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1. 发明申请

WO2008121783A1 BLOWING AGENT COMPOSITION OF HYDROCHLOROFLUOROOLEFIN 审中-公开
标题翻译：氢氟菊酯的发泡剂组合物
公开(公告)号：WO2008121783A1
公开(公告)日：2008-10-09
申请号：PCT/US2008/058600
申请日：2008-03-28
申请人： ARKEMA INC. , CHEN, Benjamin B. , ELSHEIKH, Maher Y. , BONNET, Philippe , VAN HORN, Brett L. , COSTA, Joseph S.
发明人： CHEN, Benjamin B. , ELSHEIKH, Maher Y. , BONNET, Philippe , VAN HORN, Brett L. , COSTA, Joseph S.
IPC分类号： C08J9/00 , C08J9/14
CPC分类号： C08J9/144 , C08J9/127 , C08J9/149 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2203/142
摘要： A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
摘要翻译：公开了一种用于热固性泡沫的发泡剂。发泡剂主要是氢氯氟烯烃（HCFO）HFCO-1233zd单独或与氢氟烯烃（HFO），氢氟烃（HFC），氢氯氟烯烃（HCFO），烃类的组合的反式异构体。发泡剂在制造热固性泡沫时作为发泡剂是有效的。

2. 发明申请

WO2008121790A1 BLOWING AGENT COMPOSITION OF HYDROCHLOROFLUOROOLEFIN AND HYDROFLUOROOLEFIN 审中-公开
标题翻译：氢氟菊酯和氢氟酸的发泡剂组合物
公开(公告)号：WO2008121790A1
公开(公告)日：2008-10-09
申请号：PCT/US2008/058607
申请日：2008-03-28
申请人： ARKEMA INC. , CHEN, Benjamin B. , COSTA, Joseph S. , BONNET, Philippe , ELSHEIKH, Maher Y. , VAN HORN, Brett L.
发明人： CHEN, Benjamin B. , COSTA, Joseph S. , BONNET, Philippe , ELSHEIKH, Maher Y. , VAN HORN, Brett L.
IPC分类号： C08J9/00
CPC分类号： C08J9/144 , B01F17/0085 , C08G18/06 , C08J9/146 , C08J9/149 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2300/104 , C08J2300/106 , C08J2375/04
摘要： A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234yf in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
摘要翻译：公开了一种用于热固性泡沫的发泡剂。发泡剂是氢氟氟烯烃（HCFO），优选HFCO-1234yf与氢氯氟烯烃（HCFO），优选选自HCFO-1233zd，HCFO-1223，HCFO-1233xf和其混合物的一种。发泡剂在热固性泡沫的制造中作为发泡剂是有效的。

3. 发明申请

WO2008121787A1 BLOWING AGENT COMPOSITION OF HYDROFLUOROPROPENE AND HYDROCHLOROFLUOROOLEFIN 审中-公开
标题翻译：氢氟代苯酚和氢氯酚的发泡剂组合物
公开(公告)号：WO2008121787A1
公开(公告)日：2008-10-09
申请号：PCT/US2008/058604
申请日：2008-03-28
申请人： ARKEMA INC. , CHEN, Benjamin B. , COSTA, Joseph S. , VAN HORN, Brett L. , ELSHEIKH, Maher Y. , BONNET, Philippe
发明人： CHEN, Benjamin B. , COSTA, Joseph S. , VAN HORN, Brett L. , ELSHEIKH, Maher Y. , BONNET, Philippe
IPC分类号： C08J9/00
CPC分类号： C08J9/144 , B01F17/0085 , C08G18/06 , C08J9/146 , C08J9/149 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2300/104 , C08J2300/106 , C08J2375/04
摘要： A blowing agent for thermosetting foams is disclosed. The blowing agent is the hydrofluoropropene HFO-1243zf in combination with a hydrochlorofluoroolefin (HCFO) selected from HCFO-1233zd, HCFO-1233xf and HCFO-1223. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
摘要翻译：公开了一种用于热固性泡沫的发泡剂。发泡剂是与选自HCFO-1233zd，HCFO-1233xf和HCFO-1223的氢氯氟烯烃（HCFO）组合的氢氟丙烯HFO-1243zf。发泡剂在热固性泡沫的制造中作为发泡剂是有效的。

4. 发明申请

WO2008121785A1 BLOWING AGENT COMPOSITION OF HYDROCHLOROFLUOROOLEFIN AND HYDROFLUOROOLEFIN 审中-公开
标题翻译：氢氟菊酯和氢氟酸的发泡剂组合物
公开(公告)号：WO2008121785A1
公开(公告)日：2008-10-09
申请号：PCT/US2008/058602
申请日：2008-03-28
申请人： ARKEMA INC. , CHEN, Benjamin B. , COSTA, Joseph S. , BONNET, Philippe , ELSHEIKH, Maher Y. , VAN HORN, Brett L.
发明人： CHEN, Benjamin B. , COSTA, Joseph S. , BONNET, Philippe , ELSHEIKH, Maher Y. , VAN HORN, Brett L.
IPC分类号： C08J9/00 , C08J9/14
CPC分类号： C08J9/144 , B01F17/0085 , C08G18/06 , C08J9/146 , C08J9/149 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2300/104 , C08J2300/106 , C08J2375/04
摘要： A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234ze in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
摘要翻译：公开了一种用于热固性泡沫的发泡剂。发泡剂是氢氟氟烯烃（HCFO），优选HFCO-1234ze与氢氯氟烯烃（HCFO），优选选自HCFO-1233zd，HCFO-1223，HCFO-1233xf及其混合物的一种。发泡剂在制造热固性泡沫时作为发泡剂是有效的。

5. 发明申请

WO2009114397A2 STABLE FORMULATED SYSTEMS WITH CHLORO-3,3,3-TRIFLUOROPROPENE 审中-公开
标题翻译：具有氯仿-3,3,3-三氟丙烯的稳定配方体系
公开(公告)号：WO2009114397A2
公开(公告)日：2009-09-17
申请号：PCT/US2009/036267
申请日：2009-03-06
申请人： ARKEMA INC. , VAN HORN, Brett L. , ELSHEIKH, Maher Y. , CHEN, Benjamin B. , BONNET, Philippe
发明人： VAN HORN, Brett L. , ELSHEIKH, Maher Y. , CHEN, Benjamin B. , BONNET, Philippe
IPC分类号： C10M131/04 , C10M131/10
CPC分类号： C09K5/04 , B01F17/0085 , C09K5/00 , C09K5/044 , C10M171/008 , C10M2203/065 , C10M2205/0285 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2220/302
摘要： The present invention relates to formulated systems of 1-chloro-3,3,3-trifluoropropene (R-1233zd) and/or 2-chloro-3,3,3-trifluoropropene (R-1233xf) that are sufficiently thermally and chemically stable such that they can be effectively used sans additional stabilizers. The formulations of the present invention are particularly useful compositions for refrigeration, heat transfer, and foam pre-mixes.
摘要翻译：本发明涉及足够热和化学稳定的1-氯-3,3,3-三氟丙烯（R-1233zd）和/或2-氯-3,3,3-三氟丙烯（R-1233xf）的配制体系使得它们可以有效地用于无额外的稳定剂。本发明的制剂是用于制冷，传热和泡沫预混物的特别有用的组合物。

6. 发明申请

WO2008121779A1 BLOWING AGENT COMPOSITIONS OF HYDROCHLOROFLUOROOLEFINS 审中-公开
标题翻译：氢氯酚的发泡剂组合物
公开(公告)号：WO2008121779A1
公开(公告)日：2008-10-09
申请号：PCT/US2008/058596
申请日：2008-03-28
申请人： ARKEMA INC. , VAN HORN, Brett L. , ELSHEIKH, Maher Y. , CHEN, Benjamin B. , BONNET, Philippe
发明人： VAN HORN, Brett L. , ELSHEIKH, Maher Y. , CHEN, Benjamin B. , BONNET, Philippe
IPC分类号： C08J9/00 , C08J9/14
CPC分类号： C08J9/146 , C08J9/149 , C08J2203/162 , C08J2203/182 , C08J2203/202 , C08J2205/05 , Y10T428/249953
摘要： The present invention relates to blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3, 3,3-trifluoropropene (HCFO-1233zd), particularly the trans- isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited too, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32). The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.
摘要翻译：本发明涉及包含用于制备可发泡热塑性组合物的至少一种氢氯氟烯烃（HCFO）的发泡剂组合物。本发明的HCFO包括但不限于1-氯-3,3,3-三氟丙烯（HCFO-1233zd），特别是反式异构体2-氯-3,3,3-三氟丙烯（HCFO -1233xf），二氯氟化丙烯及其混合物。本发明的发泡剂组合物与包括二氧化碳，气氛气体，氢氟烃（HFC），氢氟烯烃（HFO），烷烃，氢氟醚（HFE））及其混合物的助熔剂一起使用。在本发明中用作起泡剂的优选的HFCs包括但不限于1,1,1,2-四氟乙烷（HFC-134a），1,1-二氟乙烷（HFC-152a），1,1,1-三氟乙烷三氟乙烷（HFC-143a），五氟乙烷（HFC-125），二氟甲烷（HFC-32）。发泡剂组合物可用于生产具有改进的k因子的低密度绝缘泡沫。

7. 发明申请

WO2009151669A1 HALOGENATED ALKENE HEAT TRANSFER COMPOSITIONS WITH IMPROVED OIL RETURN 审中-公开
标题翻译：具有改进的油返回的氢化烷烃热转移组合物
公开(公告)号：WO2009151669A1
公开(公告)日：2009-12-17
申请号：PCT/US2009/036266
申请日：2009-03-06
申请人： ARKEMA INC. , VAN HORN, Brett L. , BONNET, Philippe , CHEN, Benjamin B. , ELSHEIKH, Maher Y. , CROOKER, Richard M.
发明人： VAN HORN, Brett L. , BONNET, Philippe , CHEN, Benjamin B. , ELSHEIKH, Maher Y. , CROOKER, Richard M.
IPC分类号： C09K5/00
CPC分类号： C09K5/044 , C09K3/30 , C09K5/045 , C09K2205/112 , C09K2205/122 , C09K2205/126 , C09K2205/32 , C09K2205/40 , C09K2205/41 , C10M171/008 , C10M2203/065 , C10M2203/1006 , C10M2205/028 , C10M2205/0285 , C10M2205/223 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2040/30 , C10N2220/301 , C10N2220/302 , C10N2220/303 , C10N2220/305 , C10N2240/30 , F25B1/053 , F25B1/10 , F25B9/006 , F25B31/002 , F25B2339/047 , F25B2400/18
摘要： The invention relates to heat transfer agents and heat transfer compositions containing hydrocarbon lubricating oils and halogentaed alkene heat transfer fluid that promote oil flow and provide for improved oil return. The heat transfer compositions are useful in various heat transfer systems such as refrigeration, cooling, air conditioning, chiller operations.
摘要翻译：本发明涉及含有烃润滑油和卤代烯烃传热流体的传热剂和传热组合物，其促进油流并提供改善的回油。传热组合物可用于各种传热系统，例如制冷，冷却，空调，冷冻机操作。

8. 发明申请

WO2009003165A1 STABILIZED HYDROCHLOROFLUOROOLEFINS AND HYDROFLUOROOLEFINS 审中-公开
标题翻译：稳定化氢氟醚和氢氟酸
公开(公告)号：WO2009003165A1
公开(公告)日：2008-12-31
申请号：PCT/US2008/068560
申请日：2008-06-27
申请人： ARKEMA INC. , ELSHEIKH, Maher Y. , BONNET, Philippe , CHEN, Benjamin B. , VAN HORN, Brett L.
发明人： ELSHEIKH, Maher Y. , BONNET, Philippe , CHEN, Benjamin B. , VAN HORN, Brett L.
IPC分类号： C08F2/00
CPC分类号： C09K5/045 , A62D1/0028 , A62D1/0057 , C08F2/42 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2325/06 , C08J2375/04 , C09K3/30 , C09K5/044 , C09K2205/126 , C11D3/0073 , C11D3/0084 , C11D7/5018 , C23G5/02809 , C23G5/02861
摘要： Disclosed is a combination of hydrofluoroolefins and/or hydrochlorofluoroolefins with stabilizers wherein the stabilizers minimize the degradation of the hydrofluoroolefins and hydrochlorofluoroolefins during storage, handling and use yet allow for atmospheric degradation. The combinations exhibit low or zero ozone depletion potential and lower global warming potential making them of interest as replacements for chlorofluorocarbons and hydrfluorocarbons. The combinations of the present invention comprise hydrofluoroolefins and/or hydrochlorofluoroolefins in combination with a stabilizer or stabilizers selected from free radical scavengers, acid scavengers, oxygen scavengers, polymerization inhibitors and combinations thereof.
摘要翻译：公开了氢氟烯烃和/或氢氯氟烯烃与稳定剂的组合，其中稳定剂使储存，处理和使用期间氢氟烯烃和氢氯氟烯烃的降解最小化，但允许大气降解。这些组合表现出低或零臭氧消耗潜力和较低的全球变暖潜力，使其成为氯氟烃和氢氟碳化物的替代品。本发明的组合包括与选自自由基清除剂，酸清除剂，除氧剂，聚合抑制剂及其组合的稳定剂或稳定剂组合的氢氟烯烃和/或氢氯氟烯烃。

9. 发明申请

WO2011130108A1 PROCESS FOR THE MANUFACTURE OF TETRAFLUOROOLEFINS 审中-公开
标题翻译：四氢呋喃的制备方法
公开(公告)号：WO2011130108A1
公开(公告)日：2011-10-20
申请号：PCT/US2011/031689
申请日：2011-04-08
申请人： ARKEMA INC. , ELSHEIKH, Maher Y. , BONNET, Philippe , CHEN, Benjamin B.
发明人： ELSHEIKH, Maher Y. , BONNET, Philippe , CHEN, Benjamin B.
IPC分类号： C07C17/08
CPC分类号： C07C17/25 , C07C17/087 , C07C17/10 , C07C17/206 , C07C21/18 , C07C19/10 , C07C21/04
摘要： A method for producing a tetrafluoroolefin, such as 2,3,3,3-tetrafluoropropene (HFO-1234yf), comprises contacting 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb) with or without a catalyst under conditions effective to convert the 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb) to the tetrafluoroolefin, optionally, via an intermediate. The conversion may be a one-step fluorination or a two-step fluorination and dehydrochlorination process. The 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb) may also be obtained by dehydrochlorinating 1,2,3-trichloropropane (HCC-260da) to form 2,3-dichloropropene (HCO-1250xf); fluorinating 2,3-dichloropropene (HCO-1250xf) to form 1,2-dichloro-2-fluoropropane (HCFC-261bb); and chlorinating 1,2-dichloro-2-fluoropropane (HCFC-261bb) to form 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb).
摘要翻译：一种生产四氟烯烃（如2,3,3,3-四氟丙烯（HFO-1234yf））的方法包括使1,1,1,2-四氯-2-氟代丙烷（HCFC-241bb）与或不与催化剂接触有效地将1,1,1,2-四氯-2-氟丙烷（HCFC-241bb）转化为四氟烯烃的条件，任选地经由中间体。转化可以是一步氟化或两步氟化和脱氯化氢过程。 1,1,1,2-四氯-2-氟丙烷（HCFC-241bb）也可以通过脱氯化氢化1,2,3-三氯丙烷（HCC-260da）得到2,3-二氯丙烯（HCO-1250xf）; 氟化2,3-二氯丙烯（HCO-1250xf）以形成1,2-二氯-2-氟丙烷（HCFC-261bb）; 和氯化1,2-二氯-2-氟丙烷（HCFC-261bb）以形成1,1,1,2-四氯-2-氟丙烷（HCFC-241bb）。

10. 发明申请

WO2010059493A1 PROCESS FOR THE MANUFACTURE OF HYDROFLUOROOLEFINS 审中-公开
标题翻译：氢氟虫腈的制备方法
公开(公告)号：WO2010059493A1
公开(公告)日：2010-05-27
申请号：PCT/US2009/064139
申请日：2009-11-12
申请人： ARKEMA INC. , ELSHEIKH, Maher Y. , BONNET, Philippe , WISMER, John A.
发明人： ELSHEIKH, Maher Y. , BONNET, Philippe , WISMER, John A.
IPC分类号： C07C17/00
CPC分类号： C07C17/20 , C07C17/206 , C07C17/25 , C07C17/358 , C07C21/18 , C07C21/04
摘要： The invention relates to a process for manufacturing 1,1,1,2- tetrafluoropropene (1234yf, CF 3 -CF=CH 2 ) from 1,1,3,3- tetrachlororopropene (1230za, CCl 2 =CH-CHCl 2 ) and/or 1,1,1,3,3-pentachloropropane (240fa, CCl 3 CH 2 CHCl 2 ). The process comprises an isomerization step of 1-chloro- 3,3,3 trifluoropropene (1233zd, CF 3 -CH=CHCl) to 2-chloro- 3,3,3 trifluoropropene (1233xf or CF 3 -CCl=CH 2 ).
摘要翻译：本发明涉及从1,1,3,3-四氯丙烯（1230za，CCl 2 = CH-CHCl 2）和/或1,1-二氯乙烷制备1,1,1,2-四氟丙烯（1234yf，CF 3 -CF = CH 2） 1,1,3,3-五氯丙烷（240fa，CCl3CH2CHCl2）。该方法包括1-氯-3,3,3-三氟丙烯（1233zd，CF 3 -CH = CHCl）与2-氯-3,3,3-三氟丙烯（1233xf或CF 3 -CCl = CH 2）的异构化步骤。

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