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1. 发明授权

US06465144B2 Magnetic toner, process for production thereof, and image forming method, apparatus and process cartridge using the toner 有权
标题翻译：磁性调色剂，其制造方法以及使用调色剂的成像方法，装置和处理盒
公开(公告)号：US06465144B2
公开(公告)日：2002-10-15
申请号：US09800655
申请日：2001-03-08
申请人： Akira Hashimoto , Kenji Okado , Tsutomu Kukimoto , Tatsuya Nakamura , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Keiji Komoto
发明人： Akira Hashimoto , Kenji Okado , Tsutomu Kukimoto , Tatsuya Nakamura , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Keiji Komoto
IPC分类号： G03G9083
CPC分类号： G03G9/08708 , G03G9/0819 , G03G9/0825 , G03G9/0827 , G03G9/0833 , G03G9/0835 , G03G9/0836 , G03G9/0837 , G03G9/0838 , G03G9/08782
摘要： A magnetic toner includes: magnetic toner particles each comprising at least a binder resin and magnetic toner, and inorganic fine powder. The magnetic toner has an average circularity of at least 0.970, and a magnetization of 10-50 Am2/kg at a magnetic field of 79.6 kA/m. The magnetic powder comprises at least magnetic iron oxide. The magnetic toner particles retain carbon in an amount of A and iron in an amount of B at surfaces thereof as measured by X-ray photoelectron spectroscopy, satisfying: B/A
摘要翻译：磁性调色剂包括：各自至少包含粘合剂树脂和磁性调色剂的磁性调色剂颗粒和无机细粉末。磁性调色剂在79.6kA / m的磁场下的平均圆形度为至少0.970，磁化强度为10-50Am 2 / kg。磁粉至少包含磁性氧化铁。磁性调色剂颗粒通过X射线光电子能谱法测定其表面的B量的A和铁的碳，满足：B / A <0.001。粘合剂树脂包括由至少包含苯乙烯单体的单体的聚合形成的树脂。磁性调色剂的残留苯乙烯单体含量小于300ppm，并且包含满足以下关系的至少50％的调色剂颗粒：D / C <= 0.02，其中C表示磁性的体积平均粒径调色剂，D表示磁性调色剂颗粒的表面与磁性调色剂颗粒中所含的磁性粉末颗粒之间的最小距离。由于上述特征，即使在无清洁器模式的图像形成系统中，磁性调色剂也能表现出良好的电摄影性能，包括极佳的带电性和少量的转印残留调色剂。

2. 发明授权

US06447969B1 Toner and image forming method 有权
标题翻译：调色剂和成像方法
公开(公告)号：US06447969B1
公开(公告)日：2002-09-10
申请号：US09580409
申请日：2000-05-30
申请人： Masanori Ito , Tsutomu Kukimoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Keiji Komoto
发明人： Masanori Ito , Tsutomu Kukimoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Keiji Komoto
IPC分类号： G03G9083
CPC分类号： G03G9/0827 , G03G9/0825
摘要： A toner is formed of toner particles each comprising a binder resin and iron oxide particles dispersed therein. The toner particles are characterized by uniform but non-surface-exposed dispersion of the iron oxide particles within the toner particles as represented by (i) a carbon content (A) and an iron content (B) giving a ratio B/A
摘要翻译：调色剂由分别包含粘合剂树脂和氧化铁颗粒的调色剂颗粒形成。调色剂颗粒的特征在于由（i）碳含量（A）和铁含量（B）表示的氧化铁颗粒在调色剂颗粒内的均匀但非表面暴露的分散体，其比例B / A <0.001 在通过X射线光电子能谱测定的调色剂颗粒的表面上，（ii）至少0.970的平均圆形度，和（iii）满足D / C <0.02的调色剂颗粒的至少50％，其中C表示基于通过透射电子显微镜（TEM）观察到的调色剂颗粒的截面图，每个调色剂颗粒的投影面积当量圆直径和D表示氧化铁颗粒从调色剂颗粒表面的最小距离。

3. 发明授权

US06596452B2 Magnetic toner and image-forming method making use of the same 有权
标题翻译：使用磁性调色剂和成像方法
公开(公告)号：US06596452B2
公开(公告)日：2003-07-22
申请号：US09788399
申请日：2001-02-21
申请人： Michihisa Magome , Tsutomu Kukimoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Akira Hashimoto , Keiji Komoto
发明人： Michihisa Magome , Tsutomu Kukimoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Akira Hashimoto , Keiji Komoto
IPC分类号： G03G9083
CPC分类号： G03G9/0833 , G03G9/0827 , G03G9/0835 , G03G9/0836 , G03G9/0837 , G03G9/0838 , G03G9/08708 , G03G9/08793 , G03G9/08797 , Y10S430/102
摘要： A magnetic toner comprising magnetic toner particles containing at least a binder resin, a magnetic material containing a magnetic iron oxide, and a release agent. The magnetic toner has a weight-average particle diameter of from 3 &mgr;m to 10 &mgr;m, a magnetization intensity (saturation magnetization) of from 10 Am2/kg to 50 Am2/kg (emu/g) under application of a magnetic field of 79.6 kA/m (1,000 oersteds), an average circularity of 0.970 or more, a ratio of weight-average particle diameter to number-average particle diameter, of 1.40 or less, iron and an iron compound which stand liberated from the magnetic toner particles at a liberation percentage of from 0.05% to 3.00%, and a resin component having a tetrahydrofuran-insoluble matter in an amount of from 3% by weight to 60% by weight. Also disclosed is an image-forming method making use of the magnetic toner.
摘要翻译：包含至少含有粘合剂树脂的磁性调色剂颗粒，含有磁性氧化铁的磁性材料和脱模剂的磁性调色剂。磁性调色剂的重均粒径为3μm〜10μm，在施加79.6kA的磁场下，磁化强度（饱和磁化强度）为10Am 2 / kg〜50Am 2 / kg（emu / g） / m（1,000奥斯特），平均圆形度为0.970以上，重均粒径与数均粒径的比值为1.40以下，铁和铁化合物在磁性调色剂颗粒中释放出来释放百分比为0.05％〜3.00％，以及四氢呋喃不溶物质量为3重量％〜60重量％的树脂成分。还公开了利用磁性调色剂的图像形成方法。

4. 发明授权

US07043175B2 Image forming method and apparatus 失效
标题翻译：图像形成方法和装置
公开(公告)号：US07043175B2
公开(公告)日：2006-05-09
申请号：US09987490
申请日：2001-11-15
申请人： Keiji Komoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Takeshi Kaburagi
发明人： Keiji Komoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Takeshi Kaburagi
IPC分类号： G03G15/00 , G03G15/02
CPC分类号： G03G9/0827 , G03G5/08214 , G03G9/0819 , G03G9/0835 , G03G9/09708 , Y10S430/102
摘要： In an image forming system, an image-bearing member having a photoconductor layer comprising an Si-based non-single crystal material is charged at a relatively low potential of 250 to 600 volts by a contact charging member in the presence of electroconductive fine powder. An electrostatic latent image formed on the image-bearing member is developed with a magnetic toner which includes magnetic toner particles comprising at least a binder resin and a magnetic iron oxide, and inorganic fine powder and electroconductive fine powder present at the surface of the magnetic toner particles. The magnetic toner has a weight-average particle size of 3-10 μm and an average circularity of 0.950 to 0.995, and contains 0.05 to 3.00% of isolated iron-containing particles.
摘要翻译：在图像形成系统中，具有包含Si基非单晶材料的光电导体层的图像承载部件在导电细粉存在的情况下通过接触充电部件以相对较低的电压250至600伏特进行充电。形成在图像承载部件上的静电潜像用包括至少包含粘合剂树脂和磁性氧化铁的磁性调色剂颗粒的磁性调色剂显影，以及存在于磁性调色剂表面的无机细粉末和导电细粉末粒子。磁性调色剂的重均粒径为3-10μm，平均圆形度为0.950〜0.995，含有0.05〜3.00％的分离的含铁颗粒。

5. 发明授权

US06638674B2 Magnetic toner 有权
标题翻译：磁性调色剂
公开(公告)号：US06638674B2
公开(公告)日：2003-10-28
申请号：US09911724
申请日：2001-07-25
申请人： Keiji Komoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Takeshi Kaburagi , Eriko Yanase
发明人： Keiji Komoto , Tsuyoshi Takiguchi , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Takeshi Kaburagi , Eriko Yanase
IPC分类号： G03G9083
CPC分类号： G03G9/08791 , G03G9/0821 , G03G9/0825 , G03G9/0827 , G03G9/083 , G03G9/08726
摘要： A magnetic toner is formed of magnetic toner particles each comprising a binder resin, an iron oxide, a sulfur-containing polymer, and inorganic fine powder blended with the magnetic toner particles, the toner having a weight-average particle size (D4) of 3-10 &mgr;m, and either (a) an average circularity of at least 0.970, and a magnetization of 10-50 Am2/kg (emu/g) at a magnetic field of 79.6 kA/m (1000 oersted), or (b) toner particles which retain carbon in an amount of A and iron in an amount of B at surfaces thereof, satisfying: B/A
摘要翻译：磁性调色剂由各自包含粘合剂树脂，氧化铁，含硫聚合物和与磁性调色剂颗粒混合的无机细粉末的磁性调色剂颗粒形成，调色剂的重均粒径（D4）为3 -10μm，并且（a）在79.6kA / m（1000奥斯特）的磁场下的平均圆形度为至少0.970，磁化强度为10-50Am 2 / kg（emu / g），或（b）在其表面保留B量的A和铁的碳的调色剂颗粒满足：B / A <0.001，并且含有至少50数量的D / C的磁性调色剂颗粒< 0.02，其中C表示颗粒投影面积当量圆直径，D表示磁性调色剂颗粒的表面与其中所含的氧化铁颗粒之间的最小距离。

6. 发明授权

US06653035B2 Magnetic toner 有权
公开(公告)号：US06653035B2
公开(公告)日：2003-11-25
申请号：US10202903
申请日：2002-07-26
申请人： Keiji Komoto , Tatsuya Nakamura , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Takeshi Kaburagi , Eriko Yanase
发明人： Keiji Komoto , Tatsuya Nakamura , Tatsuhiko Chiba , Michihisa Magome , Akira Hashimoto , Takeshi Kaburagi , Eriko Yanase
IPC分类号： G03G9083
CPC分类号： G03G9/0834 , G03G9/0819 , G03G9/0825 , G03G9/0827 , G03G9/0836 , G03G9/0837 , G03G9/0838 , G03G9/08711 , G03G9/08722 , G03G9/08771 , G03G9/08782 , G03G9/08791
摘要： A magnetic toner exhibiting stable performances under various environmental conditions is formed of toner particles each comprising at least a binder resin and iron oxide dispersed therein. Relative to the dry specific gravity (A) of the magnetic toner, the magnetic toner is characterized by a specific gravity distribution of toner particle fractions obtainable through wet sedimentation and including: at most 15 wt. % of a fraction having a specific gravity of above (A)×1.000 and at most (A)×1.025, 0.1-20 wt. % of a fraction having a specific gravity of above (A)×0.975 and at most (A)×1.000, at least 30 wt. % of a fraction having a specific gravity of above (A)×0.950 and at most (A)×0.975, 0.1-20 wt. % of a fraction having a specific gravity of above (A)×0.925 and at most (A)×0.950, and at most 15 wt. % of a fraction having a specific gravity of above (A)×0.900 and at most (A)×0.925.

7. 发明授权

US06635398B1 Dry toner, dry toner production process, and image forming method 失效
标题翻译：干粉，干粉生产工艺和成像方法
公开(公告)号：US06635398B1
公开(公告)日：2003-10-21
申请号：US09695079
申请日：2000-10-25
申请人： Keiji Komoto , Tsutomu Kukimoto , Tatsuhiko Chiba , Akira Hashimoto
发明人： Keiji Komoto , Tsutomu Kukimoto , Tatsuhiko Chiba , Akira Hashimoto
IPC分类号： G03G9087
CPC分类号： G03G9/0821 , G03G9/0827 , G03G9/08737
摘要： A dry toner has toner particles containing at least a binder resin, a colorant and a wax component and an external additive. The binder resin contains a component derived from a monomer selected from butadiene, isoprene and chloroprene. The toner has a main Tg from 40° C. to 70° C. When specific surface area measured by the BET method in an environment of 23° C. atmospheric temperature and 65% relative humidity is represented by A (m2/g) and specific surface area measured by the BET method in an environment of 50° C. atmospheric temperature and 3% relative humidity is represented by B (m2/g), the toner satisfies the following relationship: 0.8≦A≦4.0, 0.80≦(B/A)≦1.05. The toner has a circle-corresponding number-average particle diameter D1 from 2 to 10 &mgr;m, an average circularity from 0.950 to 0.995 and a circularity standard deviation less than 0.040. The toner has a main-peak molecular weight from 2,000 to 100,000 and contains a THF-insoluble matter from 5 to 60% by weight.
摘要翻译：干燥调色剂具有至少含有粘合剂树脂，着色剂和蜡组分的调色剂颗粒和外部添加剂。粘合剂树脂含有源自选自丁二烯，异戊二烯和氯丁二烯的单体的成分。调色剂的主要Tg为40℃至70℃。当在23℃环境温度和65％相对湿度的环境中通过BET法测得的比表面积由A（m 2 / g）和通过BET法在50℃环境温度和3％相对湿度的环境中测量的比表面积由B（m 2 / g）表示，调色剂满足以下关系：0.8 <= A <= 4.0,0.80 <=（B / A）<= 1.05。调色剂具有2至10μm的圆对应的数均粒径D1，0.950至0.995的平均圆形度和小于0.040的圆形度标准偏差。调色剂的主峰分子量为2,000〜100,000，含有5〜60重量％的THF不溶物。

8. 发明授权

US05998080A Electrostatic image-developing toner and image-forming method 有权
标题翻译：静电影像显影调色剂和成像方法
公开(公告)号：US05998080A
公开(公告)日：1999-12-07
申请号：US143392
申请日：1998-08-28
申请人： Manabu Ohno , Tsutomu Kukimoto , Satoshi Yoshida , Yasukazu Ayaki , Satoshi Handa , Akira Hashimoto , Keiji Komoto , Tsuyoshi Takiguchi
发明人： Manabu Ohno , Tsutomu Kukimoto , Satoshi Yoshida , Yasukazu Ayaki , Satoshi Handa , Akira Hashimoto , Keiji Komoto , Tsuyoshi Takiguchi
IPC分类号： G03G9/08 , G03G9/087 , G03G9/093 , G03G9/097 , G03G15/01 , G03G15/08 , G03G15/20 , G03G13/20
CPC分类号： G03G9/09733 , G03G9/0806 , G03G9/0827 , G03G9/08782 , G03G9/09378
摘要： A toner for developing an electrostatic image has toner particles containing at least a binder resin, a colorant, and a wax. The wax contains an ester compound represented by specific formula, or a mixture thereof at a content ranging from 50 to 100% by weight based on the weight of the wax.
摘要翻译：用于显影静电图像的调色剂具有至少含有粘合剂树脂，着色剂和蜡的调色剂颗粒。蜡包含由特定配方表示的酯化合物或其混合物，其含量为基于蜡重量的50至100重量％。

9. 发明授权

US06610454B2 Toner and image forming method 失效
标题翻译：调色剂和成像方法
公开(公告)号：US06610454B2
公开(公告)日：2003-08-26
申请号：US09146356
申请日：1998-09-03
申请人： Akira Hashimoto , Tsutomu Kukimoto , Manabu Ohno , Tsuyoshi Takiguchi , Yasukazu Ayaki , Satoshi Handa , Masanori Ito , Keiji Komoto
发明人： Akira Hashimoto , Tsutomu Kukimoto , Manabu Ohno , Tsuyoshi Takiguchi , Yasukazu Ayaki , Satoshi Handa , Masanori Ito , Keiji Komoto
IPC分类号： G03G9087
CPC分类号： G03G9/08757 , G03G9/08795
摘要： A toner is comprised of a binder resin, a colorant and a wax. The binder resin has a polycarbonate resin in an amount of from 0.1% by weight to 50.0% by weight and a resin other than the polycarbonate resin in an amount of from 50.0% by weight to 99.9% by weight, based on the weight of the binder resin. In molecular weight distribution as measured by gel permeation chromatography of tetrahydrofuran-soluble matter, the toner contains in an amount of 15.0% by weight or less based on the weight of the toner a component which has in its structure a repeating unit of the polycarbonate resin and is contained in components having a molecular weight of 1,000 or less.
摘要翻译：调色剂由粘合剂树脂，着色剂和蜡组成。粘合剂树脂的聚碳酸酯树脂的量为0.1重量％〜50.0重量％，除聚碳酸酯树脂以外的树脂的重量比为50.0重量％〜99.9重量％粘合剂树脂。在通过四氢呋喃可溶物质的凝胶渗透色谱法测量的分子量分布中，调色剂的含量相对于调色剂的重量为15.0重量％，其组分为聚碳酸酯树脂的重复单元并且含有分子量为1,000以下的成分。

10. 发明授权

US07070898B2 Toner 有权
标题翻译：爽肤水
公开(公告)号：US07070898B2
公开(公告)日：2006-07-04
申请号：US10726503
申请日：2003-12-04
申请人： Tatsuya Nakamura , Kenji Okado , Akira Hashimoto , Keiji Komoto
发明人： Tatsuya Nakamura , Kenji Okado , Akira Hashimoto , Keiji Komoto
IPC分类号： G03G9/08
CPC分类号： G03G9/08 , G03G9/087
摘要： A toner having a favorable fixability, excelling in charge stability, and capable of forming a image of retaining a high image density and a high resolution in long-term use is provided. That is, the toner of the present invention is a toner obtained by polymerizing a polymerizable monomer composition comprising a polymerizable monomer and a colorant, in which the polymerizable monomer composition is polymerized using a polymerization initiator comprising a redox initiator which includes an organic peroxide with a 10-hour half-life temperature of 86° C. or higher and an reducing agent; the toner has a ratio of a weight-average particle diameter to a number-average particle diameter of 1.40 or less; and the toner has top of a main-peak in a molecular weight range of 5,000 to 50,000 in a molecular weight distribution measured using GPC of the THF-soluble part thereof, including t-butanol with a content of 0.1 to 1,000 ppm.
摘要翻译：提供了具有良好的定影性，电荷稳定性优异并且能够形成长期使用中保持高图像浓度和高分辨率的图像的调色剂。也就是说，本发明的调色剂是通过使包含可聚合单体和着色剂的可聚合单体组合物聚合而获得的调色剂，其中使用包含有机过氧化物的氧化还原引发剂的聚合引发剂聚合可聚合单体组合物， 10小时半衰期为86℃以上的还原剂; 调色剂的重均粒径与数均粒径的比值为1.40以下; 并且调色剂在其THF可溶部分的GPC测量的分子量分布中具有5000至50,000的分子量范围内的主峰顶部，包括含量为0.1至1,000ppm的叔丁醇。

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