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1. 发明专利

JPS6172738A Catechol derivative useful as carrier for ion selective electrode 失效
标题翻译： CATECHOL衍生用作离子选择电极的载体
公开(公告)号：JPS6172738A
公开(公告)日：1986-04-14
申请号：JP19548884
申请日：1984-09-18
申请人： Agency Of Ind Science & Technol
发明人： SUGIHARA HIDEKI , HIRATANI KAZUHISA , OKADA TATSUHIRO
IPC分类号： G01N27/333 , C07C231/02 , C07C233/18 , C07C233/68 , G01N27/30
摘要： NEW MATERIAL:Compds. expressed by formula I (R
1 and R
2 are H, alkyl, aromatic hydrocarbon group or alkyl aromatic group, R
3 is alkyl, aromatic hydrocarbon group or alkyl aromatic group, n is 1W3).
EXAMPLE: 1,2-Bis[3-(n-octanoylamino)propoxy]-4-t-butylbenzene.
USE: A carrier for ion selective electrode. Especially when the campd. coexist with plasticizers and hydrophobic anions in a polymer membrane, they show selective electromotive response to specific cations depending on the composition of the membrane.
PREPARATION: A catechol derivative expressed by formula II and an acyl chloride are reacted in the presence of a tertiary amine, in an inert solvent at -20°CW room temp., to give the compd. expressed by formula I.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：Compds 由式I（R 1和R 2）表示为H，烷基，芳族烃基或烷基芳基，R 3为烷基，芳族烃基或烷基芳基，n为1-3）。实施例：1,2-双[3-（正辛酰基氨基）丙氧基] -4-叔丁基苯。用途：离子选择电极载体。特别是营地时。与聚合物膜中的增塑剂和疏水阴离子共存，它们根据膜的组成显示对特定阳离子的选择性电动反应。制备：将式II表示的儿茶酚衍生物和酰氯在叔胺的存在下，在惰性溶剂中，在-20℃ - 室温下反应，得到化合物。由公式I表示。

2. 发明专利

JPS59216847A Polyether derivative useful as ionophore 失效
标题翻译：聚醚衍生物作为离子源有用
公开(公告)号：JPS59216847A
公开(公告)日：1984-12-06
申请号：JP1198683
申请日：1983-01-27
申请人： Agency Of Ind Science & Technol
发明人： TAGUCHI KAZUHIRO , HIRATANI KAZUHISA , SUGIHARA HIDEKI , IIO SHIN
IPC分类号： C09K3/00 , C07C51/00 , C07C51/347 , C07C65/21 , C07C67/00
CPC分类号： Y02P20/55
摘要： NEW MATERIAL:A polyether derivative shown by the formula I [R
1 , R
2 , and R
3 are H, or alkyl; R
4 is substituent group containing two or more of H, alkyl, benzyl, 2-phenylethyl, 3-(naphthyl-1-oxy)propyl, 2-propyleneoxyphenoxy unit as repeating units].
EXAMPLE: 1-[ 3'-(O-Carboxylphenoxy)propyloxy ]-2-( 3'-O-ethoxyphenyloxy )propyloxy-4-t-butylbenzene.
USE: Useful as a cationic carrier (ionophore). Acting selectively especially on lithium ion, capable of transporting it against concentration gradient.
PREPARATION: A polyether derivative shown by the formula II (R
5 is reaction protecting group) is hydrolyzed under alkali conditions, to give a compound shown by the formula I .
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：由式I [R 1，R 2和R 3]表示的聚醚衍生物是H或烷基; R 4是含有H，烷基，苄基，2-苯基乙基，3-（萘基-1-氧基）丙基，2-丙烯氧基苯氧基单元作为重复单元的两个或更多个的取代基。实施例：1- [3' - （O-羧基苯氧基）丙氧基] -2-（3'-O-乙氧基苯氧基）丙氧基-4-叔丁基苯。用途：用作阳离子载体（ionophore）。特别是对锂离子进行选择，能够将其与浓度梯度进行运输。制备：在碱性条件下水解式II所示的聚醚衍生物（R 5为反应保护基），得到式I所示的化合物。

3. 发明专利

JPS6172737A Catechol derivative useful as carrier for ion selective electrode 失效
标题翻译： CATECHOL衍生用作离子选择电极的载体
公开(公告)号：JPS6172737A
公开(公告)日：1986-04-14
申请号：JP19548984
申请日：1984-09-18
申请人： Agency Of Ind Science & Technol
发明人： SUGIHARA HIDEKI , HIRATANI KAZUHISA , OKADA TATSUHIRO
IPC分类号： G01N27/333 , C07C67/00 , C07C231/00 , C07C231/02 , C07C235/20 , C07C235/24 , C25B11/08
摘要： NEW MATERIAL:Compds. expressed by formula I (R
1 is H, alkyl, aromatic hydrocarbon group or alkylaromatic group; R
2 and R
3 same as R
1 and at least one of each is alkyl, aryl or alkylaryl group; n is 1W3).
EXAMPLE: 1,2-Bis(N-n-octylaminocarbonylmethoxy)benzene.
USE: It is useful as a cation carrier in a polymeric membrane for ion selective electrode. When plasticizers and hydrophobic anions coexist in the polymer membrane, the compds. show selective electromotive response especially for calcium ion, so the activity of calcium ion can be measured in the presence of alkaline metal ions, except calcium ion, and ammonium ion.
PREPARATION: A biscarboxylic acid chloride expressed by formula III and two equiv. of a primary or secondary amine are acylated in an inert solvent, in the presence of a tertiary amine at -20°CW room temp., to obtain the compd. expressed by formula I.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：Compds 由式I表示（R 1是H，烷基，芳族烃基或烷基芳基; R 2和R 3与R 1相同，并且其中至少一个是烷基，芳基或烷基芳基; n为1-3）。实施例：1,2-双（N-正辛基氨基羰基甲氧基）苯。用途：作为离子选择电极聚合物膜中的阳离子载体是有用的。当增塑剂和疏水性阴离子共存在聚合物膜中时，显示出对钙离子的选择性电动反应，因此钙离子的活性可以在碱金属离子（钙离子和铵离子除外）的存在下测定。制备：由式III表示的双羧酸氯化物和2当量的伯胺或仲胺在惰性溶剂中，在叔胺存在下，在-20℃ - 室温下酰化，得到化合物。由公式I表示。

4. 发明专利

JPS6147714A Graft polymerization process 失效
标题翻译： GRAFT聚合方法
公开(公告)号：JPS6147714A
公开(公告)日：1986-03-08
申请号：JP16968584
申请日：1984-08-14
申请人： Agency Of Ind Science & Technol
发明人： AIBA SEIICHI , HIRATANI KAZUHISA
IPC分类号： C08F2/00 , C08F2/48 , C08F2/54 , C08F285/00 , C08F291/00
摘要： PURPOSE: To obtain a graft polymer suitable as a medical material, etc., without causing the degradation of the substrate, by carrying out the graft polymerization of a radically polymerizable first monomer to a polymeric substrate under the action of radiation, and then polymerizing the second monomer under the action of light or heat.
CONSTITUTION: (A) The radically polymerizable first monomer such as ethylene, acrylic acid (ester), etc. is polymerized to (B) a polymeric solid substrate made of polyethylene, polytetrafluoroethylene, etc. and having the form of powder, film, etc., at a grafting ratio of 1W50wt%, under irradiation with high-energy radiation such as electron ray, γ-ray, etc. at a dose of 0.1W5Mrad. The grafted polymer is made to react with (C) a carboxylic acid, amine, etc. having a functional group which decomposes with heat or light, e.g. dithiocarbamate group. (D) The second grafting monomer is polymerized to the product at a grafting ratio of preferably 1W10,000wt% under the action of light or heat, to obtain the objective polymer.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过在放射线的作用下进行可自由基聚合的第一单体到聚合物基质的接枝聚合，获得适合作为医疗材料等的接枝聚合物而不引起底物的降解，然后将第二单体在光或热的作用下。（A）将可自由基聚合的第一单体如乙烯，丙烯酸（酯）等聚合成（B）由聚乙烯，聚四氟乙烯等制成的具有粉末，薄膜等形式的聚合物固体基材在0.1-5Mrad的剂量下，以高能量辐射如电子射线，γ射线等照射，以1-50wt％的接枝比例。使接枝聚合物与（C）具有通过热或光分解的官能团的羧酸，胺等反应。二硫代氨基甲酸盐组。（D）第二接枝单体在光或热的作用下以接枝比优选1-10,000wt％聚合成产物，得到目标聚合物。

5. 发明专利

JPS59163342A Cation transferring method using dicarboxylic acid polyether derivative as carrier to transfer alkaline earth metal ion 失效
标题翻译：使用二羧酸聚醚衍生物作为载体转移碱金属离子的载体转移方法
公开(公告)号：JPS59163342A
公开(公告)日：1984-09-14
申请号：JP3863683
申请日：1983-03-08
申请人： Agency Of Ind Science & Technol
发明人： HIRATANI KAZUHISA , TAGUCHI KAZUHIRO , SUGIHARA HIDEKI , IIO SHIN
IPC分类号： C09K3/00 , B01D11/04 , B01D15/00 , B01J45/00 , B01J47/00 , C07C65/21
CPC分类号： Y02P20/55
摘要： NEW MATERIAL:The compound of formula I (n is 2 or 3; R and R are H or alkyl). EXAMPLE:1,2-Bis {3'-(o-carboxyphenyloxy)propyloxy}-4-t-butylbenzene. USE:A cation transfer agent (ionophore) acting selectively to an alkaline earth metal ion, having variable selective transfer capability of the above ion according to the structure and the condition of transfer, and capable of transferring the cation against the concentration gradient. PREPARATION:The objective compound of formula I can be prepared by reacting the compound of formula III with the compound of formula IV (R is protecting group) in an alkaline medium at 30-150 deg.C, especially 60-120 deg.C, and hydrolyzing the resultant compound of formula V by conventional method. When the compound is used as an ionophore, and two kinds of solutions A and B are contacted indirectly interposing the solution of the ionophore M between them, the cation contained in the solution A can be transferred to the solution B.
摘要翻译：新材料：式I化合物（n为2或3; R 1和R 2为H或烷基）。实施例：1,2-双（3' - （邻 - 羧基苯氧基）丙氧基} -4-叔丁基苯。用途：选择性地对碱土金属离子起作用的阳离子转移剂（离子载体），其具有根据结构和转移条件的上述离子的选择性转移能力，并能够相对于浓度梯度转移阳离子。制备：式I的目的化合物可以通过使式III化合物与式IV化合物（R 3是保护基）在碱性介质中在30-150℃，特别是60-120度并通过常规方法水解得到的式V化合物。当化合物用作离子载体时，并且两种溶液A和B在它们之间间接插入离子载体M的溶液时，溶液A中所含的阳离子可以转移到溶液B中。

6. 发明专利

JPS57119805A Catalytic membrane for hydrolysis 失效
标题翻译：用于水解的催化膜
公开(公告)号：JPS57119805A
公开(公告)日：1982-07-26
申请号：JP607281
申请日：1981-01-19
申请人： Agency Of Ind Science & Technol
发明人： AIBA SEIICHI , HIRATANI KAZUHISA , NAKAGAWA TSUTOMU
IPC分类号： B01D67/00 , B01D71/28 , B01D71/36 , B01D71/78 , B01D71/82 , B01J14/00 , B01J31/06 , B01J31/10 , B01J33/00 , B01J35/02 , C07B41/00 , C13K1/06
CPC分类号： C13K1/06 , B01D61/00 , B01D67/0093 , B01D71/32 , B01D2311/2696 , B01D2323/385 , B01J14/005 , B01J31/10 , B01J35/02
摘要： PURPOSE: To obtain a water-isoluble porous polymer membrane which catalyzes hydrolysis of polysaccharides and separates oligosaccharides which are the product through selective permeation by using a porous polytetrafluoroethylene membrane as a backing material and bonding polystyrene sulfonic acid thereto.
CONSTITUTION: A porous polytetrafluoroethylene membrane is immersed in mixed solns. of styrene and benzene, and γ rays are irradiated thereto to bond sulfonic acid groups to the polystyrene part which is grafted after washing, whereby a water insoluble polymer membrane is obtained. A chamber is segmented to two by such porous polymer membrane. If an aq. soln. of polysaccharides is filled in one of the section and water in the other section, the polysaccharides are hydrolyzed to oligosaccharides of low molecules by the catalytic effect of this porous polymer membrane, and are separated into the section filled with water through the membrane. In this way, the production of oligosaccharides from polysaccharides is made possible.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：获得催化多糖水解的水分多孔聚合物膜，并通过使用多孔聚四氟乙烯膜作为背衬材料并将聚苯乙烯磺酸粘合在一起，将作为产品的产品通过选择性渗透分离出来。构成：将多孔聚四氟乙烯膜浸入混合溶液中。的苯乙烯和苯，并且照射γ射线以将磺酸基团与洗涤后接枝的聚苯乙烯部分结合，由此获得水不溶性聚合物膜。通过这种多孔聚合物膜将室分成两个。如果一个水平索恩的多糖填充在另一部分中的一个部分和水中，通过该多孔聚合物膜的催化作用将多糖水解成低分子量的低聚糖，并通过该膜分离成填充有水的部分。以这种方式，可以从多糖制备寡糖。

7. 发明专利

JPS5732701A Solute permeating device 失效
标题翻译：溶剂渗透装置
公开(公告)号：JPS5732701A
公开(公告)日：1982-02-22
申请号：JP10848080
申请日：1980-08-07
申请人： Agency Of Ind Science & Technol
发明人： HIRATANI KAZUHISA
IPC分类号： B01D61/28 , B01D61/30 , B01D61/32 , B01D65/08 , B01D69/00
摘要： PURPOSE: To permit easy handling irrespectively of the specific gravities of solvents by isolating and containing a solvent contg. specific solute, the other solvent accepting said solute and a transport carrier for said solute by means of permeable membrane bodies respectively.
CONSTITUTION: A solvent contg. the solute to be permeated is injected into one of cells 1A, 1A through an injection port 1d at the top end, and a solvent to accept said solute is injected into the other. A transport carrier from the through-hole 2a of an annular body 2 is injected into the cell 2A at the center thereof together with the necessary solvent. The specific solute in the solvent put into one cell 1A permeates through a membrane body 4, and enters the cell 2A. Further, it permeates through the other membrane body 4, and is transferred into the other cell 1A. In this way, the concn., extraction or removal of the specific material is accomplished.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：通过分离并含有溶剂，允许容易处理而不考虑溶剂的比重。特定溶质，另一种溶剂，分别通过渗透膜体接受所述溶质和所述溶质的运输载体。构成：溶剂将要渗透的溶质通过上端的注入口1d注入单元1A，1A之一，并将接受所述溶质的溶剂注入另一个中。将环状体2的通孔2a的输送载体与必要的溶剂一起在其中心注入电池2A。在一个电池1A中的溶剂中的特定溶质渗入膜体4中并进入电池2A。此外，其透过另一膜体4，并被转移到另一个电池1A中。以这种方式，完成了特定材料的浓缩，提取或去除。

8. 发明专利

JPS59163343A Polyether derivative useful as ionophore 失效
标题翻译：聚醚衍生物作为离子源有用
公开(公告)号：JPS59163343A
公开(公告)日：1984-09-14
申请号：JP3863783
申请日：1983-03-08
申请人： Agency Of Ind Science & Technol
发明人： HIRATANI KAZUHISA , TAGUCHI KAZUHIRO , SUGIHARA HIDEKI , IIO SHIN
IPC分类号： C09K3/00 , B01D11/04 , B01J45/00 , B01J47/00 , C07C51/00 , C07C51/09 , C07C65/21 , C07C67/00
CPC分类号： Y02P20/55
摘要： NEW MATERIAL:The compound of formula I [R -R are H or alkyl; R may be benzyl, 2-phenylethyl, 3-(naphthyl-1-oxy)propyl or group of formula II (n>=2)]. EXAMPLE:1-[3'-( o-Carboxylphenyloxy )propyloxy]-2-[3'-( o-ethoxyphenyloxy )-propyloxy]-4(or 5)-t-butylbenzene. USE:A cation transfer agent (ionophore) acting selectively especially to lithium ion, capable of transferring the ion against concentration gradient, and having equal rate of transfer independent of the kind of anion. PREPARATION:The compound of formula I can be prepared by hydrolyzing the compound of formula III (R is protecting group) under alkaline condition. When the compound is used as an ionophore, and two kinds of solutions A and B are contacted indirectly interposing the solution of the ionophore M between them, the cation contained in the solution A can be transferred to the solution B.
摘要翻译：新材料：式I化合物[R 1 -R 4]为H或烷基; R 4可以是苄基，2-苯基乙基，3-（萘基-1-氧基）丙基或式II的基团（n> = 2）]。实施例：1- [3' - （邻 - 羧基苯氧基）丙氧基] -2- [3' - （邻 - 乙氧基苯氧基） - 丙氧基] -4（或5） - 叔丁基苯。用途：选择性地特别对锂离子起作用的离子迁移剂（离子载体），其能够离子浓度梯度转移，并且具有与阴离子种类相同的相等转移速率。制备：式Ⅰ化合物可以在碱性条件下水解式Ⅲ化合物（R 5为保护基）来制备。当化合物用作离子载体时，并且两种溶液A和B在它们之间间接插入离子载体M的溶液时，溶液A中所含的阳离子可以转移到溶液B中。

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