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1. 发明申请

WO2006087084A3 PROCESS FOR DEHYDRATING GLYCEROL TO ACROLEIN 审中-公开
标题翻译：将甘氨酸脱水成ACROLEIN的方法
公开(公告)号：WO2006087084A3
公开(公告)日：2007-01-18
申请号：PCT/EP2006000736
申请日：2006-01-06
申请人： ARKEMA FRANCE , DUBOIS JEAN-LUC , DUQUENNE CHRISTOPHE , HOELDERICH WOLFGANG , KERVENNAL JACQUES
发明人： DUBOIS JEAN-LUC , DUQUENNE CHRISTOPHE , HOELDERICH WOLFGANG , KERVENNAL JACQUES
IPC分类号： C07C45/52
CPC分类号： B01J21/066 , B01J21/06 , B01J23/002 , B01J23/30 , B01J27/053 , B01J27/16 , B01J37/20 , B01J37/28 , B01J2523/00 , C07C45/52 , C07C47/22 , B01J2523/48 , B01J2523/69 , B01J2523/41 , B01J2523/31 , B01J2523/51 , B01J2523/62
摘要： The present invention relates to a process for manufacturing acrolein by gas-phase dehydration of glycerol in the presence of strongly acidic solid catalysts with a Hammett acidity H 0 of between -9 and -18 and preferably between -10 and -16.
摘要翻译：本发明涉及一种通过气相脱水甘油制备丙烯醛的方法，所述丙烯醛在强酸性固体催化剂存在下，哈米特酸度H 0为-9至-18，优选为-10 和-16。

2. 发明申请

WO2004002980A3 METHOD FOR SYNTHESIZING COUMARIN AND THE DERIVATIVES THEREOF 审中-公开
标题翻译：法合成香豆素及其衍生物的
公开(公告)号：WO2004002980A3
公开(公告)日：2004-03-04
申请号：PCT/EP0306987
申请日：2003-07-01
申请人： GRUENENTHAL GMBH , HOELDERICH WOLFGANG , LAUFER MONIKA CORNELIA
发明人： HOELDERICH WOLFGANG , LAUFER MONIKA CORNELIA
IPC分类号： C07D311/20
CPC分类号： C07D311/20 , Y02P20/584
摘要： The invention relates to an environmentally friendly, heterocatalytic method for synthesizing coumarins based on phenols and carboxylic acids/carboxylic acid derivatives or ss-keto carboxylic acids/carboxylic acid derivatives. Alkylation of the aromatic phenol ring is assisted by an additional functional group of the carboxylic acids/carboxylic acid derivatives while the coumarin unit is formed. High yields can be obtained by using Nafion-silica composite materials. Particularly silica composites that are loaded with 20 to 80 percent of Nafion have a very high activity (compared with pure Nafion resin) due to the high number of acidic cores in connection with the improved active surface thereof. An efficient Pechmann reaction can be carried out by simple preparation in toluene, the catalyst being recyclable and/or regenerable.
摘要翻译：本专利申请描述了一种用于从苯酚和羧酸/羧酸衍生物或β-酮羧酸/羧酸衍生物开始香豆素的合成中的生态友好的非均相催化过程。通过羧酸/羧酸衍生物的另一种官能团，芳族酚环的烷基化被支撑在形成香豆素单元的。通过使用的Nafion - 二氧化硅复合材料，高产量可以实现的。载货特别是与由大量酸中心的与所述增强的活性表面积（相对于纯的Nafion树脂）具有非常高活性的连接证明20-80％的Nafion二氧化硅的复合材料。一种高效pechmann缩合反应通过简单的在甲苯中，与催化剂的可追踪性和/或再生工作起来是可能的。

3. 发明申请

WO2013190038A2 SUPPORTED CATALYSTS FOR PRODUCING ALDOL CONDENSATION PRODUCTS 审中-公开
标题翻译：负载型催化剂用于生产ALDOLKONDENSATEN
公开(公告)号：WO2013190038A2
公开(公告)日：2013-12-27
申请号：PCT/EP2013062872
申请日：2013-06-20
申请人： SYMRISE AG , HOELDERICH WOLFGANG , RITZERFELD VERENA
发明人： HOELDERICH WOLFGANG , RITZERFELD VERENA
IPC分类号： C07C45/72
CPC分类号： B01J23/10 , B01J21/063 , B01J21/066 , B01J37/031 , C07C45/74 , C07D307/46 , C07C49/248 , C07C47/232 , C07C49/255
摘要： The invention relates to novel supported catalysts which can be obtained by applying rare-earth metal oxides to a TiO2 and/or ZrO2 support.
摘要翻译：提出了新的载体上的催化剂，通过在TiO 2和/或ZrO 2载体稀土金属的氧化物的应用获得。

4. 发明专利

CA2054170A1 PRODUCTION OF CHLOROFLUOROCARBON-FREE URETHANE-CONTAINING SOFT-ELASTIC MOLDINGS HAVING A CELLULAR CORE AND A COMPACTED PERIPHERAL ZONE 未知
公开(公告)号：CA2054170A1
公开(公告)日：1992-04-27
申请号：CA2054170
申请日：1991-10-24
申请人： HORN PETER , HOELDERICH WOLFGANG , TADDEY RUDOLF , TINTELNOT DIETER
发明人： HORN PETER , HOELDERICH WOLFGANG , TADDEY RUDOLF , TINTELNOT DIETER
IPC分类号： B29C45/00 , B29C44/00 , B29K75/00 , B29L31/56 , C08G18/00 , C08G18/08 , C08G101/00 , C08J9/00 , C08J9/02 , C08J9/34 , C08K7/26 , C08L75/00
摘要： The invention relates to a process for the production of soft-elastic mouldings which contain urethane groups and are free from chlorofluorocarbons (CFCs), and have a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) crystalline, microporous molecular sieves having a cavity diameter and cavity entrance aperture of less than 1.3 nm, comprising metal oxides or metal phosphates and optionally further additives, and g) assistants, in a closed mould with compaction, expediently by reaction injection moulding (RIM).

5. 发明专利

DE102008027350A1 Preparing acrolein and acrylic acid, comprises dehydration of glycerin with or without oxygen and water in a catalyst bed filled with a tungsten-containing titanium dioxide carrier catalyst 未知
公开(公告)号：DE102008027350A1
公开(公告)日：2009-12-17
申请号：DE102008027350
申请日：2008-06-07
申请人： HOELDERICH WOLFGANG
发明人： HOELDERICH WOLFGANG , UELGEN ARDA
IPC分类号： C07C47/22 , B01J23/64 , C07C57/04
摘要： Preparing acrolein and acrylic acid, comprises dehydration of glycerin with or without oxygen and water in a catalyst bed filled with a tungsten-containing titanium dioxide carrier catalyst.

6. 发明专利

DE10212593A1 Lubricant and pressure transfer agent comprises oleochemicals with the double bonds epoxidized and converted to ketones by heterogeneous catalysis 未知
公开(公告)号：DE10212593A1
公开(公告)日：2003-07-24
申请号：DE10212593
申请日：2002-01-12
申请人： HOELDERICH WOLFGANG F
发明人： HOELDERICH WOLFGANG , RIOS LUIS ALBERTO , WECKES PATRICK , SCHUSTER HANS
IPC分类号： C10M105/34 , C10M129/70 , C07C51/373 , C07C67/313 , C07C69/716 , C10M105/24 , C10M129/40 , C11C3/00
摘要： Lubricant and pressure transfer agent comprises oleochemicals with the double bonds epoxidized and converted to ketones by heterogeneous catalysis using an environmentally friendly process. An Independent claim is also included for the preparation of the lubricant and pressure transfer agent by preparing epoxides of oleochemicals, fatty acids and/or fatty acid derivatives and heterogeneously catalyzing to ketones.

7. 发明专利

DE10002516A1 New neocarboxylic acids useful for producing compositions, especially lubricants and pressure transmission agents, comprise fatty acids and/or derivatives with acyloxylated double bond(s) 未知
公开(公告)号：DE10002516A1
公开(公告)日：2001-07-26
申请号：DE10002516
申请日：2000-01-21
申请人： HOELDERICH WOLFGANG F
发明人： HOELDERICH WOLFGANG , FISCHER JUTTA , KELLER ULRICH , WECKES PATRICK
IPC分类号： C07C59/305 , C07C59/66 , C07C69/67 , C10M101/04 , C10M105/34 , C10M105/38 , C10M129/68 , C10M129/70 , C10M129/74 , C07B41/08 , C07B41/06 , C07B41/12 , C07C51/16 , C07C51/347 , C07C59/00 , C07C59/125 , C07C67/30 , C10M105/24 , C11B3/00
摘要： New neocarboxylic acids for the production of compositions, especially lubricants and pressure transmission agents, are 3-propyloxy-2,2-dimethylpropionic acid, 3-butyloxy-2,2-dimethylpropionic acid, 3-isobutyloxy-2,2-dimethylpropionic acid, 3-(2-ethylbutyloxy)-2,2-dimethylpropionic acid, 3-benzyloxy-2,2-dimethylpropionic acid and 3-(2-methylphenyloxy)-2,2-dimethylpropionic acid. Independent claims are also included for: (1) Compositions, especially lubricants and pressure transmission agents, containing fatty acids and/or fatty acid derivatives, in which >= 1 double bond is acyloxylated. (2) The preparation of these compositions by acylating double bond(s) of fatty acid(s) and/or derivative(s) with carboxylic acids, anhydrides or halides.

8. 发明专利

DE19845975A1 Epoxide production from olefin, oxygen and hydrogen uses zeolitic oxidation catalyst produced by impregnating titanium or vanadium silicate with alkali(ne earth) salt and then platinum metal(s) 未知
公开(公告)号：DE19845975A1
公开(公告)日：2000-03-02
申请号：DE19845975
申请日：1998-08-27
申请人： HOELDERICH WOLFGANG
发明人： HOELDERICH WOLFGANG , LAUFER WILHELM
IPC分类号： B01J29/04 , C07D301/06
摘要： In the production of epoxides from olefins, oxygen and hydrogen on an oxidation catalyst based on titanium or vanadium silicates with zeolite structure, which contains 0.01-20 wt.% ruthenium, rhodium, palladium, osmium, iridium and/or platinum, the catalyst is produced by impregnating the silicate with an aqueous and/or organic solution of alkali(ne earth) salt and then with noble metal(s).

9. 发明专利

DE10200971A1 Lubricant and pressure transfer agent comprises oleochemicals with the double bonds epoxidized and then reacted with aliphatic alcohols 未知
公开(公告)号：DE10200971A1
公开(公告)日：2003-07-24
申请号：DE10200971
申请日：2002-01-12
申请人： HOELDERICH WOLFGANG
发明人： HOELDERICH WOLFGANG , RIOS LUIS ALBERTO , WECKES PATRICK , SCHUSTER HANS
IPC分类号： C07C67/31 , C10M105/34 , C10M129/70 , C07C67/313 , C07C69/708 , C10M105/22 , C10M129/26 , C11C3/00
摘要： Lubricant and pressure transfer agent comprises oleochemicals with the double bonds epoxidized and then reacted with aliphatic alcohols using an environmentally friendly process. An Independent claim is also included for the preparation of the lubricant and pressure transfer agent by preparing epoxides of oleochemicals, fatty acids and/or fatty acid derivatives and reacting with aliphatic alcohols.

10. 发明专利

DE10014922A1 New neocarboxylic acids useful for producing compositions, especially lubricants and pressure transmission agents, comprise fatty acids and/or derivatives with acyloxylated double bond(s) 未知
公开(公告)号：DE10014922A1
公开(公告)日：2001-10-31
申请号：DE10014922
申请日：2000-03-24
申请人： HOELDERICH WOLFGANG F
发明人： HOELDERICH WOLFGANG , KELLER ULRICH , FISCHER JUTTA , WECKES PATRICK
IPC分类号： C07C59/305 , C07C59/66 , C07C69/67 , C10M101/04 , C10M105/34 , C10M105/38 , C10M129/68 , C10M129/70 , C10M129/74 , C07C67/04 , C07C69/76 , C10M105/32 , C10M129/78 , C11C3/00
摘要： New neocarboxylic acids for the production of compositions, especially lubricants and pressure transmission agents, are 3-propyloxy-2,2-dimethylpropionic acid, 3-butyloxy-2,2-dimethylpropionic acid, 3-isobutyloxy-2,2-dimethylpropionic acid, 3-(2-ethylbutyloxy)-2,2-dimethylpropionic acid, 3-benzyloxy-2,2-dimethylpropionic acid and 3-(2-methylphenyloxy)-2,2-dimethylpropionic acid. Independent claims are also included for: (1) Compositions, especially lubricants and pressure transmission agents, containing fatty acids and/or fatty acid derivatives, in which >= 1 double bond is acyloxylated. (2) The preparation of these compositions by acylating double bond(s) of fatty acid(s) and/or derivative(s) with carboxylic acids, anhydrides or halides.

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