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    • 2. 发明授权
    • Method for producing Nb3Al superconductive wire
    • 生产Nb3Al超导线的方法
    • US07134181B2
    • 2006-11-14
    • US10513857
    • 2003-12-25
    • Kiyoshi InoueAkihiro KikuchiYasuo IijimaTakao Takeuchi
    • Kiyoshi InoueAkihiro KikuchiYasuo IijimaTakao Takeuchi
    • H01L39/24
    • H01L39/2409C22F1/18Y10T29/49014Y10T29/49117
    • A superfine multi-core Nb3Al superconductive wire is produced by getting a Nb3Al superconductive wire ready which was obtained by subjecting a precursor wire having a superfine multi-core structure in which a plurality of Nb/Al complex cores are embedded in Nb, Ta, a Nb based dilute alloy, or a Ta based dilute alloy as the matrix to a rapid heating and quenching treatment comprising rapidly heating to a temperature range near 2,000° C. in 2 seconds, (A) coating the Nb3Al superconductive wire with Cu or Ag as the stabilizing material; then (B) subjecting to a hot isostatic press (HIP) process for 10 minutes or more in a inert gas environment with a pressure of 40 atmospheres or more; and then (C) subjecting heat treatment for 1–200 hours in temperature range of 680–850° C., to thereby obtain a method for producing Nb3Al superconductive wire and the Nb3Al superconductive wire obtained from said method in which: the cost is comparatively low; the wire may be produced to be either round or flat; and the superconductive characteristics is more stabilized.
    • 通过获得通过对具有超细多芯结构的母体线进行处理而获得的Nb 3 Al 3 Al超导线,制造超细多芯Nb 3 Al超导线 其中在Nb,Ta,Nb基稀释合金或Ta基稀释合金中嵌入多个Nb / Al复合芯作为基体,用于快速加热和淬火处理,其包括快速加热至接近2000℃的温度范围 在2秒钟内,(A)用Cu或Ag作为稳定材料涂覆Nb 3 Al 3 Al超导线; 然后(B)在40个大气压或更大的压力的惰性气体环境中进行热等静压(HIP)处理10分钟或更长时间; 然后(C)在680-850℃的温度范围内进行热处理1-200小时,从而获得Nb 3 Al超导线的制造方法和Nb 3 从所述方法获得的超导线,其中:成本相对较低; 电线可以是圆形或扁平的; 超导特性更稳定。
    • 3. 发明授权
    • Process for the production of Nb3A1 extra-fine multifilamentary superconducting wire
    • 生产Nb3A1超细多丝超导线的工艺
    • US06508889B2
    • 2003-01-21
    • US09826826
    • 2001-04-06
    • Akihiro KikuchiYasuo IijimaKiyoshi Inoue
    • Akihiro KikuchiYasuo IijimaKiyoshi Inoue
    • H01B1200
    • B21C37/04B32B15/017C22C27/02C22F1/18H01L39/2409Y10S420/901Y10S505/806Y10S505/815Y10T29/49014
    • A high-performance Nb3Al extra-fine multifilamentary superconducting wire is produced simply and inexpensively through the improvement of critical values, Tc, Hc2 and Jc, without the addition of third elements such as Ge, Si and Cu. A first rapid heating and quenching treatment is applied to an Nb/Al composite wire having an atomic ratio of Al to Nb from 1:2.5 to 1:3.5 and having an extra-fine multifilamentary structure to form a BCC alloy phase comprising Nb with Al supersaturatedly dissolved therein wherein the treatment comprises heating the composite wire up to a temperature not lower than 1900° C. within two seconds and then introducing it into a molten metal at a temperature not higher than 400° C. to rapidly quench it. The wire is subjected to a second rapid heating and quenching treatment to form an A15-Nb3Al compound having a low degree of crystalline order but having an approximately stoichiometric composition wherein the second treatment comprises heating the wire up to a temperature not lower than 1500° C. within two seconds and then introducing it into a molten metal at a temperature not higher than 400° C. Then, an additional heat treatment is conducted to improve the degree of crystalline order of the Al5-Nb3Al compound having an approximately stoichiometric composition.
    • 通过提高临界值Tc,Hc2和Jc,不需要添加诸如Ge,Si和Cu的第三元素,简单且廉价地制造高性能Nb3Al超细多丝超导线。 对原子比为Al:Nb的Nb / Al复合线进行第一快速加热淬火处理,其比例为1:2.5〜1:3.5,并且具有超细多丝结构,以形成含有Nb的BCC合金相,Al 过饱和溶解在其中,其中处理包括在两秒钟内将复合线材加热至不低于1900℃的温度,然后在不高于400℃的温度下将其引入熔融金属中以快速淬火。 对线材进行第二次快速加热淬火处理以形成具有低结晶度但具有近似化学计量组成的A15-Nb3Al化合物,其中第二处理包括将线材加热至不低于1500℃的温度 然后在不高于400℃的温度下将其引入熔融金属中,然后进行额外的热处理,以提高具有大致化学计量组成的Al5-Nb3Al化合物的结晶度。
    • 5. 发明授权
    • Process for producing ultrafine multifilamentary Nb3(A1,Ge) or Nb3(A1,Si) superconducting wire
    • 超细多晶Nb3(A1,Ge)或Nb3(A1,Si)超导线生产工艺
    • US06372054B1
    • 2002-04-16
    • US09585419
    • 2000-06-02
    • Akihiro KikuchiYasuo IijimaKiyoshi Inoue
    • Akihiro KikuchiYasuo IijimaKiyoshi Inoue
    • H01B1200
    • H01L39/2409Y10S505/918Y10S505/919
    • A process for producing an ultrafine multifilamentary superconducting Nb3(Al,Ge) wire capable of generating a high critical current density comprising: preparing a composite core material comprising an A1—(2-30)at. % Ge alloy (where at. % represents % by atomic) 1 &mgr;m or less in thickness uniformly incorporated into a Nb matrix at a volume ratio in a range of 1:2.5 to 1:3.5 and forming a composite therewith; fabricating a composite wire having an ultrafine multifilamentary structure by embedding several tens to several millions of the resulting composite core materials in a cylindrical matrix material containing Nb; forming a A15-phase filament having a lower order in crystallinity inside the composite wire by a rapid heating and quenching treatment comprising rapidly heating to a temperature of 1,700° C. or higher in 2 seconds, followed by continuously introducing it into a molten metal; coating the composite wire with copper (Cu) which functions as a superconductivity stabilizing material; and applying a post heat treatment in the temperature range of from 650 to 900° C. to the resulting product to recover the degree of crystallinity of the Nb3(Al,Ge) in the A15 compound.
    • 一种生产能够产生高临界电流密度的超细多丝超导Nb 3(Al,Ge)线的方法,包括:制备包含A1-(2-30)的复合芯材。 %Ge合金(其中原子%代表原子%)1μm或更小的厚度均匀地掺入Nb基体中,体积比为1:2.5至1:3.5,并与其形成复合物; 通过将几十到数百万的所得复合芯材料嵌入含有Nb的圆柱形基体材料中制造具有超细多丝结构的复合线; 通过快速加热和淬火处理形成在复合线内部具有低结晶度的A15相丝,其包括在2秒内迅速加热至1700℃或更高的温度,随后将其连续引入熔融金属中; 用作为超导稳定材料的铜(Cu)涂覆复合线; 并在650〜900℃的温度范围内对所得到的产物进行后热处理,以回收A15化合物中Nb3(Al,Ge)的结晶度。
    • 8. 发明申请
    • Process for producing nb3a1 superconductive wire rod and nb3a1 superconductive wire rod produced by the process
    • 生产nb3a1超导线材和nb3a1超导线材的工艺
    • US20050176587A1
    • 2005-08-11
    • US10513857
    • 2003-12-25
    • Kiyoshi InoueAkihiro KikuchiYasuo IijimaTakao Takeuchi
    • Kiyoshi InoueAkihiro KikuchiYasuo IijimaTakao Takeuchi
    • C22F1/00C22C27/02C22F1/18H01B1/00H01B12/10H01B13/00H01L39/24
    • H01L39/2409C22F1/18Y10T29/49014Y10T29/49117
    • A superfine multi-core Nb3Al superconductive wire is produced by getting a Nb3Al superconductive wire ready which was obtained by subjecting a precursor wire having a superfine multi-core structure in which a plurality of Nb/Al complex cores are embedded in Nb, Ta, a Nb based dilute alloy, or a Ta based dilute alloy as the matrix to a rapid heating and quenching treatment comprising rapidly heating to a temperature range near 2,000° C. in 2 seconds, (A) coating the Nb3Al superconductive wire with Cu or Ag as the stabilizing material; then (B) subjecting to a hot isostatic press (HIP) process for 10 minutes or more in a inert gas environment with a pressure of 40 atmospheres or more; and then (C) subjecting heat treatment for 1-200 hours in temperature range of 680-850° C., to thereby obtain a method for producing Nb3Al superconductive wire and the Nb3Al superconductive wire obtained from said method in which: the cost is comparatively low; the wire may be produced to be either round or flat; and the superconductive characteristics is more stabilized.
    • 通过获得通过对具有超细多芯结构的母体线进行处理而获得的Nb 3 Al 3 Al超导线,制造超细多芯Nb 3 Al超导线 其中在Nb,Ta,Nb基稀释合金或Ta基稀释合金中嵌入多个Nb / Al复合芯作为基体,用于快速加热和淬火处理,其包括快速加热至接近2000℃的温度范围 在2秒钟内,(A)用Cu或Ag作为稳定材料涂覆Nb 3 Al 3 Al超导线; 然后(B)在40个大气压或更大的压力的惰性气体环境中进行热等静压(HIP)处理10分钟或更长时间; 然后(C)在680-850℃的温度范围内进行热处理1-200小时,从而获得Nb 3 Al超导线的制造方法和Nb 3 从所述方法获得的超导线,其中:成本相对较低; 电线可以是圆形或扁平的; 超导特性更稳定。
    • 9. 发明授权
    • Multifilament Nb.sub.3 Al superconducting linear composite articles
    • 多丝Nb3Al超导线性复合制品
    • US4917965A
    • 1990-04-17
    • US315825
    • 1989-02-24
    • Kiyoshi InoueTakao TakeuchiYasuo IijimaMichio Kosuge
    • Kiyoshi InoueTakao TakeuchiYasuo IijimaMichio Kosuge
    • H01L39/14
    • H01L39/14Y10S428/93Y10S505/813Y10T428/12486
    • A long, linear composite article which is characterized in that a large number of composite filaments are present as spaced from one another in a continuous layer composed of copper, a copper alloy, niobium, tantalum or vanadium, each of said composite filaments having a structure that at least one strand of a linear body is surrounded by an aluminum alloy or niobium, said linear body being composed substantially of extremely fine, filamentary superconducting Nb.sub.3 Al compound having an average diameter of from about 0.03 .mu.m to about 1 .mu.m. The said composite article can be prepared by drawing a composite material composed of (a) an aluminum alloy and (b) niobium, together with copper or a copper alloy once or plural times repeatedly, until the average diameter of the aluminum alloy of (a) becomes about 1 .mu.m or less, and heat-treating the resultant linear composite material. This composite articles exhibit excellent superconducting characteristics in high-magnetic field and alternating-current magnetic field.
    • 一种长线型复合制品,其特征在于,在由铜,铜合金,铌,钽或钒构成的连续层中以大量的复合长丝彼此间隔开地存在,所述复合长丝具有结构 线状体的至少一根线被铝合金或铌包围,所述直线体基本上由平均直径为约0.03μm至约1μm的极细微细的超导Nb 3 Al化合物组成。 所述复合制品可以通过将(a)铝合金和(b)铌与铜或铜合金一起重复复制一次或多次制成的复合材料制备,直到(a)的铝合金的平均直径 )为1μm以下,对所得的线状复合材料进行热处理。 该复合材料在高磁场和交流磁场中表现出优异的超导特性。