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    • 1. 发明授权
    • Colored low-expansion transparent glass ceramic
    • 彩色低膨胀透明玻璃陶瓷
    • US5010041A
    • 1991-04-23
    • US390771
    • 1989-08-08
    • Akihiro KoyamaKeiji KitamuraNobuyuki Yamamoto
    • Akihiro KoyamaKeiji KitamuraNobuyuki Yamamoto
    • C03C4/02C03C10/00C03C10/14
    • C03C10/0045C03C10/0027
    • A colored low-expansion transparent glass ceramic comprising 100 parts by weight of a base glass (a) having the following composition, the following coloring components (b) and the following auxiliary coloring component (c) mixed thereto in the following ratio, and in that the principal crystalline phase is .beta.-quartz solid solution.(a) Base glass______________________________________ (weight %) ______________________________________ LiO.sub.2 3.5 to 5.5 Na.sub.2 O 0 to 4.0 K.sub.2 O 0 to 4.0 Na.sub.2 O + K.sub.2 O 0.5 to 4.0 MgO 0.1 to 3.0 Al.sub.2 O.sub.3 20.5 to 23.0 SiO.sub.2 60.0 to 68.5 TiO.sub.2 1.0 to 7.0 ZrO.sub.2 0 to 3.5 TiO.sub.2 + ZrO.sub.2 3.5 to 7.0 P.sub.2 O.sub.5 0 to 4.0 ______________________________________ (b) Coloring components______________________________________ (part by weight) ______________________________________ CoO 0 to 0.02 Cr.sub.2 O.sub.3 0 to 0.05 MoO.sub.3 0 to 0.04 NiO 0 to 0.075 ______________________________________ (c) Auxiliary coloring componentAt least one selected from the group consisting of______________________________________ (part of weight) ______________________________________ Cl 0 to 0.6 Br 0 to 0.4, and I 0 to 0.03 ______________________________________ The total amount of auxiliary component is 0.002 to 0.7 part by weight.In order to produce such glass ceramic, a raw material so prepared as to produce a glass ceramic having a composition comprising 100 parts by weight of the base glass (a) having the above-described composition, the coloring components (b) and the auxiliary coloring components (c) mixed thereto in the above-described ratio is melted and cooled and the thus-obtained glass ceramic is heat treated so as to form .beta.-quartz solid solution crystals as the principal crystalline phase.
    • 包含100重量份具有以下组成的基础玻璃(a)的着色低膨胀透明玻璃陶瓷,以下列比例混合以下着色组分(b)和以下辅助着色组分(c),并在 主晶相为β-石英固溶体。 (a)基础玻璃 - (重量%)-LiO2 3.5〜5.5 -Na2O 0〜4.0-K2O 0〜4.0 -Na2O + K2O 0.5〜4.0 -MgO 0.1〜3.0 -Al2O3 20.5〜23.0 -SiO2 60.0〜68.5 -TiO2 1.0 至7.0-ZrO 2至3.5 -TiO 2 + ZrO 2 3.5至7.0 -P 2 O 5 0至4.0 - (b)着色组分 - (重量份)-CoO 0至0.02 -Cr 2 O 3 0至0.05-MoO 3 0至0.04 -NiO 0至 0.075 - (c)辅助着色成分选自 - (重量份数)-Cl 0〜0.6 -Br 0〜0.4,-I 0〜0.03的至少一种 - 辅助成分的总量为0.002〜 0.7重量份。 为了制造这种玻璃陶瓷,制备如下制备的玻璃陶瓷的原料,该玻璃陶瓷的组成包含100重量份具有上述组成的基础玻璃(a),着色组分(b)和助剂 将以上述比例混合的着色组分(c)熔化并冷却,将由此得到的玻璃陶瓷进行热处理,形成作为主晶相的β-石英固溶体晶体。
    • 3. 发明授权
    • Glass composition and substrate for information recording medium
    • 用于信息记录介质的玻璃组合物和底物
    • US06399527B1
    • 2002-06-04
    • US09401126
    • 1999-09-22
    • Shoichi KishimotoAkihiro KoyamaJunji KurachiNobuyuki Yamamoto
    • Shoichi KishimotoAkihiro KoyamaJunji KurachiNobuyuki Yamamoto
    • C03C3085
    • C03C3/085C03C3/087
    • A glass composition having a high Young's modulus and a low density is disclosed which can be mass-produced by a continuous process and easily made to have high surface smoothness. Also disclosed are a substrate including the glass composition and reduced in bending and resonance even upon high-speed rotation, a recording medium usable at a lower flying height, and an information recording device having a higher recording capacity and a shorter access time. The glass composition includes, in terms of mol %, 40 to 55% silicon dioxide (SiO2), 0.5 to 6% aluminum oxide (Al2O3), 2 to 20% lithium oxide (Li2O), 0 to 10% sodium monoxide ((Na2O), 2 to 30% R2O (R2O=Li2O+Na2O), 5 to 25% magnesium oxide (MgO), 0 to 25% calcium oxide (CaO), 0 to 10% strontium oxide (SrO), 10 to 40% RO (RO=MgO+CaO+SrO), 0 to 10% titanium dioxide (TiO2), and 0 to 5% zirconium oxide (ZrO2).
    • 公开了具有高杨氏模量和低密度的玻璃组合物,其可以通过连续工艺大量生产并且易于制成具有高表面平滑度。 还公开了包括玻璃组合物的基底,即使在高速旋转时减少弯曲和共振,可以在较低飞行高度下使用的记录介质,以及具有较高记录容量和较短访问时间的信息记录装置。 玻璃组合物以摩尔%计包含40至55%的二氧化硅(SiO 2),0.5至6%的氧化铝(Al 2 O 3),2至20%的氧化锂(Li 2 O),0至10%的一氧化钠((Na 2 O) ),2〜30%的R2O(R2O = Li2O + Na2O),5〜25%的氧化镁(MgO),0〜25%的氧化钙(CaO),0〜10%的氧化锶(SrO),10〜40%的RO (RO = MgO + CaO + SrO),0〜10%的二氧化钛(TiO 2)和0〜5%的氧化锆(ZrO 2)。
    • 7. 发明授权
    • Heat-resistant glass composition
    • 耐热玻璃组合物
    • US5925583A
    • 1999-07-20
    • US927532
    • 1997-09-11
    • Tetsuro YoshiiAkihiro KoyamaHiroyuki TanakaNobuyuki YamamotoShigekazu Yoshii
    • Tetsuro YoshiiAkihiro KoyamaHiroyuki TanakaNobuyuki YamamotoShigekazu Yoshii
    • G02F1/1333C03C3/087G09F9/30
    • C03C3/087
    • A heat-resistant glass composition which comprises, in % by weight; 56 to 68% of SiO.sub.2, 0.2 to 5% of Al.sub.2 O.sub.3, 0 to 6.4% of ZrO.sub.2, 0 to 0.5% of Li.sub.2 O, 0.2 to 8% of Na.sub.2 O, 2.5 to 14% of K.sub.2 O, 1 to 7% of MgO, 2 to 12% of CaO, 0 to 12% of SrO, 0 to 13% of BaO, 0 to 2% of ZnO, 0 to 1% in total of SO.sub.3 and Sb.sub.2 O.sub.3, and 0 to 3% of TiO.sub.2, with the proviso of the total amount of Na.sub.2 O and K.sub.2 O being 7 to 17%, the total amount of MgO and CaO being 7 to 15%, the total amount of SrO and BaO being 4 to 18%, the total amount of MgO, CaO, SrO, and BaO being 15 to 27%, and the total amount of SiO.sub.2, Al.sub.2 O.sub.3, and ZrO.sub.2 being 58% or more, and which has an average thermal expansion coefficient of 75.times.10.sup.-7 to 100.times.10.sup.-7 /K at 50 to 350.degree. C. and a strain point of 530.degree. C. or more. The heat-resistant glass composition has substantially the same thermal expansion coefficient as that of a soda-lime glass used as a window pane of buildings and a strain point than that of the soda-lime glass.
    • 一种耐热玻璃组合物,其以重量%计; 56〜68%的SiO2,0.2〜5%的Al2O3,0〜6.4%的ZrO2,0〜0.5%的Li2O,0.2〜8%的Na2O,2.5〜14%的K2O,1〜7%的MgO,2 至12%的CaO,0〜12%的SrO,0〜13%的BaO,0〜2%的ZnO,0〜1%的SO 3和Sb 2 O 3,0〜3%的TiO 2, Na2O和K2O的总量为7〜17%,MgO和CaO的总量为7〜15%,SrO和BaO的总量为4〜18%,MgO,CaO,SrO和 BaO为15〜27%,SiO 2,Al 2 O 3和ZrO 2的总量为58%以上,在50〜350℃下的平均热膨胀系数为75×10 -7〜100×10 -7 / K, 应变点为530℃以上。 耐热玻璃组合物具有与用作建筑物窗玻璃的钠钙玻璃和应变点大致相同的热膨胀系数,而不是钠钙玻璃。