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1. 发明授权

KR850001912B1 PROCESS FOR THE PREPARATION OF ISOBUTYRYL FLUORIDE 失效
公开(公告)号：KR850001912B1
公开(公告)日：1985-12-31
申请号：KR820002508
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： CORN JOHN E , NORTON RICHARD V , PASCOE RALPH F
IPC分类号： C07C67/14 , C07C51/00 , C07C51/04 , C07C51/12 , C07C51/14 , C07C51/58 , C07C53/42 , C07C53/50 , C07C67/00
摘要： Carbonylation of propylene and organic acid comprises (a) forming a liq. mixt. of CO in an anhydrous acid (HF) in a first reactor at 10 - 100≦̸C under a pressure of 14 - 682 bars, and (b) reacting in the liq. phase in a second reactor the mixt. from (a) with propylene at 40 - 60≦̸C and 39-340 bars to form isobutyryl fluoride. The molar ratio of the CO to the anhydrous acid (HF) is 1.1 - 5 and that of the HF to the propylene is 10 - 30.

2. 发明授权

KR850001915B1 PROCESS FOR THE PREPARATION OF CARBOXYLIC ESTERS FROM ISOBUTYRYL FLUORIDE FORMED BY CARBONYLATION 失效
公开(公告)号：KR850001915B1
公开(公告)日：1985-12-31
申请号：KR820002510
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： PASCOE RALPH F , NORTON RICHARD V
IPC分类号： C07C67/14 , C07C20060101 , C07C51/00 , C07C51/10 , C07C51/363 , C07C51/58 , C07C53/38 , C07C67/00 , C07C67/317 , C07C67/36 , C07C69/02 , C07C69/14 , C07C69/22 , C07C69/24 , C07C69/54
摘要： Carboxylic acid ester is prepd. from isobutyl fluoride (I) by esterifying a mixt. comprising (I) and less than the amt. of alcohol required to esterify the entire (I) in the mixt. to a carboxylic ester (II) under anhydrous conditions in which (II) is formed. The esterification is effected at 20-150≦̸C and 1-340 bars in the presence of the anhydrous hydrofluoric acid, the latter being used in an initial amt. of 0.01-95.5 wt.% to 99.09-4.5 wt.% (I). The alcohol is a 1-2≦̸C primary or secondary alcohol. The process is specifically for the prepn. of methyl(meth)acrylate.

3. 发明授权

KR850001913B1 PROCESS FOR THE PREPARATION OF CARBOXYLIC ACID FROM ISOBUTYRYL FLUORIDE FORMED BY CARBONYLATION 失效
公开(公告)号：KR850001913B1
公开(公告)日：1985-12-31
申请号：KR820002509
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： NORTON RICHARD V , GROTE DACE , CORN JOHN E , PASCOE RALPH F
IPC分类号： C07C53/124 , C07C51/00 , C07C51/04 , C07C51/12 , C07C51/14 , C07C51/58 , C07C67/00
摘要： A carboxylic acid is produced by hydrolyzing a mixt. comprising an acyl fluoride (I) with less than the amt. of water required to hydrolyze the entire(I) in the mixt. to carboxylic acid, under conditions in which the carboxylic acid is formed and the acid is regenerated from the anion. Hydrolysis is effected at 20-150≦̸C and 1- 1340 bars. The acyl fluoride (I) is formed by reacting CO, anhydrous HF acid and an organic cpd. capable of reacting with CO and HF acid. The ratio of HF acid to (I) is 0.01-95.5 pts. wt. acid to 99.09-4.5 pts. wt. (I). The organic acid is an olefin having up to 20C and at least one double bond to form an acylium anion.

4. 发明专利

GB2106893B PROCESS FOR THE PRODUCTION OF ISOBUTYRIC ACID ANHYDRIDE 未知
公开(公告)号：GB2106893B
公开(公告)日：1985-09-18
申请号：GB8130055
申请日：1981-10-05
申请人： ASHLAND OIL INC
发明人： NORTON RICHARD V , PASCOE RALPH F , ZEHNER LEE R , CORN JOHN E , GROTE DACE
IPC分类号： C07C51/56 , C07C51/58 , C07C53/124 , C07C51/54

5. 发明专利

CA1192576A PRODUCTION OF AN ACYLIUM ANION PRODUCT AND CARBOXYLIC ACIDS AND ESTERS THEREFROM 未知
公开(公告)号：CA1192576A
公开(公告)日：1985-08-27
申请号：CA404491
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： CORN JOHN E JR , NORTON RICHARD V , PASCOE RALPH F
IPC分类号： C07C67/14 , C07C51/00 , C07C51/04 , C07C51/12 , C07C51/14 , C07C51/58 , C07C53/42 , C07C53/50 , C07C67/00 , C07C53/124 , C07C57/065
摘要： A carbonylation process for producing acylium anion addition product, e.g., acid fluorides, wherein the carbon monoxide and anhydrous acid such as hydrogen fluoride are premixed to form a single liquid phase which is reacted in a second reactor with the organic compound, e.g., propylene, to produce an organic carbon monoxide acid anion addition product, e.g., isobutyryl fluoride.

6. 发明专利

DD207900A5 未知
公开(公告)号：DD207900A5
公开(公告)日：1984-03-21
申请号：DD24046882
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： CORN JOHN E , NORTON RICHARD V , PASCOE RALPH F
IPC分类号： C07C67/14 , C07C51/00 , C07C51/04 , C07C51/12 , C07C51/14 , C07C51/58 , C07C53/42 , C07C53/50 , C07C67/00 , C07C57/04
摘要： In a carbonylation process for a producing acyl halides, e.g. acyl fluorides, the carbon monoxide and anhydrous acid such as hydrogen fluoride are premixed to form a single liquid phase which is reacted in a second reactor with an organic compound, i.e. an ester or an olefin, e.g. propylene, to produce an acyl halide, e.g., isobutyryl fluoride. In the second reactor the temperature is 0- 90 DEG C and the pressure 34-340 bars. The mole ratio of anhydrous acid to organic compounds is 1-100 moles of anhydrous acid per mole of organic compound and the mole ratio of carbon monoxide to organic compound is 1 to 5 moles of carbon monoxide per mole of organic compound. The acyl halide product may be hydrolysed to form the corresponding carboxylic acid which may in turn be oxydehydrogenated in the organic phase to form the corresponding unsaturated acid, e.g., acrylic acid or methacrylic acid.

7. 发明专利

ZA8203929B PRODUCTION OF AN ACYLIUM ANION PRODUCT AND CARBOXYLIC ACIDS AND ESTERS THEREFROM 未知
公开(公告)号：ZA8203929B
公开(公告)日：1983-11-30
申请号：ZA8203929
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： CORN JOHN E JR , NORTON RICHARD V , PASCOE RALPH F
IPC分类号： C07C67/14 , C07C51/00 , C07C51/04 , C07C51/12 , C07C51/14 , C07C51/58 , C07C53/42 , C07C53/50 , C07C67/00 , C01B
CPC分类号： C07C51/14 , C07C51/12 , C07C51/58 , C07C53/124 , C07C53/42

8. 发明专利

GB2101592A Production of carboxylic esters from acyl halides formed by carbonylation 未知
公开(公告)号：GB2101592A
公开(公告)日：1983-01-19
申请号：GB8216303
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： NORTON RICHARD V , PASCOE RALPH F
IPC分类号： C07C67/14 , C07C20060101 , C07C51/00 , C07C51/10 , C07C51/363 , C07C51/58 , C07C53/38 , C07C67/00 , C07C67/317 , C07C67/36 , C07C69/02 , C07C69/14 , C07C69/22 , C07C69/24 , C07C69/54
摘要： Carboxylic esters, e.g., methyl isobutyrate, are formed by esterifying an acyl halide, e.g., isobutyryl fluoride, with less than the total amount of alcohol, e.g., methanol, required to react with the acyl halide under conditions whereby the anhydrous acid, e.g., hydrogen fluoride, is regenerated. Esterification is conducted at a temperature of 20 to 150 DEG C and under a pressure of 1 to 340 bars. The initial amount of anhydrous acid to acyl halide is 0.01 to 95.5 parts by weight anhydrous acid to 99.99 to 4.5 parts by weight of acyl halide. The carboxylic ester may be oxydehydrated in the vapour phase to form the corresponding unsaturated carboxylic ester (e.g. methyl acrylate or methyl methacrylate).

9. 发明专利

CA1314292C PROCESS FOR THE CARBONYLATION OF PROPYLENE 未知
公开(公告)号：CA1314292C
公开(公告)日：1993-03-09
申请号：CA564222
申请日：1988-04-14
申请人： ASHLAND OIL INC
发明人： PASCOE RALPH F , SCACCIA CARLO
IPC分类号： C07C51/62 , C07C53/42
摘要： A process for the improvement in the utilization of carbon monoxide and for the utilization of propylene having varying grades of purity in the carbonylation of propylene with carbon monoxide and hydrogen fluoride to form isobutyryl fluoride in a carbonylation reactor whereby the effluent from the reactor is (a) passed into a first phase separator where the effluent is separated into an overhead gaseous stream and a bottom liquid stream which contains unreacted carbon monoxide, (b) the bottom liquid stream from (a) is passed into a second reactor where it is contacted with a gaseous stream which contains propylene and allowing essentially all of the propylene to react, (c) the effluent from the second reactor is passed to a second phase separator where overhead gases are separated from liquid bottoms, (d) the liquid bottoms from the second phase separator are passed to a degassing pot where overhead gases are removed and the liquid bottoms stream which is essentially isobutyryl fluoride is taken to recovery, (e) the overhead gases from (d) are optionally mixed with inert gases and the stream is recycled to the hydrogen fluoride fed to the carbonylation reactor and/or recycled back to the gaseous stream in (b), (f) the gases from overhead stream in (a) are passed to a compressor and then to the recycle gaseous stream from (e), (g) the overhead gases from (e) are divided into a first portion which is sent to recycle as in (e) and a second portion which is sent to a refrigeration unit where said second portion into a bottom stream of less volatile materials and an overhead stream of volatile materials, a portion of the bottoms stream is added to the isobutyryl fluoride stream for recovery in (d), and the overhead, less volatile stream from (g) is sent to waste disposal is described.

10. 发明专利

IT1195931B 未知
公开(公告)号：IT1195931B
公开(公告)日：1988-11-03
申请号：IT2170982
申请日：1982-06-04
申请人： ASHLAND OIL INC
发明人： JOHN E CORN JR , NORTON RICHARD V , PASCOE RALPH F
IPC分类号： C07C67/14 , C07C51/00 , C07C51/04 , C07C51/12 , C07C51/14 , C07C51/58 , C07C53/42 , C07C53/50 , C07C67/00 , C07C
摘要： In a carbonylation process for a producing acyl halides, e.g. acyl fluorides, the carbon monoxide and anhydrous acid such as hydrogen fluoride are premixed to form a single liquid phase which is reacted in a second reactor with an organic compound, i.e. an ester or an olefin, e.g. propylene, to produce an acyl halide, e.g., isobutyryl fluoride. In the second reactor the temperature is 0- 90 DEG C and the pressure 34-340 bars. The mole ratio of anhydrous acid to organic compounds is 1-100 moles of anhydrous acid per mole of organic compound and the mole ratio of carbon monoxide to organic compound is 1 to 5 moles of carbon monoxide per mole of organic compound. The acyl halide product may be hydrolysed to form the corresponding carboxylic acid which may in turn be oxydehydrogenated in the organic phase to form the corresponding unsaturated acid, e.g., acrylic acid or methacrylic acid.

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