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    • 7. 发明授权
    • Carbon membrane laminated body and method for manufacturing the same
    • 碳膜层叠体及其制造方法
    • US07891499B2
    • 2011-02-22
    • US12471532
    • 2009-05-26
    • Akimasa IchikawaMiyuki Yabuki
    • Akimasa IchikawaMiyuki Yabuki
    • B01D69/12B01D71/06B01D71/64B01D67/00B01D53/22
    • B01D71/021B01D53/228B01D63/066B01D67/0067B01D69/12B01D69/125B01D2325/04
    • A carbon membrane laminated body includes: a porous substrate, a first porous carbon membrane as a carbon membrane underlayer disposed on a surface of the porous substrate, and a second porous carbon membrane as a carbon membrane separation layer disposed on a surface of the carbon membrane underlayer, having a smaller film thickness, and a smaller average pore diameter, compared with those of the carbon membrane underlayer. It is preferable to form the carbon membrane underlayer and the carbon membrane separation layer by carbonizing a carbon membrane underlayer precursor disposed on a surface of the porous substrate and the carbon membrane separation layer precursor disposed on a surface of the carbon membrane underlayer precursor at 400 to 1000° C. in a non-oxidation atmosphere. The carbon membrane laminated body is a separation membrane excellent in both separation performance and flux when it is used as a separation membrane of a mixture.
    • 碳膜层压体包括:多孔基材,作为设置在多孔基材的表面上的碳膜底层的第一多孔碳膜和设置在碳膜表面上的作为碳膜分离层的第二多孔碳膜 与碳膜底层相比具有更小的膜厚度和更小的平均孔径。 优选通过将设置在多孔基材的表面上的碳膜下层前体碳化和碳膜下层前体的碳膜分离层前体在400〜80℃下碳化来形成碳膜底层和碳膜分离层 1000℃,在非氧化气氛中。 碳膜层叠体是当用作混合物的分离膜时,分离性能和通量均优异的分离膜。