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    • 7. 发明申请
    • METHOD FOR PREPARING ALKALI METAL SULPHIDE
    • 制备碱金属硫化物的方法
    • WO2014076416A9
    • 2014-07-17
    • PCT/FR2013052725
    • 2013-11-13
    • ARKEMA FRANCE
    • SCHMITT PAUL GUILLAUMEFREMY GEORGES
    • C01B17/22
    • C01B17/22
    • The present invention concerns a method for preparing an alkali metal sulphide, from at least one oxygenated alkali metal compound comprising at least one step a) consisting of reacting said oxygenated alkali compound(s) with at least one sulphur compound of formula (I): in which: - R represents a linear or branched alkyl or alkenyl radical, containing 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms; - n is equal to 0, 1 or 2; - x is equal to 0 or to a whole number having a value of between 1 and 10, preferably x is a whole number equal to 1, 2, 3 or 4; - R' represents a linear or branched alkyl or alkenyl radical, containing 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms or, only if n = x = 0, a hydrogen atom; -or indeed R and R' can form, together and with the sulphur atom(s) bearing them, a sulphur heterocycle containing 2 to 12 carbon atoms, preferably 2 to 8 carbon atoms, and optionally one or a plurality of heteroatoms chosen from oxygen, nitrogen and sulphur.
    • 本发明涉及一种由至少一种含氧碱金属化合物制备碱金属硫化物的方法,该方法包括至少一个步骤a),其包括使所述氧化的碱性化合物与至少一种式(I)的硫化合物反应: 其中:-R表示含有1至6个碳原子,优选1至4个碳原子的直链或支链烷基或链烯基; - n等于0,1或2; - x等于0或具有介于1和10之间的整数,优选x是等于1,2,3或4的整数; -R'表示含有1至6个碳原子,优选1至4个碳原子的直链或支链烷基或烯基,或仅在n = x = 0时,氢原子; - 或者确实,R和R'可以与含有它们的硫原子一起形成含有2至12个碳原子,优选2至8个碳原子的硫杂环,以及任选的一个或多个选自氧的杂原子 ,氮和硫。