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    • 7. 发明授权
    • Derivatives of 8-hydroxyquinoline
    • 8-羟基喹啉的衍生物
    • US5023333A
    • 1991-06-11
    • US338830
    • 1989-04-14
    • Adolf Hubele
    • Adolf Hubele
    • A01C1/00A01G13/00A01N25/32A01N31/16A01N43/00A01N43/42A01N43/50A01N43/54A01N43/76A01N43/78A01N43/84A01P13/00C07D215/26C07D215/28C07D401/12C07D403/12C07D405/12C07D413/12
    • C07D401/12A01N25/32A01N43/42C07D215/26C07D215/28C07D403/12C07D405/12C07D413/12
    • In the method of protecting cultivated plants from the harmful effects of agrochemicals, quinoline derivatives of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, halogen, nitro, cyano, alkyl or alkoxy, R.sub.4, R.sub.5 and R.sub.6 independently of one another are hydrogen, halogen or alkyl, X is an aliphatic, acyclic, saturated hydrocarbon radical having 1 to 3 carbon atoms and Y is a carboxyl group, or a salt thereof, a mercaptocarbonyl group or a salt thereof, a carboxylic acid ester group, a carboxylic acid thiolester group, an unsubstituted or substituted carboxylic acid amide group, a cyclised, unsubstituted or substituted derivative of a carboxylic acid amide group or a carboxylic acid hydrazide group, or X and Y together are an unsubstituted or substituted tetrahydrufuran-2-one ring, including acid addition salts and metal complexes thereof, a compositions containing such derivatives, are used. Novel quinoline derivatives and their preparation are also described.
    • 在保护栽培植物免受农药有害影响的方法中,其中R 1,R 2和R 3彼此独立地为氢,卤素,硝基,氰基,烷基或烷氧基,R4,R5和 R 6彼此独立地是氢,卤素或烷基,X是具有1至3个碳原子且Y是羧基的脂肪族,非环状饱和烃基,或其盐,巯基羰基或其盐,羧酸 酸酯基,羧酸硫醇酯基,未取代或取代的羧酸酰胺基,羧酸酰胺基或羧酸酰肼基的环化,未取代或取代的衍生物,或X和Y一起是未取代或取代的四氢呋喃 -2-环,包括其酸加成盐和金属配合物,含有这些衍生物的组合物。 还描述了新的喹啉衍生物及其制备方法。
    • 8. 发明授权
    • 2-phenylamino pyrimidine derivatives and their uses as microbicides
    • 2-苯基氨基嘧啶衍生物及其用作杀微生物剂
    • US4897396A
    • 1990-01-30
    • US202770
    • 1988-06-03
    • Adolf Hubele
    • Adolf Hubele
    • A01N43/54C07D239/42
    • C07D239/42A01N43/54
    • Novel compounds of the formula ##STR1## in which: R.sub.1 and R.sub.2 independently of one another are hydrogen, halogen, C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.2 -haloalkyl, C.sub.1 -C.sub.3 -alkoxy or C.sub.1 -C.sub.3 -haloalkoxy;R.sub.3 is hydrogen; C.sub.1 -C.sub.4 -alkyl; C.sub.1 -C.sub.2 -alkyl substituted by halogen or by hydroxy; cyclopropyl; or cyclopropyl substituted by halogen and/or by methyl;R.sub.4 is C.sub.1 -C.sub.8 -alkyl; C.sub.2 -C.sub.6 -alkyl substituted by halogen, hydroxy, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.4 -alkoxyalkoxy or by C.sub.1 -C.sub.3 -alkylthio; C.sub.3 -C.sub.6 -alkenyl; C.sub.3 -C.sub.6 -alkynyl; C.sub.3 -C.sub.7 -cycloalkyl; or C.sub.3 -C.sub.7 -cycloalkyl substituted by methyl; andX is oxygen or sulphur.Compounds of formula I are valuable preparations for controlling microorganisms, especially in the agrochemical sector, and insect pests.
    • 新的式(I)化合物,其中:R 1和R 2彼此独立地是氢,卤素,C 1 -C 3 - 烷基,C 1 -C 2 - 卤代烷基,C 1 -C 3 - 烷氧基或C 1 -C 3 - 卤代烷氧基; R3是氢; C 1 -C 4 - 烷基; 被卤素或羟基取代的C1-C2-烷基; 环丙基 或被卤素和/或甲基取代的环丙基; R4是C1-C8-烷基; 被卤素,羟基,氰基,C1-C4-烷氧基,C3-C4-烷氧基烷氧基或C1-C3-烷硫基取代的C2-C6-烷基; C3-C6-烯基; C3-C6-炔基; C 3 -C 7 - 环烷基; 或被甲基取代的C 3 -C 7 - 环烷基; X是氧或硫。 式I的化合物是用于控制微生物,特别是在农业化学领域和害虫中的有价值的制剂。