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1. 发明授权

EP0066387B1 Combination process for upgrading residual oils 有权
标题翻译：用于提高残留油的组合方法
公开(公告)号：EP0066387B1
公开(公告)日：1985-11-13
申请号：EP82302428.6
申请日：1982-05-12
申请人： ASHLAND OIL, INC.
发明人： Busch, Lloyd E. , Walters, Paul W. , Zandona, Oliver J.
IPC分类号： C10G51/04
CPC分类号： C10G51/04

2. 发明公开

EP0062779A1 Process for convertions carbo-metallic oils to lighter products 有权
标题翻译： Verfahren zur Umwandlung karbometallischeÖlein niedrig siedende Produkte。
公开(公告)号：EP0062779A1
公开(公告)日：1982-10-20
申请号：EP82102265.4
申请日：1982-03-19
申请人： ASHLAND OIL, INC.
发明人： Myers, George D. , Busch, Lloyd E.
IPC分类号： C10G11/18 , B01J8/18 , B01J29/38
CPC分类号： B01J8/1836 , B01J2208/00088 , B01J2208/00353 , B01J2208/00495 , B01J2208/0053 , C10G11/182
摘要： A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650°F and material which is characterized by a carbon residue on pyrolysis of at least about 1 and a Nickel Equivalents of heavy metals content of at least about 4 parts per million. This process comprises flowing the carbo-metallic oil together with particulate cracking catalyst through a progressive flow type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a predetermined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900 to about 1400°F, and under a pressure of about 10 to about 50 pounds per square inch absolute sufficient for causing a conversion per pass in the range of about 50% to about 90?f while producing coke in amounts in the range of about 6 to about 14% by weight based on fresh feed, and laying down coke on the catalyst in amounts in the range of about 0.3 to about 3% by weight. The spent, coke-laden catalyst from the stream of hydrocarbons formed by vaporized feed and resultant cracking products is separated and regenerated in one or more regeneration beds in one or more regeneration zones by burning the coke on the spent catalyst with oxygen. The bed density is in the range of about 25 to about 50 pounds per cubic foot and the bed or beds are sustained by fluidization gas containing combustion-supporting gas having a linear velocity in the range of about 0.2 to about 4 feet per second Liquid water is added to the bed or beds in a weight ratio of water to converter feed from about 0.01 to about 0.5 to at least partly absorb the heat produced by the burning coke The catalyst particles are retained in the regeneration zone or zones in contact with the combustion-supporting gas for an average total residence time in said zone or zones of about 5 to about 30 minutes to reduce the level of carbon on the catalyst to about 0.25% by weight or less. The regenerated catalyst is recycled to the reactor and contacted with fresh carbo-metallic oil.
摘要翻译：将碳金属油经济转化为轻质产品的方法。碳金属油含有650°F，其特征在于热解后的碳残余物至少约为1，镍的重量金属含量至少约为4ppm。该方法包括使碳金属油与颗粒裂化催化剂一起通过具有细长反应室的逐步流动型反应器，所述反应室至少部分垂直或倾斜，预定蒸气提升管停留时间在约0.5至约10秒，在约900至约1400°F的温度和约10至约50磅/平方英寸的压力下绝对足以使每次转化率在约50％至约90％的范围内，同时以基于新鲜进料的约6至约14重量％范围内的量生产焦炭，并以约0.3至约3重量％的量在催化剂上沉积焦炭。通过汽化进料和产生的裂化产物形成的碳氢化合物流中消耗的焦炭催化剂在一个或多个再生区中的一个或多个再生床中通过用氧气在废催化剂上燃烧焦炭来分离和再生。床密度在约25至约50磅/立方英尺的范围内，并且床或床由包含具有在约0.2至约4英尺/秒范围内的线性速度的燃烧支持气体的流化气体维持液态水以水至转化器进料的重量比从约0.01至约0.5加入到床或床中，以至少部分地吸收由燃烧焦炭产生的热量。催化剂颗粒保留在与燃烧接触的再生区或区域中在大约5至大约30分钟的所述区域中的平均总停留时间，以将催化剂上的碳水平降低到约0.25重量％或更少。将再生的催化剂再循环到反应器中并与新鲜的碳 - 金属油接触。

3. 发明公开

EP0101553A3 Method and apparatus for converting oil feeds 失效
标题翻译：用于转化油料的方法和装置
公开(公告)号：EP0101553A3
公开(公告)日：1984-06-06
申请号：EP83106610
申请日：1983-07-06
申请人： ASHLAND OIL, INC.
发明人： Busch, Lloyd E. , Palmeter, Charles W. , Henderson, Gerald O. , Rice, William M.
IPC分类号： C10G11/18 , B01J08/24 , C10G47/30
CPC分类号： C10G11/18 , B01J8/085
摘要： Novel riser reactor design with associated multiple feed inlet means for contacting regenerated catalyst particles with low quality naphtha, C. minus wet gas product of hydrocarbon conversion and a residual oil feed comprising components boiling above about 1025°F and comprising metal contaminants. Low quality naphtha from thermal cracking is charged either separately or in admixture with C. and lower boiling wet gas product of hydrocarbon conversion to the bottom portion of the riser conversion zone for contact with freshly regenerated zeolite cracking catalyst. The vaporous material thus charged conveys the regenerated catalyst at an acceptable velocity to an expanded section of the riser wherein residual oil is charged by a plurality of nozzle means penetrating the wall of the riser in the transition section to the expander user section. A suspension of hydrocarbon vapors and catalyst particles is then passed through the riser discharge for a desired contact time before separation by balistic separation with a cup about the riser upper to the riser end.
摘要翻译：具有相关联的多个进料入口装置的新型提升管反应器设计，用于使再生催化剂颗粒与低质量石脑油，C5减去烃转化的湿气产物和包含沸点高于约1025°F并且包含金属污染物的组分的残余油进料接触。来自热裂解的低质量石脑油可以单独地或与C5转化的低沸点湿气产物混合加入到提升管转化区的底部以与新鲜再生的沸石裂化催化剂接触。如此加载的气态材料以可接受的速度将再生催化剂输送到提升管的扩张部分，其中残余油被穿过过渡部分中的提升管壁的膨胀器用户部分的多个喷嘴装置充电。然后将碳氢化合物蒸气和催化剂颗粒的悬浮液通过提升管排出口达到期望的接触时间，然后通过与提升管上升至提升管端的杯子进行弹道分离而分离。

4. 发明公开

EP0106052A1 Demetallizing and decarbonizing heavy residual oil feeds 有权
标题翻译：脱金属和重残油原料的脱碳。
公开(公告)号：EP0106052A1
公开(公告)日：1984-04-25
申请号：EP83107852.2
申请日：1983-08-09
申请人： ASHLAND OIL, INC.
发明人： Busch, Lloyd E. , Henderson, Gerald O.
IPC分类号： C10G45/66 , C10G45/14
CPC分类号： C10G47/30 , C10G47/22
摘要： The method and means for effecting selective visbreaking of residual oil feeds (3, 7, 8) comprising metallo-organic compounds with a fluid solid sorbent particle material in the presence of process sour water (1,2,4) and wet gas recycle material (9) is described to provide a gas oil rich product more suitable for crystalline zeolite fluid catalytic cracking operations.

5. 发明公开

EP0066387A1 Combination process for upgrading residual oils 有权
标题翻译： Kombinationsverfahrenfürdie Verbesserung vonResidualölen。
公开(公告)号：EP0066387A1
公开(公告)日：1982-12-08
申请号：EP82302428.6
申请日：1982-05-12
申请人： ASHLAND OIL, INC.
发明人： Busch, Lloyd E. , Walters, Paul W. , Zandona, Oliver J.
IPC分类号： C10G51/04
CPC分类号： C10G51/04
摘要： A combination process is described for upgrading residual oils (2) and high boiling portions thereof comprising metal contaminants and high boiling Conradson carbon forming compounds comprising a thermal visbreaking operation (7) with fluidizable inert solids followed by a fluidized zeolite catalytic cracking operation 12 processing demetallized products (8) (10) of the visbreaking operation, regenerating solid particulate of each operation under conditions to provide CO rich flue gases relied upon to generate steam used in each of the fluidized solids conversion operation and downstream product separation arrangements, separating the wet gas product stream of each operation in a common product recovery arrangement (22) and processing the high boiling feed product of visbreaking comprising up to 100 ppm Ni + V metal contaminant over a recycled crystalline zeolite cracking catalyst distributed in a sorbent matrix material comprising a high lever of Ni + V metal contaminant.
摘要翻译：描述了一种组合方法，其用于升级包含金属污染物和高沸点康拉逊碳形成化合物的残余油（2）和其高沸点部分，其包括具有可流化惰性固体的热减粘裂化操作（7），随后是流化沸石催化裂化操作12处理脱金属产品（8）（10），每个操作的固体颗粒在提供富CO烟道气的条件下再生，以产生在每个流化固体转化操作和下游产物分离装置中使用的蒸汽，分离湿气体每个操作的产品流在共同的产品回收装置（22）中，并且处理分散在吸附剂基质材料中的再循环的结晶沸石裂化催化剂上，包括高达100ppm的Ni + V金属污染物的高沸点进料产品，其包含高杠杆的Ni + V金属污染物。

6. 发明公开

EP0097829A3 Carbometallic oil conversion with hydrogen in a vented riser using a high metals containing catalyst 有权
标题翻译：使用含有高金属催化剂的通风炉中的氢气进行碳交换油转化
公开(公告)号：EP0097829A3
公开(公告)日：1986-02-12
申请号：EP83105422
申请日：1983-06-01
申请人： ASHLAND OIL, INC.
发明人： Myers, George D. , Busch, Lloyd E.
IPC分类号： C10G47/30
CPC分类号： B01J29/90 , C10G11/18 , C10G47/30
摘要： A process for the production of high octane gasoline and/or valuable lower molecular weight product from carbometallic oils comprising contacting hydrogen and a carbometallic feed in a progressive flow reaction zone with hot conversion catalysts capable of activating hydrogen and hydrogen gas. The hydrogen gas may be introduced into the feed prior to or simultaneous with contacting the feed with catalysts. Alternately, the hydrogen gas may be introduced to the catalysts prior to or simultaneously with its contact with the carbometallic feed.

7. 发明授权

EP0062779B1 Process for convertions carbo-metallic oils to lighter products 有权
标题翻译：将金属油转换成更轻的产品的方法
公开(公告)号：EP0062779B1
公开(公告)日：1985-03-20
申请号：EP82102265.4
申请日：1982-03-19
申请人： ASHLAND OIL, INC.
发明人： Myers, George D. , Busch, Lloyd E.
IPC分类号： C10G11/18 , B01J8/18 , B01J29/38
CPC分类号： B01J8/1836 , B01J2208/00088 , B01J2208/00353 , B01J2208/00495 , B01J2208/0053 , C10G11/182

8. 发明公开

EP0101553A2 Method and apparatus for converting oil feeds 失效
标题翻译： Verfahren und Vorrichtung zur Umwandlung vonÖleinsätzen。
公开(公告)号：EP0101553A2
公开(公告)日：1984-02-29
申请号：EP83106610.5
申请日：1983-07-06
申请人： ASHLAND OIL, INC.
发明人： Busch, Lloyd E. , Palmeter, Charles W. , Henderson, Gerald O. , Rice, William M.
IPC分类号： C10G11/18 , B01J8/24 , C10G47/30
CPC分类号： C10G11/18 , B01J8/085
摘要： Novel riser reactor design with associated multiple feed inlet means for contacting regenerated catalyst particles with low quality naphtha, C. minus wet gas product of hydrocarbon conversion and a residual oil feed comprising components boiling above about 1025°F and comprising metal contaminants. Low quality naphtha from thermal cracking is charged either separately or in admixture with C. and lower boiling wet gas product of hydrocarbon conversion to the bottom portion of the riser conversion zone for contact with freshly regenerated zeolite cracking catalyst. The vaporous material thus charged conveys the regenerated catalyst at an acceptable velocity to an expanded section of the riser wherein residual oil is charged by a plurality of nozzle means penetrating the wall of the riser in the transition section to the expander user section. A suspension of hydrocarbon vapors and catalyst particles is then passed through the riser discharge for a desired contact time before separation by balistic separation with a cup about the riser upper to the riser end.
摘要翻译：具有相关联的多个进料入口装置的新型提升管反应器设计，用于使再生催化剂颗粒与低质量石脑油，C5减去烃转化的湿气产物和包含沸点高于约1025°F并且包含金属污染物的组分的残余油进料接触。来自热裂解的低质量石脑油可以单独地或与C5转化的低沸点湿气产物混合加入到提升管转化区的底部以与新鲜再生的沸石裂化催化剂接触。如此加载的气态材料以可接受的速度将再生催化剂输送到提升管的扩张部分，其中残余油由穿过过渡部分中的提升管壁的膨胀器使用部分的多个喷嘴装置充电。然后将碳氢化合物蒸气和催化剂颗粒的悬浮液通过提升管排出口达到期望的接触时间，然后通过与提升管上升至提升管端的杯子进行弹道分离而分离。

9. 发明授权

EP0097829B1 Carbometallic oil conversion with hydrogen in a vented riser using a high metals containing catalyst 有权
标题翻译：使用含金属高催化剂的加氢器中的氢气进行碳交换油转化
公开(公告)号：EP0097829B1
公开(公告)日：1990-04-11
申请号：EP83105422.6
申请日：1983-06-01
申请人： ASHLAND OIL, INC.
发明人： Myers, George D. , Busch, Lloyd E.
IPC分类号： C10G47/30
CPC分类号： B01J29/90 , C10G11/18 , C10G47/30

10. 发明公开

EP0097829A2 Carbometallic oil conversion with hydrogen in a vented riser using a high metals containing catalyst 有权
标题翻译：通过使用具有高金属含量的催化剂在提升管氢手段碳氮化金属油转化率。
公开(公告)号：EP0097829A2
公开(公告)日：1984-01-11
申请号：EP83105422.6
申请日：1983-06-01
申请人： ASHLAND OIL, INC.
发明人： Myers, George D. , Busch, Lloyd E.
IPC分类号： C10G47/30
CPC分类号： B01J29/90 , C10G11/18 , C10G47/30
摘要： A process for the production of high octane gasoline and/or valuable lower molecular weight product from carbometallic oils comprising contacting hydrogen and a carbometallic feed in a progressive flow reaction zone with hot conversion catalysts capable of activating hydrogen and hydrogen gas. The hydrogen gas may be introduced into the feed prior to or simultaneous with contacting the feed with catalysts. Alternately, the hydrogen gas may be introduced to the catalysts prior to or simultaneously with its contact with the carbometallic feed.
摘要翻译：一种用于从金属碳氮化油，包括使氢气和与热转化催化剂，能够活化氢和氢气的渐进流反应区中的碳氮化金属原料生产高辛烷值汽油和/或有价值的低分子量产物的过程。氢气可以被引入之前或同时接触，催化剂进料的进料。可替换地，氢气可以被引入到催化剂之前或同时，其与金属碳氮化原料接触。

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