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    • 8. 发明专利
    • Ferroelectric liquid crystal mixtures containing 5-arylindane derivatives
    • DE19840447A1
    • 2000-03-09
    • DE19840447
    • 1998-09-04
    • AVENTIS RES & TECH GMBH & CO
    • OGAWA AYAKOSCHMIDT WOLFGANGWINGEN RAINER
    • C07C25/22C07C25/24C07C43/225C07D239/26C09K19/02C09K19/32C09K19/34C07C43/192C07D213/04C07F7/02C09K19/42G02F1/13G09F9/35
    • A ferroelectric liquid crystal mixture comprises a compound (I) and a further compound selected from (II)-(VII). A ferroelectric liquid crystal mixture comprises a compound from group A and a further compound from any of the groups B-G. Group A comprises 5-arylindane derivatives of formula (I), which do not contain more than four 5- or 6-membered rings: R , R = (a) H, F, Cl, cyano or trifluoromethoxy, provided only one is an A group, (b) 1-20C alkyl, optionally with an asymmetric carbon in which (b1) one or more non-adjacent, non-terminal methylene groups are replaced with a linking group, e.g. ether, and/or (b2) one or more methylene groups are replaced by an unsaturated group and/or (b3) hydrogens are replaced by F and/or Cl, and/or (b4) the terminal methyl group may be replaced by a chiral group; R -R = H or 1-16C alkyl, optionally containing one or more non-adjacent, non-terminal ether groups and/or one or 2 ethylene groups to replace methylene groups and/or F or Cl instead of H, or R and R together may be tetramethylene or pentamethylene if bonded to a ring system; R = (a) H, halo or cyano, or (b) 1-16C alkyl with the conditions (b1)-(b3) for R above; Y -Y = -CF-, -N- or -CH-; M -M = a direct bond or a linking group; A -A = 1,4-phenylene or a heterocyclic group, all optionally substituted; and a, b, c = 0 or 1. Group B comprises phenanthrene derivatives of formula (II): E -E = -N-, -CF- or -CH- subject to provisos; and G = dimethylene or ethylene. Group C comprises 2-fluoropyridine derivatives of formula (III): Group D comprises phenylene derivatives of formula (IV): X , X = H, F, Cl, trifluoromethyl or cyano, provided both are not H. Group E comprises m-substituted aromatic compounds of formula (V): X = F, Cl, Br, cyano, trifluoromethyl or trifluoromethoxy or 1-12C alkyl, optionally with an asymmetric carbon having 1-2 (thio)ether, carbonyl, carbonyloxy or oxycarbonyl groups replacing non-adjacent, non-terminal methylene groups and/or one or more F and/or Cl and/or cyano groups. Group F comprises (1,3,4)-thiadiazoles of formula (VI): X -X = -CF-, -N- or -CH-. Group G comprises 4-cyanocyclohexyls of formula (VII): The full definitions for (I) and (II) are given in the DEFINITIONS (Full Definitions) Field. Independent claims are also included for: (a) a compound of group A; (b) a ferroelectric liquid crystal display device comprising the mixture of compounds.