor simultaneous with raw materials introduction. Magnesium-to-calcium ratios greater than one are achieved by blending dolime with magnesium-rich ore.
    • 将细碎的石灰以任何程度的去除均匀地引入设计成产生颗粒或聚集体的搅拌反应器中。 浓缩的乙酸以等于产生醋酸钙镁所需的化学组合速率的速率在稳定的流中同时引入。 反应物流的含水量至关重要; 包括中和水在内的水的摩尔比与乙酸钙镁产品的摩尔比必须落在3.3-7.0的范围内以形成所需的颗粒,并避免从反应器中粘附,结块和粉尘排出。 将产物颗粒从反应器中流出并干燥以用作无污染的道路和走道除冰剂。 通过在原料引入的同时引入稳定的牵引剂流到反应器,任选地将牵引剂并入除冰机颗粒中。 镁与钙的比例大于1是通过混合dolime与富镁矿石实现的。
    • 5. 发明授权
    • Magnesium calcium acetate products, and process for their manufacture
    • 醋酸镁产品及其制造工艺
    • US4699725A
    • 1987-10-13
    • US941171
    • 1986-12-12
    • Alan B. Gancy
    • Alan B. Gancy
    • C07C51/41C09K3/18C22B3/16
    • C22B3/165C07C51/412C09K3/185Y02P10/234
    • Finely divided ore blends containing chemically active magnesium oxide and calcium oxide are physically combined with a critical amount of water prior to reaction with acetic acid. Intermediate products range in physical consistency from putty-like masses to viscous liquors, depending upon the relative fraction of magnesium oxide in the ore feed. Intermediate products freeze to form hydrates of magnesium calcium acetate, the freeze times being dependent upon a number of chemical and physical parameters. Product drying requirements range from minimal drying to none at all, depending upon the magnesium fraction in the products. Products are non-friable and have excellent crush strength, and are suitable for storage, shipping and application in chemical deicing as well as other end use applications where crude low-cost materials are called for.A unique situation centers around the composition corresponding to the magnesium mol fraction of 0.8. This material requires no drying and exhibits an extraordinary high crush strength. Additionally, as much as 75% by weight of traction agent (sand) can be successfully incorporated into this material without the aid of chemical binders.
    • 在与乙酸反应之前,将含有化学活性氧化镁和氧化钙的细碎矿物混合物与临界量的水物理组合。 中间产品的物理稠度范围从腻子状物质到粘稠液体,这取决于矿石进料中氧化镁的相对分数。 中间产物冷冻形成醋酸镁的水合物,冷冻时间取决于许多化学和物理参数。 产品干燥要求从最小干燥到根本不变,取决于产品中的镁分数。 产品不易碎,具有优异的抗压强度,适用于化学除冰的储存,运输和应用以及其他需要粗制低成本材料的最终用途。 围绕与镁摩尔分数为0.8的组成相对应的独特情况。 该材料不需要干燥,表现出非凡的高抗压强度。 另外,不用化学粘合剂就可以将75%(重量)以上的牵引剂(沙子)成功地并入该材料中。
    • 6. 发明授权
    • Low-energy process for the manufacture of calcium/magnesium
acetate-chloride deicers and freezing point depressants
    • 用于制造钙/醋酸镁 - 氯化物除冰剂和凝固点抑制剂的低能量方法
    • US4673519A
    • 1987-06-16
    • US747579
    • 1985-06-24
    • Alan B. Gancy
    • Alan B. Gancy
    • C07C53/10C07C51/00C07C51/41C07C67/00C09K3/18
    • C09K3/185
    • Several novel means are presented of chemically combining calcium/magnesium acetate with calcium chloride to form a series of calcium magnesium acetate-chloride triple-salts. The low-cost processes are carried out using minimal proportions of water, and no co-products or by-products are formed. Products are optionally pelletized for use as roadway deicing agents. By adjusting the relative amount of chloride input, products can be tailored to adequately perform a given deicing or freezing-point depression task with a minimum of environmental pollution by chloride.All product variations are non-deliquescent.In the preferred embodiment, lime is reacted with concentrated acetic acid to form calcium/magnesium acetate. To the acetate is added an aqueous calcium chloride solution. The concentration of water in the reaction batch is critical to the attainment of complete chemical combination to form a flowable solid product.
    • 提出了几种新的方法,将钙/醋酸镁与氯化钙化学结合形成一系列的乙酸钙 - 氯化钙三盐。 低成本的方法是使用最少比例的水进行的,不会形成副产物或副产物。 产品可选择地被造粒用作道路除冰剂。 通过调整氯化物输入的相对量,产品可以通过氯化物的最小环境污染来适当地进行给定的除冰或凝固点抑制任务。 所有产品的变化都是非潮解性的。 在优选的实施方案中,将石灰与浓缩的乙酸反应以形成钙/醋酸镁。 向乙酸酯中加入氯化钙水溶液。 反应批料中的水浓度对于获得完全的化学组合来形成可流动的固体产品是至关重要的。
    • 7. 发明授权
    • Nonpolluting salts and method of making same
    • 非污染盐及其制备方法
    • US4511485A
    • 1985-04-16
    • US486853
    • 1983-04-20
    • Alan B. Gancy
    • Alan B. Gancy
    • C07C53/10C09K3/18C01F5/00C01F11/00C07C51/41
    • C09K3/185C07C53/10
    • A reduced pollutant-containing salt mixture and method of making same is provided wherein a salt mixture partially comprised of calcium acetate and partially comprised of at least one other pollutant salt is produced by mixing a pollutant salt-containing solution and a calcium acetate-containing solution and converting said mixture into a solid salt containing both the pollutant salt and the nonpollutant calcium acetate. A process option involves chemically reacting calcium chloride and calcium acetate in a calcium chloride-to-calcium acetate mole ratio in the range from 0 to 1 to produce a non-deliquescent salt. A further process option includes mixing either dry calcium chloride or dry sodium chloride with dry calcium acetate to obtain a reduced pollutant-containing salt mixture.
    • 提供减少的含污染物的盐混合物及其制备方法,其中通过混合含污染盐的溶液和含乙酸钙的溶液来制备部分由乙酸钙组成的部分由至少一种其它污染物盐组成的盐混合物 并将所述混合物转化成含有污染物盐和不污染的乙酸钙两者的固体盐。 一种方法包括以氯化钙与乙酸钙的摩尔比在0至1的范围内化学反应氯化钙和乙酸钙,以产生非潮解盐。 进一步的处理方法包括将干氯化钙或干氯化钠与干燥的乙酸钙混合以获得减少的含污染物的盐混合物。
    • 9. 发明授权
    • Novel road and highway deicer and traction agent, and process for its
manufacture
    • 新型道路和公路除冰机及牵引剂及其制造工艺
    • US4430242A
    • 1984-02-07
    • US404365
    • 1982-08-02
    • Alan B. Gancy
    • Alan B. Gancy
    • C09K3/18
    • C09K3/185
    • A process of reacting aqueous acetic acid and crushed raw limestone in such a way as to produce a mixture of calcium acetate, calcium acid-acetate, and unreacted raw limestone devoid of undesirable fine limestone. Such a product is useful in winter highway treatment, where the environmentally safe soluble acetates function to depress the freezing point of water, and the limestone acts as a roadway traction agent. When as much as 3 mols of acetic acid per mol of active calcium carbonate in limestone are used, all the limestone is consumed, with virtually 100% yield of calcium acid-acetate.
    • 使乙酸水溶液和破碎的原料石灰石以使乙酸钙,酸式醋酸钙和未反应的未经处理的石灰石混合物形成不合乎需要的细石灰石的混合物的方法。 这种产品在冬季高速公路处理中是有用的,其中环境安全的可溶性乙酸盐起到降低水的凝固点的作用,并且石灰石作为道路牵引剂。 当使用石灰石中每摩尔活性碳酸钙多达3摩尔的乙酸时,所有的石灰石被消耗,几乎100%的酸性醋酸钙的产率。
    • 10. 发明授权
    • Continuous cyclic process for alkylation of hydrocarbons
    • 烃的烷基化的连续循环过程
    • US4260846A
    • 1981-04-07
    • US47448
    • 1979-06-11
    • Bela I. KarsayRobert L. SturtevantAlan B. Gancy
    • Bela I. KarsayRobert L. SturtevantAlan B. Gancy
    • C07C2/54C07C2/62C07C2/58
    • C07C2/54C07C2/62C07C2527/054
    • An improved cyclic process for the alkylation of isoparaffins with olefins in the presence of a circulating concentrated sulfuric acid catalyst is disclosed. Improvement in the octane rating of the product alkylate is achieved by periodic fortification of the sulfuric acid catalyst with a sulfur trioxide-bearing fortifying agent under conditions wherein the harmful effects caused by contact of the sulfur trioxide with the hydrocarbons in the alkylation zone are minimized. The acid catalyst is fortified during less than about 15% of the cycles of the circulating acid catalyst through the alkylation system to maintain the water content of the acid catalyst in the range of above about 1% and below about 4% by weight. The process effects not only essentially 100% utilization of the fortifying agent for water removal but also improves the octane rating of the product alkylate while simultaneously extending the service life of the acid catalyst by allowing use of the catalyst having higher organic content.
    • 公开了一种用于在循环浓硫酸催化剂存在下用烯烃烷基化异链烷烃的改进的循环方法。 烷基化产物的辛烷值的改进是通过在三氧化硫与烷基化区的接触引起的有害影响最小化的条件下,用含三氧化硫的强化剂对硫酸催化剂进行周期性强化来实现的。 酸催化剂在小于循环酸催化剂通过烷基化系统的约15%的循环中被强化,以将酸催化剂的水含量保持在约1%和低于约4%重量的范围内。 该方法不仅实质上利用了除水强化剂的100%,还提高了烷基化产物的辛烷值,同时通过使用具有较高有机含量的催化剂延长了酸催化剂的使用寿命。