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1. 发明授权

US09012899B2 Electroluminescent metal complexes with nucleophilic carbene ligands 有权
标题翻译：具有亲核卡宾配体的电致发光金属络合物
公开(公告)号：US09012899B2
公开(公告)日：2015-04-21
申请号：US13915745
申请日：2013-06-12
申请人： Achim Lamatsch
发明人： Roger Pretot , Paul Adriaan Van Der Schaaf , Jemima Schmidt , Beat Schmidhalter , Thomas Schafer , Bernd Lamatsch
IPC分类号： H01L35/24 , H01L51/00 , C07F15/00 , C09K11/06 , H05B33/14 , H01L51/50
CPC分类号： H01L51/0067 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1059 , C09K2211/1092 , C09K2211/185 , H01L51/0071 , H01L51/0072 , H01L51/0074 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H01L51/5048 , H05B33/14
摘要： This invention relates to electroluminescent metal complexes of the formula (I) wherein the ring A, represents an optionally substituted aryl group which can optionally contain heteroatoms, the ring B, represents an optionally substituted nitrogen containing aryl group, which can optionally contain further heteroatoms, or the ring A may be taken with the ring B binding to the ring A to form a ring; the group C, represents an acyclic carbene, or a cyclic carbene (ring C), which can optionally contain heteroatoms, the ring D, represents an optionally substituted aryl group which can optionally contain heteroatoms, n1 is an integer of 1 to 3, m1 is an integer of 0, 1 or 2, m2 is an integer 0 or 1, M1 is a metal with an atomic weight of greater than 40, L3 is a monodentate ligand or a bidentate ligand, Y is —C(═O)— or —C(X1)2—, wherein X1 is hydrogen or C1-4alkyl, especially hydrogen and y is 0 or 1, especially 0; a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays and as catalysts.
摘要翻译：本发明涉及式（I）的电致发光金属络合物，其中环A表示任选地含有杂原子的任选取代的芳基，环B表示任选取代的含氮芳基，其可任选地含有另外的杂原子，或者环A可以与环B结合成环A而形成环; 基团C表示非环状卡宾或可以任选含有杂原子的环状卡宾（环C），环D表示任选地含有杂原子的任意取代的芳基，n1为1〜3的整数，m1 是0,1或2的整数，m2是0或1的整数，M1是原子量大于40的金属，L3是单齿配体或二齿配体，Y是-C（= O） - 或-C（X1）2-，其中X 1是氢或C 1-4烷基，特别是氢，y是0或1，特别是0; 其制备方法，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指示剂，作为生物测定中的磷光指示剂和催化剂。

2. 发明申请

US20130292660A1 ELECTROLUMINESCENT METAL COMPLEXES WITH NUCLEOPHILIC CARBENE LIGANDS 有权
标题翻译：电致发光金属配合物与核酸碳配体
公开(公告)号：US20130292660A1
公开(公告)日：2013-11-07
申请号：US13915745
申请日：2013-06-12
申请人： Achim Lamatsch
发明人： Roger Pretot , Paul Adriaan Van Der Schaaf , Jemima Schmidt , Beat Schmidhalter , Thomas Schafer , Bernd Lamatsch
IPC分类号： H01L51/00
CPC分类号： H01L51/0067 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1059 , C09K2211/1092 , C09K2211/185 , H01L51/0071 , H01L51/0072 , H01L51/0074 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H01L51/5048 , H05B33/14
摘要： This invention relates to electroluminescent metal complexes of the formula (I) wherein the ring A, represents an optionally substituted aryl group which can optionally contain heteroatoms, the ring B, represents an optionally substituted nitrogen containing aryl group, which can optionally contain further heteroatoms, or the ring A may be taken with the ring B binding to the ring A to form a ring; the group C, represents an acyclic carbene, or a cyclic carbene (ring C), which can optionally contain heteroatoms, the ring D, represents an optionally substituted aryl group which can optionally contain heteroatoms, n1 is an integer of 1 to 3, m1 is an integer of 0, 1 or 2, m2 is an integer 0 or 1, M1 is a metal with an atomic weight of greater than 40, L3 is a monodentate ligand or a bidentate ligand, Y is —C(═O)— or —C(X1)2—, wherein X1 is hydrogen or C1-4alkyl, especially hydrogen and y is 0 or 1, especially 0; a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays and as catalysts.
摘要翻译：本发明涉及式（I）的电致发光金属络合物，其中环A表示任选地含有杂原子的任选取代的芳基，环B表示任选取代的含氮芳基，其可任选地含有另外的杂原子，或者环A可以与环B结合成环A而形成环; 基团C表示非环状卡宾或可以任选含有杂原子的环状卡宾（环C），环D表示任选地含有杂原子的任选取代的芳基，n1为1〜3的整数，m1 是0,1或2的整数，m2是0或1的整数，M1是原子量大于40的金属，L3是单齿配体或二齿配位体，Y是-C（= O） - 或-C（X1）2-，其中X1是氢或C1-4烷基，特别是氢，y是0或1，特别是0; 其制备方法，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指示剂，作为生物测定中的磷光指示剂和催化剂。

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