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1. 发明授权

US08333867B2 Method for bonding fibrous silicone-coated supports 失效
标题翻译：粘合有机硅涂层载体的方法
公开(公告)号：US08333867B2
公开(公告)日：2012-12-18
申请号：US10555700
申请日：2004-05-05
申请人： Alain Pouchelon , Maryline Quemin , Laurent Dumont , Francis Lafaysse
发明人： Alain Pouchelon , Maryline Quemin , Laurent Dumont , Francis Lafaysse
IPC分类号： C04B37/00
CPC分类号： C08J5/06 , B29C65/02 , B29C65/4835 , B29C65/5057 , B29C66/71 , B29C66/723 , B29C66/7292 , B29C66/73921 , B29C66/73941 , C08J2383/04 , C08L83/00 , C09J5/06 , C09J5/10 , C09J183/04 , C09J2400/263 , C09J2483/00 , B29C65/00 , B29K2083/00 , B29K2077/10 , B29K2077/00 , B29K2067/00 , B29K2033/08 , B29K2029/04 , B29K2027/12 , B29K2021/00 , B29K2001/00
摘要： The invention relates to a process for the adhesive bonding of fibrous supports using a silicone elastomer which is thermosetted by radical crosslinking using at least one peroxide. The silicone elastomer is inserted between the supports over at least a portion of the region of overlap of the supports, where the supports are held in contact in the region of overlap in an manner that prevents trapping of air at the interface between the supports. The supports containing the silicone elastomer are heated while in intimate contact to allow the adhesive bonding of the supports by crosslinking of the adhesive.
摘要翻译：本发明涉及一种使用硅氧烷弹性体粘合纤维载体的方法，其通过使用至少一种过氧化物的自由基交联而热固化。硅氧烷弹性体在支撑件的重叠区域的至少一部分之间插入在支撑件之间，其中支撑件在重叠的区域中以防止在支撑件之间的界面处捕获空气的方式保持接触。包含硅氧烷弹性体的载体在紧密接触的同时被加热，以通过交联粘合剂来粘合粘合载体。

2. 发明申请

US20070261790A1 Method for Bonding Fibrous Silicone-Coated Supports 失效
标题翻译：粘结纤维有机硅涂层载体的方法
公开(公告)号：US20070261790A1
公开(公告)日：2007-11-15
申请号：US10555700
申请日：2004-05-05
申请人： Alain Pouchelon , Maryline Quemin , Laurent Dumont , Francis Lafaysse
发明人： Alain Pouchelon , Maryline Quemin , Laurent Dumont , Francis Lafaysse
IPC分类号： C09J5/00
CPC分类号： C08J5/06 , B29C65/02 , B29C65/4835 , B29C65/5057 , B29C66/71 , B29C66/723 , B29C66/7292 , B29C66/73921 , B29C66/73941 , C08J2383/04 , C08L83/00 , C09J5/06 , C09J5/10 , C09J183/04 , C09J2400/263 , C09J2483/00 , B29C65/00 , B29K2083/00 , B29K2077/10 , B29K2077/00 , B29K2067/00 , B29K2033/08 , B29K2029/04 , B29K2027/12 , B29K2021/00 , B29K2001/00
摘要： The invention relates to the adhesive bonding of fibrous materials, in particular of flexible supports, such as woven supports or nonwoven supports, comprising at least one silicone coating obtained by the application of a coat or by impregnation. The aim of the invention is to provide an improved process for combining together fiber/silicone composite parts using a silicone elastomer, which process has to be economical and not very expensive to carry out. This aim is achieved by the invention, which relates to a process for the adhesive bonding of fibrous supports, this process being of the type of those consisting in causing the supports to be adhesively bonded to overlap one another, a silicone-based adhesive thermosetting by radical crosslinking using at least one peroxide being inserted between the supports over at least a portion of the region of overlap. The process is characterized in that it consists essentially in employing at least one silicone adhesive selected from Pumpable Silicone Elastomers (PSE) or Liquid Silicone Rubbers (LSR): e.g. MDDViM, comprising as filler silica treated with a silicone MOHDMOH, which are thermosetting by radical crosslinking using at least one peroxide, which are liquid at ambient temperature and which have a Brookfield viscosity η at 25° C.≧100 Pa·s and an extrusion rate Er in g.min−1≦−50; in directly forming and deploying this liquid adhesive on at least one of the supports to be adhesively bonded in their region of overlap; in holding the supports in intimate contact in their region of overlap comprising at least one layer of adhesive, so as to prevent any trapping of air at the interface; and in heating the supports thus held in intimate contact, so as to make possible the adhesive bonding of the supports by crosslinking of the adhesive.
摘要翻译：本发明涉及纤维材料的粘合剂，特别是柔性载体，例如纺织支撑体或非织造支撑物，其包括通过涂覆或浸渍获得的至少一种硅氧烷涂层。本发明的目的是提供一种使用硅氧烷弹性体将纤维/硅酮复合部件组合在一起的改进方法，该方法必须是经济的并且不是非常昂贵的。该目的通过本发明来实现，本发明涉及一种用于纤维支撑体的粘合剂的方法，该方法是这样一种方法，其包括使支撑体粘合地彼此重叠的那些类型，由硅基粘合剂热固化的硅氧烷基粘合剂自由基交联使用至少一种过氧化物在重叠区域的至少一部分上插入支撑体之间。该方法的特征在于其基本上使用至少一种选自可泵送硅酮弹性体（PSE）或液体硅橡胶（LSR）的硅氧烷粘合剂： M D D M M，其包含用硅氧烷M OH（OH）OH处理的填料二氧化硅，其通过使用至少一种过氧化物的自由基交联进行热固化，其在环境温度下是液体的，并且其在25℃下具有Brookfield粘度等级> = 100Pa.s，挤出速率Er（g.min）≤50; 在至少一个支撑体上直接形成和展开该液体粘合剂以在其重叠区域中粘合地结合; 在其包括至少一层粘合剂的重叠区域中保持紧密接触的支撑件，以防止在界面处的任何空气捕获; 并且加热由此保持紧密接触的支撑件，从而可以通过粘合剂的交联使支撑体粘合。

3. 发明授权

US07642331B2 Composition based on silicone oils that can be crosslinked into elastomers for the impregnation treatment of fibrous materials 失效
标题翻译：基于可以交联成弹性体以用于纤维材料的浸渍处理的硅油的组合物
公开(公告)号：US07642331B2
公开(公告)日：2010-01-05
申请号：US10522578
申请日：2003-07-16
申请人： Alain Pouchelon , Maryline Quemin , Francis Lafaysse
发明人： Alain Pouchelon , Maryline Quemin , Francis Lafaysse
IPC分类号： C08G77/06 , D06M15/19
CPC分类号： D06N3/128 , C09D183/04 , D06M15/643 , D06M15/693 , Y10T428/2915 , C08L83/00
摘要： A hydrosilylation (polyaddition)-vulcanizing elastomer silicone composition, including (a) a vinylated polyorganosiloxane (POS), (b) at least one hydrogenated POS, (c) a platinum catalyst, (d) optionally a coupling agent, (e) optionally a mineral filler, (f) optionally a crosslinking inhibitor, and optionally a POS resin and functional additives. The composition has a dynamic viscosity between 1,000 and 7,000 mPa·s, at 25° C. before crosslinking and, after overall crosslinking by thermal effect has at least one of the following properties: a Shore A hardness of at least 2, a breaking strength of at least 0.5 N·mm−1, and a breaking elongation of at least 50%. Also disclosed is a composite which is fully impregnated by means of a 100% bicomponent (RTV-2) silicone liquid.
摘要翻译：氢化硅烷化（加聚） - 硫化弹性体硅氧烷组合物，包括（a）乙烯基化聚有机硅氧烷（POS），（b）至少一种氢化POS，（c）铂催化剂，（d）任选的偶联剂，（e）矿物填料，（f）任选的交联抑制剂，以及任选的POS树脂和功能添加剂。组合物在交联前在25℃下具有1,000-7,000mPa.s的动态粘度，并且在通过热效应进行整体交联之后具有以下特性中的至少一种：肖氏A硬度至少为2，断裂强度至少0.5Nmm-1，断裂伸长率至少为50％。还公开了通过100％双组分（RTV-2）有机硅液体完全浸渍的复合材料。

4. 发明申请

US20060142523A1 Composition of crosslinkable elastomer silicone oils for treatment by impregnation of fibrous materials 失效
标题翻译：用于通过浸渍纤维材料处理的可交联弹性体硅油的组成
公开(公告)号：US20060142523A1
公开(公告)日：2006-06-29
申请号：US10522578
申请日：2003-07-16
申请人： Alain Pouchelon , Maryline Quemin , Francis Lafaysse
发明人： Alain Pouchelon , Maryline Quemin , Francis Lafaysse
IPC分类号： C08G77/06 , D06M15/19
CPC分类号： D06N3/128 , C09D183/04 , D06M15/643 , D06M15/693 , Y10T428/2915 , C08L83/00
摘要： A hydrosilylation (polyaddition)-vulcanizing elastomer silicone composition, including (a) a vinylated polyorganosiloxane (POS), (b) at least one hydrogenated POS, (c) a platinum catalyst, (d) optionally a coupling agent, (e) optionally a mineral filler, (f) optionally a crosslinking inhibitor, and optionally a POS resin and functional additives. The composition has a dynamic viscosity between 1,000 and 7,000 mPa·s, at 25° C. before crosslinking and, after overall crosslinking by thermal effect has at least one of the following properties: a Shore A hardness of at least 2, a breaking strength of at least 0.5 N·mm−1, and a breaking elongation of at least 50%. Also disclosed is a composite which is fully impregnated by means of a 100% bicomponent (RTV-2) silicone liquid.
摘要翻译：氢化硅烷化（加聚） - 硫化弹性体硅氧烷组合物，包括（a）乙烯基化聚有机硅氧烷（POS），（b）至少一种氢化POS，（c）铂催化剂，（d）任选的偶联剂，（e）矿物填料，（f）任选的交联抑制剂，以及任选的POS树脂和功能添加剂。组合物在交联前在25℃下具有1,000-7,000mPa.s的动态粘度，并且在通过热效应进行整体交联之后具有以下特性中的至少一种：肖氏A硬度至少为2，断裂强度为至少0.5N·mm -1，断裂伸长率为至少50％。还公开了通过100％双组分（RTV-2）有机硅液体完全浸渍的复合材料。

5. 发明申请

US20090264035A1 ANTI-FOULING POLYADDITION SILICONE VARNISH, APPLICATION OF THIS VARNISH TO A SUPPORT AND SUPPORT THUS TREATED 有权
标题翻译：防粘聚硅氧烷VARNISH，将本VARNISH应用于支持和支持THUSTED
公开(公告)号：US20090264035A1
公开(公告)日：2009-10-22
申请号：US12096781
申请日：2006-12-07
申请人： Alain Pouchelon , Maryline Quemin
发明人： Alain Pouchelon , Maryline Quemin
IPC分类号： B32B5/02 , B32B9/04 , B32B17/10 , C08L83/04 , B05D3/10
CPC分类号： D06N3/128 , C08L83/04 , C09D5/1675 , C09D183/04 , D06M15/643 , Y10T428/26 , Y10T428/31663 , Y10T442/20 , Y10T442/60 , C08L83/00
摘要： The invention relates to silicone compositions particularly useful for the production of anti-fouling varnishes that can be applied to flexible or bulk supports. The aim is to provide an anti-fouling silicone varnish for textiles coated with silicone elastomers which is economical, adhesive, non-slip and glossy. This aim is achieved by means of a crosslinkable silicone composition comprising: A—100 parts by weight of dry POS resin (A), preferably of formula MMViQ, B—35 to 150 parts by weight of POS (B), preferably of formula (MH)(2w+2) Qw with w=1 to 6, C—0.0005 to 0.1 by weight of Pt as catalyst (C), D1—0 to 50 parts by weight of at least one particulate component (D1) chosen from the group of (co)polyamide powders, D2—0 to 50 parts by weight of at least one particulate component (D2) chosen from the group of silica powders, D3—0 to 50 parts by weight of at least one particulate component (D3) chosen from the group of reinforcing silica powders, D4—0 to 50 parts by weight of at least one particulate component (D4) chosen from the group of metal oxide powders, preferably titanium oxide, cerium oxide or aluminium oxide A12O3 (hydrated alumina) powders, or alternatively mica powders, E—0.01 to 1 part by weight of at least one crosslinking inhibitor (E) useful in particular as a regulator, F—0 to 800 parts by weight of at least one solvent (F), G—0 to 5 parts by weight of at least one adhesion promoter (G), H—0 to 5 of at least one functional additive (H) for imparting priorities 0 to 10. The invention also comprises a varnishing process, and a composite comprising the varnished support.
摘要翻译：本发明涉及特别可用于生产可应用于柔性或体积载体的防污清漆的硅氧烷组合物。目的是为涂有硅橡胶的纺织品提供防污的硅油清漆，这是经济，粘合，防滑和有光泽的。该目的通过可交联的有机硅组合物实现，其包含：A-100重量份的干POS树脂（A），优选式MMViQ，B-35至150重量份的POS（B），优选式 MH）（2w + 2）Qw，w = 1〜6，C-0.0005〜0.1重量比Pt作为催化剂（C），D1-0〜50重量份的至少一种选自一组（共）聚酰胺粉末，D2-0至50重量份的至少一种选自二氧化硅粉末，D3-0至50重量份的至少一种颗粒组分（D3）的颗粒组分（D2）选自增强二氧化硅粉末组，D4-0至50重量份的选自金属氧化物粉末，优选氧化钛，氧化铈或氧化铝A12O3（水合氧化铝）粉末的至少一种颗粒组分（D4），或者云母粉末，E-0.01至1重量份的至少一种特别用作调节剂的交联抑制剂（E），F-0至 800重量份的至少一种溶剂（F），G-0至5重量份的至少一种粘合促进剂（G），H-0至5个至少一种功能添加剂（H），用于赋予优先权0至本发明还包括上漆工艺，以及包括上漆支架的复合材料。

6. 发明授权

US08329307B2 Anti-fouling polyaddition silicone varnish, application of this varnish to a support and support thus treated 有权
标题翻译：防污聚硅氧烷清漆，将这种清漆用于支撑和支撑，从而处理
公开(公告)号：US08329307B2
公开(公告)日：2012-12-11
申请号：US12096781
申请日：2006-12-07
申请人： Alain Pouchelon , Maryline Quemin
发明人： Alain Pouchelon , Maryline Quemin
IPC分类号： B32B27/12
CPC分类号： D06N3/128 , C08L83/04 , C09D5/1675 , C09D183/04 , D06M15/643 , Y10T428/26 , Y10T428/31663 , Y10T442/20 , Y10T442/60 , C08L83/00
摘要： This invention relates to silicon compositions particularly useful for the production of anti-fouling varnishes that can be applied to flexible or bulk supports. In particular, embodiments of the invention are directed to cross-linkable silicone composition that is cross-linkable by polyaddition and includes at least two inter-reactive polyorganosiloxane (POS) species (A) and (B) in the presence of a metal catalyst (C) in order to allow cross-linking by polyaddition; and optionally at least one particulate component (D); at least one cross-linking inhibitor (E); optionally at least one solvent (F), optionally at least one adhesion promoter (G); and optionally at least one functional additive (H) for imparting specific properties.
摘要翻译：本发明涉及特别可用于生产可应用于柔性或散装载体的防污清漆的硅组合物。特别地，本发明的实施方案涉及可通过加聚交联的可交联硅氧烷组合物，并且在金属催化剂存在下包括至少两种反应活性聚有机硅氧烷（POS）（A）和（B） C）以允许通过加聚交联; 和任选的至少一种颗粒组分（D）; 至少一种交联抑制剂（E）; 任选至少一种溶剂（F），任选的至少一种粘合促进剂（G）; 和任选的至少一种用于赋予特定性质的功能添加剂（H）。

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