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    • 4. 发明授权
    • Process for production of zeolite film
    • 沸石膜生产工艺
    • US07973090B2
    • 2011-07-05
    • US12118911
    • 2008-05-12
    • Kenji SuzukiShinji NakamuraMiyuki YabukiToshihiro Tomita
    • Kenji SuzukiShinji NakamuraMiyuki YabukiToshihiro Tomita
    • C08J5/20
    • B01D71/028B01D61/362B01D67/0051B01D2323/08B01D2325/04C01B37/02C01B39/04
    • A process for producing a zeolite membrane comprising a seed crystal forming step of placing, in a pressure-resistant vessel, a seeding sol containing silica, water and a structure-directing agent and a support in a state that the support is immersed in the seeding sol and heating the heat-resistant vessel to form a zeolite seed crystal on the surface of the support, and a membrane formation step of allowing the zeolite seed crystal to grow to form a zeolite membrane on the surface of the support. In the seed crystal forming step, the molar ratio of water/silica in the seeding sol is set 10 to 50 and the heating of the pressure-resistant vessel is conducted at 90 to 130° C. The crystal c-axis of the present zeolite membrane is oriented in a direction vertical to the surface of the support and its thickness is uniform.
    • 一种沸石膜的制造方法,其特征在于,包括晶种形成工序,在所述耐压容器中,将所述载体浸渍在所述接种中的状态下,将含有二氧化硅,水和结构导向剂的载置溶胶和载体 溶胶并加热耐热容器以在载体表面上形成沸石晶种,以及允许沸石晶种生长以在载体表面上形成沸石膜的膜形成步骤。 在晶种形成工序中,将接种溶胶中的水/二氧化硅的摩尔比设定为10〜50,耐压容器的加热在90〜130℃下进行。本沸石的晶体c轴 膜在垂直于支撑体表面的方向上取向,并且其厚度是均匀的。
    • 8. 发明申请
    • Inorganic separation membrane and method for manufacturing the same
    • 无机分离膜及其制造方法
    • US20060266696A1
    • 2006-11-30
    • US11289763
    • 2005-11-29
    • Takao MasudaTeruoki TagoShuichi YoshidaToshihiro TomitaKenji Suzuki
    • Takao MasudaTeruoki TagoShuichi YoshidaToshihiro TomitaKenji Suzuki
    • B01D71/04
    • B01D71/04B01D67/0051B01D69/02B01D69/12B01D2325/04B01D2325/30B01D2325/36
    • The present invention provides an inorganic separation membrane including a silicalite nanocrystalline layer formed on a porous ceramic substrate, and a porous inorganic protective layer is formed on the nanocrystalline layer. The crystal grain diameter of the silicalite nanocrystal is preferably 150 nm or less, and the thickness of the silicalite nanocrystalline layer is preferably 1.0 to 4.0 μm. The separation membrane may be manufactured by: immersing a porous ceramic substrate in a dispersion solution of silicalite nanocrystals; laminating the silicalite nanocrystals on the surface of the porous ceramic substrate by evacuating the insider of the porous ceramic substrate; forming a porous inorganic protective layer on the silicalite nanocrystalline layer by a hydrothermal synthesis by heating after immersing the porous substrate in a zeolite synthesis solution containing a silica source; and removing organic components in the silicalite nanocrystal by liquid phase oxidation.
    • 本发明提供一种无机分离膜,其包括在多孔陶瓷基板上形成的硅沸石纳米晶层,在纳米晶层上形成多孔无机保护层。 硅沸石纳米晶体的晶粒直径优选为150nm以下,并且硅沸石纳米晶层的厚度优选为1.0〜4.0μm。 分离膜可以通过以下步骤制造:将多孔陶瓷基材浸渍在硅沸石纳米晶体的分散溶液中; 通过抽真空多孔陶瓷基板的内部,在多孔陶瓷基板的表面层叠硅沸石纳米晶体; 在将多孔基材浸入含有二氧化硅源的沸石合成溶液中之后通过加热通过水热合成在硅沸石纳米晶层上形成多孔无机保护层; 并通过液相氧化除去硅沸石纳米晶体中的有机成分。