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    • 4. 发明授权
    • Pneumatic rubber tire having annular rubber strip containing electrically conductive bonded to its inner surface
    • 气动橡胶轮胎,其具有环状橡胶条,其内部导电性地结合
    • US07318464B2
    • 2008-01-15
    • US10346652
    • 2003-01-17
    • Bruce Raymond HahnTarah Pecora ShpargelJoseph Carmine Lettieri
    • Bruce Raymond HahnTarah Pecora ShpargelJoseph Carmine Lettieri
    • B60C23/00B60C19/00
    • H01Q1/2241B60C1/00B60C19/00B60C23/0493H01Q1/22
    • A pre-cured pneumatic rubber tire of open toroidal shape having a pre-cured rubber strip, comprised of at least one elastomer and which contains at least one electrically conductive element, adhesively bonded to an inner surface of the tire's cavity. The adhesive is an RTV polysiloxane comprised of an hydroxyl terminated (silanol terminated) polysiloxane and crosslinking agent. The adhesive is applied as a layer, or coating, thereof onto a surface of said pre-cured rubber strip, and/or onto a corresponding pre-cured inner surface of said pre-cured tire, and the resulting coated pre-cured rubber strip and inner surface of said pre-cured tire brought together with said layer of adhesive therebetween and the adhesive allowed to cure and thereby bond said strip to said tire inner surface. In one aspect of the invention, said strip is an annular pre-cured rubber strip bonded to the tire's inner surface in its crown region or to said tire inner surface circumferential with and close to the periphery of the tire's open cavity. In another aspect of the invention, said tire inner surface is of a textured configuration and optionally contains a thin coating thereon of a polysiloxane material. In a further aspect of the invention, said pre-cured rubber strip contains a transducer and/or microprocessor inductively and/or electrically connected to said electrically conductive element(s), for example a wire antenna, contained in said rubber strip.
    • 一种具有开口环形形状的预固化气动橡胶轮胎,其具有由至少一种弹性体组成的预固化橡胶条,并且其包含至少一个导电元件,其粘合到轮胎腔的内表面上。 粘合剂是由羟基封端(硅烷醇封端)聚硅氧烷和交联剂组成的RTV聚硅氧烷。 将粘合剂作为层或其涂层施加到所述预固化橡胶条的表面上和/或施加到所述预硫化轮胎的相应的预固化内表面上,并且所得到的涂覆的预固化橡胶条 并且所述预固化轮胎的内表面与其间的所述粘合剂层一起接合,并且所述粘合剂允许固化,从而将所述带粘合到所述轮胎内表面。 在本发明的一个方面,所述条带是环形预固化橡胶条,其环形预固化橡胶条在其冠部区域或所述轮胎内表面的轮胎内表面上周向连接并且靠近轮胎的开口腔的周边。 在本发明的另一方面,所述轮胎内表面是纹理构造,并且任选地在其上包含聚硅氧烷材料的薄涂层。 在本发明的另一方面,所述预固化橡胶条包含感应和/或电连接到所述导电元件(例如包含在所述橡胶条中的线状天线)的换能器和/或微处理器。
    • 5. 发明申请
    • ELASTOMERS CONTAINING SURFACE METALATED SILICEOUS FILLERS
    • 包含表面金属化硅胶填料的弹性体
    • US20080295936A1
    • 2008-12-04
    • US12098506
    • 2008-04-07
    • Frank James FeherBruce Raymond HahnAaron Scott Puhala
    • Frank James FeherBruce Raymond HahnAaron Scott Puhala
    • B60C11/00C08K5/5415
    • C08K5/548C08K9/02C08K9/12Y02T10/862C08L21/00
    • This invention is based upon the concept of modifying the surface of silica with a metal, such as titanium or zirconium, which will catalyze silanol condensation reactions on the surface of the silica. In other words, modifying the surface of silica with titanium or zirconium provides a catalyst for the silanol condensation reaction between the silica surface and silane coupling agents used in silica filled compounds. The utilization of such metalated silica as a filler in rubber compositions results in improved polymer filler interaction and in turn improved physical properties. For instance, such surface metalated siliceous fillers can be used in tire tread compounds to attain improved rolling resistance and treadwear without compromising traction characteristics. The present invention more specifically discloses an elastomeric composition which is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler. The subject invention further reveals a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler.
    • 本发明是基于用二氧化硅表面上的硅烷醇缩合反应的金属如钛或锆改性二氧化硅表面的概念。 换句话说,用钛或锆改性二氧化硅表面提供二氧化硅表面和二氧化硅填充的化合物中使用的硅烷偶联剂之间的硅烷醇缩合反应的催化剂。 在橡胶组合物中使用这种金属化二氧化硅作为填料导致聚合物填料相互作用改善,从而改善了物理性能。 例如,这种表面金属化的硅质填料可用于轮胎胎面胶料中以获得改善的滚动阻力和胎面磨损,而不损害牵引特性。 本发明更具体地公开了一种弹性体组合物,其由(1)橡胶状聚合物,(2)二氧化硅偶联剂和(3)表面金属化硅质填料组成。 本发明进一步揭示了一种轮胎,其由具有外圆周胎面的大致环形胎体,两个间隔开的胎圈,从胎圈到胎圈延伸的至少一个帘布层和从所述胎面径向延伸并将所述胎面连接到所述胎圈的轮胎,其中 所述胎面适于与地面接触,并且其中所述胎面由(1)橡胶状聚合物,(2)二氧化硅偶联剂和(3)表面金属化硅质填料组成。
    • 7. 发明申请
    • ELASTOMERS CONTAINING SURFACE METALATED SILICEOUS FILLER
    • 包含表面金属化硅胶填料的弹性体
    • US20110186197A1
    • 2011-08-04
    • US13081861
    • 2011-04-07
    • Frank James FeherBruce Raymond HahnAaron Scott Puhala
    • Frank James FeherBruce Raymond HahnAaron Scott Puhala
    • B60C11/00C08F8/42
    • C08K5/548C08K9/02C08K9/12Y02T10/862C08L21/00
    • This invention is based upon the concept of modifying the surface of silica with a metal, such as titanium or zirconium, which will catalyze silanol condensation reactions on the surface of the silica. In other words, modifying the surface of silica with titanium or zirconium provides a catalyst for the silanol condensation reaction between the silica surface and silane coupling agents used in silica filled compounds. The utilization of such metalated silica as a filler in rubber compositions results in improved polymer filler interaction and in turn improved physical properties. For instance, such surface metalated siliceous fillers can be used in tire tread compounds to attain improved rolling resistance and treadwear without compromising traction characteristics. The present invention more specifically discloses an elastomeric composition which is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler. The subject invention further reveals a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler.
    • 本发明是基于用二氧化硅表面上的硅烷醇缩合反应的金属如钛或锆改性二氧化硅表面的概念。 换句话说,用钛或锆改性二氧化硅表面提供二氧化硅表面和二氧化硅填充的化合物中使用的硅烷偶联剂之间的硅烷醇缩合反应的催化剂。 在橡胶组合物中使用这种金属化二氧化硅作为填料导致聚合物填料相互作用改善,从而改善了物理性能。 例如,这种表面金属化的硅质填料可用于轮胎胎面胶料中以获得改善的滚动阻力和胎面磨损,而不损害牵引特性。 本发明更具体地公开了一种弹性体组合物,其由(1)橡胶状聚合物,(2)二氧化硅偶联剂和(3)表面金属化硅质填料组成。 本发明进一步揭示了一种轮胎,其由具有外圆周胎面的大致环形胎体,两个间隔开的胎圈,从胎圈到胎圈延伸的至少一个帘布层和从所述胎面径向延伸并将所述胎面连接到所述胎圈的轮胎,其中 所述胎面适于与地面接触,并且其中所述胎面由(1)橡胶状聚合物,(2)二氧化硅偶联剂和(3)表面金属化硅质填料组成。
    • 8. 发明授权
    • Elastomers containing surface metalated siliceous fillers
    • 含有表面金属化硅质填料的弹性体
    • US07943693B2
    • 2011-05-17
    • US12098506
    • 2008-04-07
    • Frank James FeherBruce Raymond HahnAaron Scott Puhala
    • Frank James FeherBruce Raymond HahnAaron Scott Puhala
    • C08K3/34C08K5/24
    • C08K5/548C08K9/02C08K9/12Y02T10/862C08L21/00
    • This invention is based upon the concept of modifying the surface of silica with a metal, such as titanium or zirconium, which will catalyze silanol condensation reactions on the surface of the silica. In other words, modifying the surface of silica with titanium or zirconium provides a catalyst for the silanol condensation reaction between the silica surface and silane coupling agents used in silica filled compounds. The utilization of such metalated silica as a filler in rubber compositions results in improved polymer filler interaction and in turn improved physical properties. For instance, such surface metalated siliceous fillers can be used in tire tread compounds to attain improved rolling resistance and treadwear without compromising traction characteristics. The present invention more specifically discloses an elastomeric composition which is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler. The subject invention further reveals a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler.
    • 本发明是基于用二氧化硅表面上的硅烷醇缩合反应的金属如钛或锆改性二氧化硅表面的概念。 换句话说,用钛或锆改性二氧化硅表面提供二氧化硅表面和二氧化硅填充的化合物中使用的硅烷偶联剂之间的硅烷醇缩合反应的催化剂。 在橡胶组合物中使用这种金属化二氧化硅作为填料导致聚合物填料相互作用改善,从而改善了物理性能。 例如,这种表面金属化的硅质填料可用于轮胎胎面胶料中以获得改善的滚动阻力和胎面磨损,而不损害牵引特性。 本发明更具体地公开了一种弹性体组合物,其由(1)橡胶状聚合物,(2)二氧化硅偶联剂和(3)表面金属化硅质填料组成。 本发明进一步揭示了一种轮胎,其由具有外圆周胎面的大致环形胎体,两个间隔开的胎圈,从胎圈到胎圈延伸的至少一个帘布层和从所述胎面径向延伸并将所述胎面连接到所述胎圈的轮胎,其中 所述胎面适于与地面接触,并且其中所述胎面由(1)橡胶状聚合物,(2)二氧化硅偶联剂和(3)表面金属化硅质填料组成。