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    • 7. 发明授权
    • Polythiourethane-based polymerizable composition and optical resin obtained from the same
    • 聚硫氨酯类聚合性组合物和由其得到的光学树脂
    • US08304506B2
    • 2012-11-06
    • US11990616
    • 2006-08-04
    • Akinori RyuMamoru TanakaKunio Okumura
    • Akinori RyuMamoru TanakaKunio Okumura
    • C08G18/00
    • C08G18/757C08G18/3876G02B1/041C08L75/04C08L81/00
    • Provided are a polymerizable composition for giving a resin which has a high refractive index and low dispersion, and is especially excellent in impact resistance and tintability; and a resin and an optical component each obtained by curing the composition. There used a polymerizable composition comprising (A) a compound represented by Formula (1) and/or by Formula (2), at least one compound as the following component (B), and at least one compound as the following component (C): (B) polythiol compounds optionally having at least one (poly)sulfide bond in a molecule, and (C) compounds represented by Formula (3): HO—[R1-(Y)n]m—R2-X  (3) (in above Formula (3), X is an OH group or a SH group; Y is an oxygen atom or a sulfur atom; R1 and R2 are each independently an optionally substituted methylene group or an optionally substituted alkylene group having carbon atoms of not smaller than 2 and not larger than 4; n is an integer of 0 or 1 when Y is an oxygen atom, or 0 or an integer of not smaller than 1 and not larger than 2 when Y is a sulfur atom; and m is 0 or an integer of not smaller than 1 and not larger than 3, provided that (carbon number of R1+n)×m+(carbon number of R2) is 3 or larger).
    • 提供一种用于赋予折射率高,分散性低的树脂的聚合性组合物,其耐冲击性和着色性特别优异; 以及通过固化该组合物而获得的树脂和光学部件。 使用包含(A)由式(1)表示的化合物和/或式(2)表示的化合物,至少一种下述成分(B)的化合物和至少一种下述成分(C)的化合物的聚合性组合物, :(B)分子中任选具有至少一个(多)硫键的多硫醇化合物,和(C)由式(3)表示的化合物:HO- [R1-(Y)n] m-R2-X(3) (上述式(3)中,X为OH基或SH基; Y为氧原子或硫原子; R 1和R 2各自独立地为任选取代的亚甲基或碳原子的任选取代的亚烷基 小于2且不大于4;当Y为氧原子时,n为0或1的整数,当Y为硫原子时,为0或1以上2以下的整数,m为0 (R1 + n的碳数)×m +(碳数R2)为3以上)的1或更大的3以上的整数。
    • 8. 发明申请
    • Polythiourethane-based polymerizable composition and optical resin obtained from the same
    • 聚硫氨酯类聚合性组合物和由其得到的光学树脂
    • US20090099329A1
    • 2009-04-16
    • US11990616
    • 2006-08-04
    • Akinori RyuMamoru TanakaKunio Okumura
    • Akinori RyuMamoru TanakaKunio Okumura
    • C08G18/30
    • C08G18/757C08G18/3876G02B1/041C08L75/04C08L81/00
    • Provided are a polymerizable composition for giving a resin which has a high refractive index and low dispersion, and is especially excellent in impact resistance and tintability; and a resin and an optical component each obtained by curing the composition. There used a polymerizable composition comprising (A) a compound represented by Formula (1) and/or by Formula (2), at least one compound as the following component (B), and at least one compound as the following component (C): (B) polythiol compounds optionally having at least one (poly)sulfide bond in a molecule, and (C) compounds represented by Formula (3): HO—[R1-(Y)n]m—R2-X  (3) (in above Formula (3), X is an OH group or a SH group; Y is an oxygen atom or a sulfur atom; R1 and R2 are each independently an optionally substituted methylene group or an optionally substituted alkylene group having carbon atoms of not smaller than 2 and not larger than 4; n is an integer of 0 or 1 when Y is an oxygen atom, or 0 or an integer of not smaller than 1 and not larger than 2 when Y is a sulfur atom; and m is 0 or an integer of not smaller than 1 and not larger than 3, provided that (carbon number of R1+n)×m+(carbon number of R2) is 3 or larger).
    • 提供一种用于赋予折射率高,分散性低的树脂的聚合性组合物,其耐冲击性和着色性特别优异; 以及通过固化该组合物而获得的树脂和光学部件。 使用包含(A)由式(1)表示的化合物和/或式(2)表示的化合物,至少一种下述成分(B)的化合物和至少一种下述成分(C)的化合物的聚合性组合物, :(B)分子中任选具有至少一个(多)硫键的多硫醇化合物,和(C)式(3)表示的化合物:<?在线式描述=“在线式”末端=“ 引线“→HO- [R1-(Y)n] m-R2-X(3)<?in-line-formula description =”In-line Formulas“end =”tail“?> ),X是OH基或SH基; Y是氧原子或硫原子; R 1和R 2各自独立地是任选取代的亚甲基或任选取代的碳原子数不小于2且不大于2的亚烷基 当Y为氧原子时,n为0或1的整数,Y为硫原子时为0或1以上2以下的整数,m为0以下的整数。 1以上3以下 (碳数R1 + n)×m +(碳数R2)为3以上)。