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    • 7. 发明授权
    • Clear coating with composition of acrylic and polyester polycarboxylic acids, polyepoxide and crosslinked resin particles
    • 用丙烯酸和聚酯多元羧酸,聚环氧化物和交联树脂颗粒组成的透明涂层
    • US06656531B2
    • 2003-12-02
    • US10134514
    • 2002-04-30
    • Manabu YoshiokaAkira FushimiSeigo MiyazoeMasanobu InoueYoshio Eguchi
    • Manabu YoshiokaAkira FushimiSeigo MiyazoeMasanobu InoueYoshio Eguchi
    • B05D136
    • C09D167/00C08L33/064C08L63/00C08L67/00C09D133/064C09D163/00C09D167/04C08L2666/02C08L2666/14
    • A method for forming a coated film comprises (1) applying a water or solvent based coating composition on an undercoated or intercoated substrate to form a base coating, (2) applying a clear coating composition thereon to form a clear coating without curing the base coating, and (3) heating and curing both the base coating and clear coating, wherein the clear coating composition comprises as a binder (a) from 10-70% by weight of an acrylic polycarboxylic acid having on average 2 or more carboxyl groups per molecule obtained by copolymerizing an acid anhydride group-containing ethylenically unsaturated monomer with an ethylenically unsaturated monomer having no acid anhydride group, then reacting the resulting copolymer with a monoalcohol; (b) from 5-70% by weight of a polyester polycarboxylic acid having an acid value of from 50-350 mg KOH/g (solid) obtained by reacting a polyester polyol having 3 or more hydroxyl groups with an acid anhydride group-containing compound; (c) from 10-80% by weight of a polyepoxide with both an epoxy group and a hydroxyl group; and (d) crosslinked resin particles prepared in the presence of an amphoteric ionic group-containing polyester.
    • 一种形成涂膜的方法包括(1)在底涂或基底上涂布水或溶剂基涂料组合物以形成底涂层,(2)在其上施加透明涂料组合物以形成透明涂层,而不固化底涂层 ,和(3)加热和固化基底涂层和透明涂层,其中透明涂料组合物包含作为粘合剂(a)10-70重量%的每分子具有平均2个以上羧基的丙烯酸多元羧酸 通过使含酸酐基团的烯属不饱和单体与不具有酸酐基团的烯属不饱和单体共聚,然后使所得共聚物与一元醇反应得到;(b)5-70重量%的具有酸的聚酯多元羧酸 通过使具有3个或更多个羟基的聚酯多元醇与含酸酐基的化合物反应获得的50-350mg KOH / g(固体)的值;(c)10-80% 具有环氧基和羟基的聚环氧化物的聚合物; 和(d)在两性离子基聚酯的存在下制备的交联树脂颗粒。
    • 8. 发明授权
    • Composition of acrylic polycarboxylic acid, polyester polycarboxylic acid and polyepoxide
    • 丙烯酸多元羧酸,聚酯多元羧酸和聚环氧化物的组成
    • US06410647B1
    • 2002-06-25
    • US09450719
    • 1999-11-30
    • Manabu YoshiokaAkira FushimiSeigo MiyazoeMasanobu InoueYoshio Eguchi
    • Manabu YoshiokaAkira FushimiSeigo MiyazoeMasanobu InoueYoshio Eguchi
    • C08L3302
    • C09D167/00C08L33/064C08L63/00C08L67/00C09D133/064C09D163/00C09D167/04C08L2666/02C08L2666/14
    • A high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance comprises: (a) 10 to 70% by weight of an acrylic polycarboxylic acid having 2 or more carboxyl groups per molecule on an average, an acid value of 5 to 300 mg KOH/g (solid) and a number-average molecular weight of 500 to 8000; (b) 5 to 70% by weight of a polyester polycarboxylic acid having an acid value of 50 to 350 mg KOH/g (solid), a number-average molecular weight of 400 to 3500 and a ratio of weight-average molecular weight to number-average molecular weight of 1.8 or less, which is obtained by reacting a polyester polyol having 3 or more hydroxyl groups with an acid anhydride group-containing compound; and (c) 10 to 80% by weight of a polyepoxide having an epoxy equivalent of 50 to 700 and a number-average molecular weight of 200 to 10000; provided that the amounts of the components (a) to (c) being based on the weight of the total solid contained in the curable resin composition.
    • 形成耐酸雨性,耐擦伤性和外观优异的涂膜的高固体固化性树脂组合物包含:(a)平均每分子具有10〜70重量%的具有2个以上羧基的丙烯酸多元羧酸, 酸值为5〜300mg KOH / g(固体),数均分子量为500〜8000;(b)5〜70重量%的酸值为50〜350mg KOH的聚酯多元羧酸 / g(固体),数均分子量为400〜3500,重均分子量与数均分子量的比值为1.8以下,通过使具有3个以上羟基的聚酯多元醇 与含酸酐基的化合物; 和(c)10〜80重量%的环氧当量为50〜700,数均分子量为200〜10000的聚环氧化物; 前提条件是组分(a)至(c)的量基于可固化树脂组合物中所含的总固体的重量。