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    • 6. 发明专利
    • AT340812T
    • 2006-10-15
    • AT02015683
    • 2002-07-17
    • ASAHI GLASS CO LTD
    • TOYOTA YOSHINORIHORIE AKIOWADA HIROSHISUGIYAMA KAYOKOAKAGI ETSUKO
    • C08G65/28C08G18/08C08G18/40C08G18/48C08G18/63C08G18/76C08G65/26
    • The present invention relates to a method for producing a flexible polyurethane foam which comprises reacting a polyol compound and a polyisocyanate compound in the presence of a blowing agent and a catalyst, wherein as the polyol compound, a polyol mixture containing a polyoxyalkylene polyol obtained by a method which comprises subjecting propylene oxide and ethylene oxide to ring-opening addition polymerization with an initiator in the presence of a catalyst, wherein the polyoxyalkylene polyol is a polyoxyalkylene polyol obtained by subjecting propylene oxide to ring-opening addition polymerization with an initiator in the presence of a double metal cyanide complex catalyst to form an oxypropylene block chain, subjecting ethylene oxide and propylene oxide to ring-opening addition polymerization randomly to form an oxyalkylene random chain, changing the catalyst and subjecting ethylene oxide to ring-opening addition polymerization in the presence of an alkali metal catalyst to form an oxyethylene block chain, and the polyoxyalkylene polyol is a polyoxyalkylene polyol having a hydroxyl value of from 5 to 56 mgKOH/g, a proportion of an initiator residue of at most 25 mass%, a proportion of the oxypropylene block chain of from 5 to 50 mass%, a total oxyethylene group content of from 5 to 60 mass%, and a ratio of primary hydroxyl groups among terminal hydroxyl groups of at least 60 mol%, is used.
    • 9. 发明专利
    • DE60214937D1
    • 2006-11-09
    • DE60214937
    • 2002-07-17
    • ASAHI GLASS CO LTD
    • TOYOTA YOSHINORIHORIE AKIOWADA HIROSHISUGIYAMA KAYOKOAKAGI ETSUKO
    • C08G18/48C08G65/28C08G18/08C08G18/40C08G18/63C08G18/76C08G65/26
    • The present invention relates to a method for producing a flexible polyurethane foam which comprises reacting a polyol compound and a polyisocyanate compound in the presence of a blowing agent and a catalyst, wherein as the polyol compound, a polyol mixture containing a polyoxyalkylene polyol obtained by a method which comprises subjecting propylene oxide and ethylene oxide to ring-opening addition polymerization with an initiator in the presence of a catalyst, wherein the polyoxyalkylene polyol is a polyoxyalkylene polyol obtained by subjecting propylene oxide to ring-opening addition polymerization with an initiator in the presence of a double metal cyanide complex catalyst to form an oxypropylene block chain, subjecting ethylene oxide and propylene oxide to ring-opening addition polymerization randomly to form an oxyalkylene random chain, changing the catalyst and subjecting ethylene oxide to ring-opening addition polymerization in the presence of an alkali metal catalyst to form an oxyethylene block chain, and the polyoxyalkylene polyol is a polyoxyalkylene polyol having a hydroxyl value of from 5 to 56 mgKOH/g, a proportion of an initiator residue of at most 25 mass%, a proportion of the oxypropylene block chain of from 5 to 50 mass%, a total oxyethylene group content of from 5 to 60 mass%, and a ratio of primary hydroxyl groups among terminal hydroxyl groups of at least 60 mol%, is used.