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    • 1. 发明授权
    • Liquid photocurable compositions
    • 液体光固化组合物
    • US06025114A
    • 2000-02-15
    • US913466
    • 1997-09-11
    • Ajay Haridas PopatJohn Robert Lawson
    • Ajay Haridas PopatJohn Robert Lawson
    • B29C67/00C08F2/48C08F290/06G03C9/08G03F7/00G03F7/027G03F7/028
    • G03F7/0037G03F7/027
    • 1. This invention relates to a liquid composition comprising:a) 2 to 20 parts of a monomeric poly(meth)acrylate having a functionality of at least 3 and a MW of at least 650;b) 20 to 60 parts of a urethane(meth)acrylate having a functionality of 2 to 4 and a MW of 400 to 10,000;c) 20 to 80 parts of a monomeric or oligomeric di(meth)acrylate based on bisphenol A or bisphenol F; andd) 0.1 to 10 parts of a photoinitiator;wherein all parts are by weight and the total number of parts of a)+b)+c)+d) add up to 100.The compositions are suitable for the stereolithographic production of three-dimensional articles such as models of mechanical and body parts and are particularly notable for their low curl & shrinkage coupled with fast rate of cure.
    • PCT No.PCT / GB96 / 00518 Sec。 371日期:1997年9月11日 102(e)1997年9月11日PCT PCT 1996年3月6日PCT公布。 公开号WO96 / 28763 本发明涉及一种液体组合物,其包含:a)2至20份官能度至少为3且MW至少为650的单体聚(甲基)丙烯酸酯; b)20〜60份官能度为2〜4,MW为400〜10,000的氨基甲酸酯(甲基)丙烯酸酯; c)20至80份基于双酚A或双酚F的单体或低聚二(甲基)丙烯酸酯; 和d)0.1至10份光引发剂; 其中所有份数均为重量,a)+ b)+ c)+ d)的总数为d)加起来为100.该组合物适用于三维制品的立体光刻产生,例如机械和身体部位的模型 并且特别值得注意的是它们的低卷曲和收缩加上快速的固化速度。
    • 3. 发明授权
    • Free radical polymerisation process
    • 自由基聚合过程
    • US5684101A
    • 1997-11-04
    • US727659
    • 1996-10-11
    • Andrew Victor Graham MuirJohn Robert LawsonDavid Mark Haddleton
    • Andrew Victor Graham MuirJohn Robert LawsonDavid Mark Haddleton
    • C07F5/02C08F2/38C08F4/12C08F4/70
    • C07F5/022C08F2/38
    • Process for the free-radical polymerization of at least one olefinically unsaturated monomer, the polymerization being performed in the presence of a compound for effecting molecular weight control, being a CoII chelate of the following formula: ##STR1## wherein each group X is a divalent group which forms with the two carbon atoms to which it is bonded a pericondensed polycyclic group, being a group having 3 or more carbocyclic rings where the oxime-containing carbocyclic ring has carbon atoms in common with 2 or more of the other rings, the polycyclic group being unsubstituted (apart from the oxime groups) or having at least one hydrocarbyl substituent; and wherein each group Q is independently selected from F, Cl, Br, OH, C.sub.1-12 alkoxy, aryloxy, C.sub.1-12 alkyl and aryl; or two Q groups taken together provide on one or both boron atoms a group --O--(G)--O-- where G is a divalent aryl or alicyclic linking group or an alkylene linking group; or two Q groups taken together on one or both boron atoms provide a 1,5-cyclooctanediyl linking group; or being a CoIII analogue of the cobalt II chelate in which the Co atom is additionally covalently bonded to H, a halide or other anion, or a homolytically dissociable organic group. Novel Co chelates for use in the process are also disclosed.
    • PCT No.PCT / GB95 / 00577 Sec。 371日期:1996年10月11日 102(e)日期1996年10月11日PCT 1995年3月17日PCT公布。 出版物WO95 / 27737 日期1995年10月19日至少一种烯属不饱和单体的自由基聚合的方法,该聚合是在用于进行分子量控制的化合物存在下进行的,作为下式的CoII螯合物:其中 每个基团X是与其键合的两个碳原子形成的二价基团,它是具有3个或更多个碳环的基团,其中含肟的碳环具有与2个或更多个碳原子共同的碳原子 其他环,多环基团是未取代的(除了肟基团)或具有至少一个烃基取代基; 并且其中每个基团Q独立地选自F,Cl,Br,OH,C 1-12烷氧基,芳氧基,C 1-12烷基和芳基; 或两个Q基团在一个或两个硼原子上提供基团-O-(G)-O-,其中G是二价芳基或脂环连接基团或亚烷基连接基团; 或一个或两个硼原子一起取代的两个Q基团提供1,5-环辛二基连接基团; 或者是钴II螯合物的CoIII类似物,其中Co原子另外共价键合到H,卤化物或其它阴离子,或者是均质解离的有机基团。 还公开了用于该方法的新型Co螯合物。