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    • 3. 发明申请
    • PROCESS FOR PRODUCING CELLULOSIC MOLDINGS
    • 方法制备纤维素状体
    • WO1996018761A1
    • 1996-06-20
    • PCT/EP1995004873
    • 1995-12-11
    • AKZO NOBEL NVCONNOR, Hans-GeorgBUDGELL, Derek
    • AKZO NOBEL NV
    • D01F02/00
    • C08J5/18C08J2301/02D01F2/00D01F13/02Y02P70/627
    • A process for producing molded fibers, filaments, threads, films, membranes in the form of flat, tubular and hollow fiber membranes, etc., wherein cellulosic solutions in an amine oxide of a tertiary amine and optionally water, especially in N-methylmorpholine-N-oxide and water, are forced through an extrusion die and the resulting molding is precipitated in a regenerating bath and washed, the regenerating bath liquid and wash water being reprocessed, optionally for purposes of recuperating the amine oxide of the tertiary amine, is characterized by the addition of hydrogen peroxide, peracetic acid, ozone or chlorine dioxide to the regenerating bath and/or the wash water. The added substances can be preferably catalytically or enzymatically broken down before the water and solvent are recuperated.
    • 用于生产成型制品如纤维,长丝,纱线,薄膜,膜在平膜,软管膜和中空纤维膜等等的形式的处理进行说明。 通过在叔胺的胺氧化物,如果需要水按压纤维素溶液,特别是在N-甲基吗啉-N-氧化物和水,通过喷嘴并在凝固浴中沉淀时,所得模制品的洗涤,其中一个凝固浴液和洗涤水,如果必要的话,为回收 叔胺的氧化胺的进行后处理,其特征在于,加入沉淀浴和/或洗涤水,过氧化氢,过乙酸,臭氧或二氧化氯。 所添加的物质可水和溶剂回收之前优选催化或酶促分解。
    • 6. 发明申请
    • MEMBRANE MODULE WITH HOLLOW FIBRE MEMBRANES ARRANGED IN LAYERS
    • 与聚能层膜组件布置的中空纤维膜
    • WO1998028064A1
    • 1998-07-02
    • PCT/EP1997007083
    • 1997-12-17
    • AKZO NOBEL NVBAURMEISTER, UlrichWOLLBECK, Rudolf
    • AKZO NOBEL NV
    • B01D63/02
    • B01D61/00B01D63/024B01D63/026B01D63/04B01J20/321B01J20/3212B01J20/3219B01J20/3236B01J20/3248B01J20/3251B01J20/3257B01J20/3259B01J20/3261B01J20/3274B01J20/3285B01J35/06
    • Method and device for material-specific fluid treatment, the device comprising a housing (3) with a distribution area (8) and a collection area (9), between which a construction of adjacent, flat first and second layers (18, 19) is arranged, which contain first and/or second hollow fibre membranes (1,2), and a matrix, at which material-specifically acting groups for fluid treatment are immobilized, the filling ratio epsilon of the housing (3), determined by the hollow fibre membranes and the matrix, is greater than 0.55. The first hollow fibre membranes (1) are open towards the distribution area (8) and closed towards the collection area (9), and the second hollow fibre membranes (2) are open towards the collection area (9) and closed towards the distribution area (8). The hollow fibre membranes are immersed at least at their open end (10, 12) in casting compounds (6,7). The layers contained in the device are, substantially, of equal thickness, and each first layer is(18), at least on one of its sides, adjacent to a second layer (19), and each second layer (19) is, at least on one of its sides, adjacent to a first layer (18).
    • 装置和方法用于特定物质的流体处理,该装置包括一个外壳(3)与分配空间(8)和一收集室(9)中,相互相邻的,平面的第一层和第二层的结构(18,19)被布置在它们之间, 第一和第二中空纤维膜(1,2)包含,和一个矩阵被固定在用于流体处理,其中,通过所述中空纤维膜和所述壳体的所述基质填充比的ε-所确定的特定物质的基团(3)是大于0.55。 第一中空纤维膜(1)是在分配器空间的方向开口(8),并在收集空间(9)被关闭,第二中空纤维膜(2)在收集空间(9)的方向打开,并且在分配器空间(8)的方向关闭,方向和 中空纤维膜是开放的至少在其在封装化合物端部(10,12)(6,7)嵌入。 中包含的器件层是基本上相同的厚度,并且每个第一层(18)至少邻近其一侧的第二层(19)和每个第二层(19)至少在其一侧的第一层( 18)。
    • 8. 发明申请
    • IMPROVED GAS PHASE PROCESS FOR FORMING POLYKETONES
    • 改进形成聚酮的气相工艺
    • WO1996000254A1
    • 1996-01-04
    • PCT/US1995008050
    • 1995-06-26
    • AKZO NOBEL NVHANNA, Paul, K.
    • AKZO NOBEL NVCHERON, Teresa, M.PETERSON, Claude, B.
    • C08G67/02
    • C08G67/02
    • Polyketones can be formed in enhanced yield by conducting the polymerization of the carbon monoxide and olefin monomers used to form the polyketone in a gas phase polymerization process in the presence of a polyketone catalyst support which is substantially saturated with an amount of a liquid, non-polymerizable diluent which is effective in increasing the amount of polyketone formed over that which would be formed in the substantial absence of the diluent. The catalyst support which is substantially saturated with the liquid, non-polymerizable diluent is formed in a previous solution polymerization step in which the polyketone catalyst support is formed by polymerizing carbon monoxide and an olefin in the diluent comprising a catalyst so that the polymer which is formed adsorbs substantially all the diluent followed by continuation of the reaction substantially in the gas phase in the presence of the saturated polyketone catalyst support.
    • 聚酮可以通过在气相聚合过程中用于形成聚酮的一氧化碳和烯烃单体的聚合在聚酮催化剂载体存在下进行聚合而形成,所述聚酮催化剂载体基本上用一定量的液体, 可聚合的稀释剂有效地增加在基本上不存在稀释剂时形成的聚酮的量。 基本上被液体不可聚合的稀释剂饱和的催化剂载体在之前的溶液聚合步骤中形成,其中聚酮催化剂载体通过在包含催化剂的稀释剂中聚合一氧化碳和烯烃形成,使得聚合物是 形成的吸附基本上所有的稀释剂,随后在饱和聚酮催化剂载体的存在下基本上在气相中继续反应。
    • 10. 发明申请
    • FLAME RETARDED, STABILIZED POLYESTER COMPOSITION
    • 阻燃,稳定的聚酯组合物
    • WO1996013545A1
    • 1996-05-09
    • PCT/US1995013730
    • 1995-10-23
    • AKZO NOBEL NVMOY, Paul, Y.ALESSIO, Gerald, R.
    • AKZO NOBEL NV
    • C08K05/3492
    • C08K5/523C08K5/0008
    • Flame retarded and stabilized polyester composition contain: (a) a polyester resin derived from a cyclohexanemethanol and a carbocyclic acid; (b) a polyphosphate containing a bridging unit between the phosphate moieties therein which is derived from an arylene-containing diol; and (c) a stabilizer which is either: (i) a combination of a hindered phenol-substituted isocyanurate and an epichlorohydrin-bisphenol A reaction product; or (ii) a combination of an ester of a hindered phenol and oxidized polyethylene; when the arylene-containing diol is a monoarylene-containing diol, such as resorcinol or hydroquinone; or (iii) a hindered phenol-substituted isocyanurate; or (iv) a phenolic oxamide antioxidant; or (v) combination of a hindered phenol-substituted isocyanurate and an epichlorohydrin-bisphenol A reaction product; or (vi) combination of an ester of a hindered phenol and oxidized polyethylene; when the arylene-containing diol is a biarylene-containing diol with an alkylene bridging group between the two arylene groups, such as bisphenol A.
    • 阻燃和稳定的聚酯组合物包含:(a)衍生自环己烷甲醇和碳环酸的聚酯树脂; (b)在其中衍生自含亚芳基的二醇的磷酸酯部分之间含有桥连单元的多磷酸酯; 和(c)稳定剂,其为:(i)受阻酚取代的异氰脲酸酯和表氯醇 - 双酚A反应产物的组合; 或(ii)受阻酚和氧化聚乙烯的酯的组合; 当含亚芳基的二醇是含单亚芳基的二醇时,例如间苯二酚或氢醌; 或(iii)受阻酚取代的异氰脲酸酯; 或(iv)酚醛酰胺抗氧化剂; 或(v)受阻酚取代的异氰脲酸酯和表氯醇 - 双酚A反应产物的组合; 或(vi)受阻酚与氧化聚乙烯的酯的组合; 当含亚芳基的二醇是在两个亚芳基之间具有亚烷基桥连基团的双亚芳基的二醇时,例如双酚A.