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1. 发明授权

US06953345B1 Water-metachromatic cloth sheet, toy set using the same, and writing instrument for water-metachromatic members 有权
标题翻译：水异色布片，使用其的玩具组，以及用于水异色构件的书写工具
公开(公告)号：US06953345B1
公开(公告)日：2005-10-11
申请号：US09679341
申请日：2000-10-04
申请人： Akio Nakashima , Takao Kani
发明人： Akio Nakashima , Takao Kani
IPC分类号： A63H33/22 , A63H33/00 , B41M3/00 , B43K11/00 , B43K27/08 , B44D2/00 , B44F1/10 , D06M11/79 , D06P1/00 , D06Q1/10 , G09B11/00 , B43L1/00 , G09B11/10
CPC分类号： B43K11/005 , A63H33/22 , B43K8/02 , B43K11/00 , B43K27/08 , B43L1/00 , B43L1/002 , B44D2/002 , B44F1/10 , D06M11/79 , D06P1/004 , D06P1/44 , D06P1/54 , D06Q1/10
摘要： A water-metachromatic sheet has a support with a porous layer containing a binder resin with dispersed fine-particle silicic acid. The sheet is capable of rendering different transparency between water absorbed and unabsorbed states. The support is a cloth having a weight per unit area of 30 gm2 to 1,000 gm2, the fine-particle silicic acid is contained in an amount of from 1 gm2 to 30 gm2, and the fine-particle silicic acid is incorporated in an amount from 0.5 to 2 parts by weight based on 1 part by weight of the binder resin.
摘要翻译：水异色性片材具有带有多孔层的载体，该多孔层含有分散的细颗粒硅酸的粘合剂树脂。该片材能够在吸水和未吸收状态之间呈现不同的透明度。该支撑体是每单位面积重量为30gm 2〜1000gm 2以上的布，细粒状硅酸的含量为1g / SUP> 2〜30gm 2，微粒硅酸的添加量相对于粘合剂树脂1重量份为0.5〜2重量份。

2. 发明申请

US20060008315A1 Writing instrument for water-metachromatic members with detachable pen point holder 有权
标题翻译：用可拆卸笔尖支架的水异色构件书写工具
公开(公告)号：US20060008315A1
公开(公告)日：2006-01-12
申请号：US11201140
申请日：2005-08-11
申请人： Akio Nakashima , Takao Kani
发明人： Akio Nakashima , Takao Kani
IPC分类号： B43K5/00
CPC分类号： B43K11/005 , A63H33/22 , B43K8/02 , B43K11/00 , B43K27/08 , B43L1/00 , B43L1/002 , B44D2/002 , B44F1/10 , D06M11/79 , D06P1/004 , D06P1/44 , D06P1/54 , D06Q1/10
摘要： A writing instrument for a water-metachromatic member has a cylindrical container capable of holding water, formed with an opening at a tip end thereof to communicate the interior of the container with the exterior thereof, a hollow cylindrical holder which directly holds a pen point member, being formed at a tip end with an opening through which the tip end of said pen point member is projected outwardly and at a rear end with a communication hole, and a gap provided between an inner peripheral surface of the cylindrical holder and an outer peripheral surface of the rod-like body to form a gap for generating a capillary force therebetween. When the holder is held to the container, water is supplied through said communication hole to said pen point member. When the holder is detached from the container, the opening of the container is usable for water supply.
摘要翻译：一种用于水 - 异染色构件的书写工具具有能够保持水的圆柱形容器，其在其末端形成有开口以将容器的内部与其外部连通，中空圆柱形保持器，其直接保持笔尖构件在尖端部形成有一个开口，所述笔尖部件的前端通过该开口向外突出并在后端形成有连通孔，并且在所述圆筒形保持器的内周表面和外周面之间设置间隙杆状体的表面形成用于在其间产生毛细管力的间隙。当保持器被保持在容器上时，通过所述连通孔将水供给到所述笔尖部件。当保持器与容器分离时，容器的开口可用于供水。

3. 发明申请

US20070086832A1 Writing instrument for water-metachromatic members with detachable pen point holder 审中-公开
公开(公告)号：US20070086832A1
公开(公告)日：2007-04-19
申请号：US11594892
申请日：2006-11-09
申请人： Akio Nakashima , Takao Kani
发明人： Akio Nakashima , Takao Kani
IPC分类号： B43K8/06 , B43K29/00
CPC分类号： B43K11/005 , A63H33/22 , B43K8/02 , B43K11/00 , B43K27/08 , B43L1/00 , B43L1/002 , B44D2/002 , B44F1/10 , D06M11/79 , D06P1/004 , D06P1/44 , D06P1/54 , D06Q1/10
摘要： A writing instrument for a water-metachromatic member has a cylindrical container capable of holding water, formed with an opening at a tip end thereof to communicate the interior of the container with the exterior thereof, a hollow cylindrical holder which directly holds a pen point member, being formed at a tip end with an opening through which the tip end of said pen point member is projected outwardly and at a rear end with a communication hole, and a gap provided between an inner peripheral surface of the cylindrical holder and an outer peripheral surface of the rod-like body to form a gap for generating a capillary force therebetween. When the holder is held to the container, water is supplied through said communication hole to said pen point member. When the holder is detached from the container, the opening of the container is usable for water supply.

4. 发明授权

US07168876B2 Writing instrument for water-metachromatic members with detachable pen point holder 有权
标题翻译：用可拆卸笔尖支架的水异色构件书写工具
公开(公告)号：US07168876B2
公开(公告)日：2007-01-30
申请号：US11201140
申请日：2005-08-11
申请人： Akio Nakashima , Takao Kani
发明人： Akio Nakashima , Takao Kani
IPC分类号： B43K5/00 , B43K8/06
CPC分类号： B43K11/005 , A63H33/22 , B43K8/02 , B43K11/00 , B43K27/08 , B43L1/00 , B43L1/002 , B44D2/002 , B44F1/10 , D06M11/79 , D06P1/004 , D06P1/44 , D06P1/54 , D06Q1/10
摘要： A writing instrument for a water-metachromatic member has a cylindrical container capable of holding water, formed with an opening at a tip end thereof to communicate the interior of the container with the exterior thereof, a hollow cylindrical holder which directly holds a pen point member, being formed at a tip end with an opening through which the tip end of said pen point member is projected outwardly and at a rear end with a communication hole, and a gap provided between an inner peripheral surface of the cylindrical holder and an outer peripheral surface of the rod-like body to form a gap for generating a capillary force therebetween. When the holder is held to the container, water is supplied through said communication hole to said pen point member. When the holder is detached from the container, the opening of the container is usable for water supply.
摘要翻译：一种用于水 - 异染色构件的书写工具具有能够保持水的圆柱形容器，其在其末端形成有开口以将容器的内部与其外部连通，中空圆柱形保持器，其直接保持笔尖构件在尖端部形成有一个开口，所述笔尖部件的前端通过该开口向外突出并在后端形成有连通孔，并且在所述圆筒形保持器的内周表面和外周面之间设置间隙杆状体的表面形成用于在其间产生毛细管力的间隙。当保持器被保持在容器上时，通过所述连通孔将水供给到所述笔尖部件。当保持器与容器分离时，容器的开口可用于供水。

5. 发明申请

US20120246909A1 ACCESSORY MAKING DEVICE, ACCESSORY MAKING KIT, AND METHOD FOR MAKING ACCESSORY 有权
标题翻译：附件制造装置，附件制造工具包和制造附件的方法
公开(公告)号：US20120246909A1
公开(公告)日：2012-10-04
申请号：US13517258
申请日：2010-12-16
申请人： Natsuko Kobayashi , Haruka Kasuga , Akio Nakashima
发明人： Natsuko Kobayashi , Haruka Kasuga , Akio Nakashima
IPC分类号： B23P19/00 , B23P11/00
CPC分类号： B44C5/00 , Y10T29/4959 , Y10T29/49591 , Y10T29/49826 , Y10T29/49838 , Y10T29/49998 , Y10T29/53652 , Y10T29/53696 , Y10T29/53961 , Y10T29/5397
摘要： An accessory making device (1) of the present invention is a device for making an accessory including a core (83) formed into a substantially ring shape by connecting both ends of a stretchable cord-like body (46) having rubber-like elasticity and a decoration main body (83) disposed around the core in such a manner so as to abut both ends thereof against each other in a contracted state so as to be reduced in axial length. The accessory making device (1) includes a long rigid holder (5). The holder (5) can retain connecting portions (47M, 47F) on both end sides of the cord-like body (46) with the connecting portions (47M, 47F) of the cord-like body (46) separated from each other, and can be inserted through the decoration main body (83).
摘要翻译：本发明的辅助制造装置（1）是一种用于制造附件的装置，该装置包括通过将具有橡胶状弹性的可拉伸的线状体（46）的两端连接而形成为大致环状的芯（83）设置在芯体周围的装饰主体（83），以使其两端在收缩状态下彼此抵接以减小轴向长度。配件制造装置（1）包括长的刚性支架（5）。保持器（5）可以将线状体（46）的连接部分（47M，47F）彼此分开地保持在绳状体（46）的两端侧上的连接部分（47M，47F）并可以穿过装饰主体（83）插入。

6. 发明授权

US06984418B2 Water-metachromatic laminate, and process for its production 有权
公开(公告)号：US06984418B2
公开(公告)日：2006-01-10
申请号：US10819229
申请日：2004-04-07
申请人： Akio Nakashima , Hisayoshi Kato
发明人： Akio Nakashima , Hisayoshi Kato
IPC分类号： B05D5/00
CPC分类号： B32B27/04 , Y10T428/1362 , Y10T428/1366 , Y10T428/24802 , Y10T428/24835 , Y10T428/24851 , Y10T428/249953 , Y10T428/249994 , Y10T428/249996 , Y10T428/249998 , Y10T428/25 , Y10T428/251 , Y10T442/20 , Y10T442/2139 , Y10T442/2148 , Y10T442/2164 , Y10T442/2221
摘要： On a support, a porous resin layer which is opaque in a water-unabsorbed state and capable of turning transparent in a water-absorbed state is formed, and also a water-repellent resin layer is so provided as to exist in the porous resin layer at its some area or areas in a co-existent state, to make up a water-metachromatic laminate. A novel toy element can be provided in which latent images standing invisible in a normal condition are rendered visible by means of water as a medium so as to be visually distinguished.

7. 发明授权

US06964807B2 Water-metachromatic laminate, and process for its production 有权
标题翻译：水异色层压板及其生产工艺
公开(公告)号：US06964807B2
公开(公告)日：2005-11-15
申请号：US09961425
申请日：2001-09-25
申请人： Akio Nakashima , Hisayoshi Kato
发明人： Akio Nakashima , Hisayoshi Kato
IPC分类号： B32B27/04 , B32B23/08
CPC分类号： B32B27/04 , Y10T428/1362 , Y10T428/1366 , Y10T428/24802 , Y10T428/24835 , Y10T428/24851 , Y10T428/249953 , Y10T428/249994 , Y10T428/249996 , Y10T428/249998 , Y10T428/25 , Y10T428/251 , Y10T442/20 , Y10T442/2139 , Y10T442/2148 , Y10T442/2164 , Y10T442/2221
摘要： On a support, a porous resin layer which is opaque in a water-unabsorbed state and capable of turning transparent in a water-absorbed state is formed, and also a water-repellent resin layer is so provided as to exist in the porous resin layer at its some area or areas in a co-existent state, to make up a water-metachromatic laminate. A novel toy element can be provided in which latent images standing invisible in a normal condition are rendered visible by means of water as a medium so as to be visually distinguished.
摘要翻译：在支撑体上形成在水不吸收状态下不透明并且能够在吸水状态下变透明的多孔树脂层，并且还提供防水树脂层以存在于多孔树脂层中在其一些区域或共存状态的区域中，以构成水异色层压板。可以提供一种新颖的玩具元件，其中在正常状态下站立不可见的潜像通过水作为介质被可视地视觉区分。

8. 发明授权

US08147959B2 Color-change laminate 有权
标题翻译：变色层压板
公开(公告)号：US08147959B2
公开(公告)日：2012-04-03
申请号：US12335846
申请日：2008-12-16
申请人： Akio Nakashima , Atsushi Sasada
发明人： Akio Nakashima , Atsushi Sasada
IPC分类号： B32B5/16
CPC分类号： C09K9/00 , Y10T428/24997 , Y10T428/249986 , Y10T428/2982 , Y10T428/2989 , Y10T428/2991 , Y10T428/2998
摘要： A color-change laminate in which a color tone derived from a porous layer is visually perceived in a dry state and a metallic lustrous property is visually perceived in a liquid-absorbed state of the porous layer caused by water application is excellent in luminance and which satisfies both of changing properties and decorative properties in the dry state and in the liquid-absorbed state. A color-change laminate includes a support having a metallic lustrous property and a porous layer provided on the surface of the support. The porous layer includes a low-refractive-index pigment and a transparent metallic lustrous pigment formed by coating a transparent core material with a metal oxide and/or a transparent metallic lustrous pigment having a color-flopping property all fixed onto a binder resin in a dispersed state and is different in transparency in a liquid-absorbed state and in a liquid-unabsorbed state.
摘要翻译：其中由多孔层产生的色调在干燥状态下视觉上感觉到并且由水施加引起的多孔层的液体吸收状态下视觉上感觉到金属光泽性的变色层压板的亮度优异，满足干燥状态和液体吸收状态下的变化特性和装饰性能。变色层压板包括具有金属光泽性质的支撑体和设置在支撑体表面上的多孔层。多孔层包括低折射率颜料和透明金属光泽颜料，该透明金属光泽颜料通过将透明芯材与金属氧化物和/或透明金属光泽颜料进行涂覆而形成，所述透明金属光泽颜料全部固定在粘合剂树脂上分散状态，并且在液体吸收状态和液体未吸收状态下的透明度不同。

9. 发明申请

US20100248585A1 DRAWING TOY AND DRAWING TOY SET USING THE SAME 审中-公开
标题翻译：绘制玩具和绘图玩具使用它
公开(公告)号：US20100248585A1
公开(公告)日：2010-09-30
申请号：US12161395
申请日：2007-01-29
申请人： Akio Nakashima
发明人： Akio Nakashima
IPC分类号： A63H13/15 , A63H33/22
CPC分类号： B44F1/06 , A63H33/22 , B44D2/002
摘要： An drawing toy 1 having a excellent performance in play to which water is applied to form images such as letters or characters, and patterns or designs, which are perceivable as images having brilliance is constituted of an drawable member 2 having a light-transmitting support 3 and provided on the surface thereof a porous layer 4 in which a low refractive index pigment has been made dispersedly fixed to a binder resin and which comes different in transparency between a liquid-absorbed condition and a liquid-non-absorbed condition, and a light source 5 which irradiates the back surface of the drawable member with light. A drawing toy set is constituted of the drawing toy 1 and a water-applying implement 15.
摘要翻译：具有优良性能的绘图玩具1由具有透光支撑件3的可抽出构件2构成，该玩具1具有用于形成诸如字母或字符的图像的优异性能，以及可感知为具有光亮度的图像的图案或设计并且在其表面上设置多孔层4，其中低折射率颜料已经分散地固定在粘合剂树脂上，并且在液体吸收状态和液体不吸收状态之间的透明度不同，并且光光源5照射可拉伸部件的背面。绘图玩具组由绘图玩具1和施水工具15构成。

10. 发明授权

US07753680B2 Water-discoloring drawing toy and water-discoloring drawing toy set including the same 有权
标题翻译：水褪色绘画玩具和水褪色绘画玩具组包括相同
公开(公告)号：US07753680B2
公开(公告)日：2010-07-13
申请号：US11706386
申请日：2007-02-15
申请人： Akio Nakashima
发明人： Akio Nakashima
IPC分类号： G09B11/00
CPC分类号： B44D2/00 , B43L1/00
摘要： To provide: a water-discoloring drawing toy which, when a writing utensil or applicator for water adhesion is applied thereto, produces a multicolor image and which eliminates the monotonous production of monochromatic images in a related-art technique and is rich in unexpectedness and changes; and a water-discoloring drawing toy set including this drawing toy.A water-discoloring drawing toy 1 having such a constitution that a drawing made by applying a writing utensil or applicator for water adhesion produces a multicolor image, the drawing toy comprising: a substrate; many non-discoloring images differing in color tone and adjoining each other disposed on the substrate so that at least two color tones per 100 cm2 can be visually recognized in the part having the non-discoloring images; and a porous layer for preventing the non-discoloring images from being seen in the ordinary state, the porous layer being disposed over the non-discoloring images and comprising a binder resin and a low-refractive-index pigment fixed therein in a dispersed state, the porous layer having a difference in transparency between a liquid-impregnated state and an unimpregnated state. Also provided is a water-discoloring drawing toy set which comprises the water-discoloring drawing toy 1 and a writing utensil 3 or applicator for water adhesion.
摘要翻译：提供：一种褪色绘画玩具，当将用于水粘附的书写用具或涂布器施加到其上时，产生多色图像，并且消除了相关技术中单色图像的单调生成，并且具有丰富的意外和变化 ; 和一个包括这个绘画玩具的水褪色绘画玩具组。具有这样一种构造的水褪色绘画玩具1，其中通过应用用于水粘附的书写用具或涂抹器制成的图形产生多色图像，所述绘图玩具包括：衬底; 许多色调不同的非变色图像彼此相邻设置在基板上，使得在具有非变色图像的部分中可以视觉识别每100cm 2的至少两个色调; 以及用于防止在普通状态下看不到不变色图像的多孔层，所述多孔层设置在所述非变色图像上并且以分散状态包含粘合剂树脂和固定在其中的低折射率颜料，多孔层在液体浸渍状态和未浸渍状态之间的透明度差异。还提供了一种水褪色绘画玩具组，其包括水褪色绘画玩具1和书写用具3或用于水粘附的涂抹器。

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