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    • 3. 发明申请
    • PROCESSES INVOLVING THE USE OF ANTISOLVENT CRYSTALLIZATION
    • 涉及使用抗结晶的方法
    • WO2006045795A3
    • 2006-11-09
    • PCT/EP2005055527
    • 2005-10-25
    • AKZO NOBEL NVBARGEMAN GERRALDDEMMER RENE LODEWIJK MARIATEN KATE ANTOONKUZMANOVIC BORISVAN LARE CORNELIS ELIZABETH JOMAYER MATEO JOZEF JACQUESSCHUTYSER MAARTEN ANDRE IRENEVAN STRIEN CORNELIS JOHANNES G
    • BARGEMAN GERRALDDEMMER RENE LODEWIJK MARIATEN KATE ANTOONKUZMANOVIC BORISVAN LARE CORNELIS ELIZABETH JOMAYER MATEO JOZEF JACQUESSCHUTYSER MAARTEN ANDRE IRENEVAN STRIEN CORNELIS JOHANNES G
    • C01D3/16C01D3/06
    • C01D3/16C01D3/06
    • The present invention pertains to a process involving the use of an antisolvent comprising the steps of - feeding water to a salt source to form an aqueous solution comprising said salt if the salt source is not yet in the form of an aqueous salt solution, - feeding said aqueous solution to a crystallizer/settler, - contacting said aqueous solution with one or more antisolvents which force the salt to at least partly crystallize, with one or more crystal growth inhibitors being present in the antisolvents and/or in the aqueous solution, and/or one or more scaling inhibitors being present in the antisolvents and/or in the aqueous solution, - subjecting an overflow of the crystallizer/settler comprising one or more antisolvents and an aqueous salt solution to a separation step wherein one or more antisolvents are separated from the aqueous salt solution by one or more techniques selected from the group consisting of adsorption, ion-exchange, a temperature change induced phase split, a pH change induced phase split, a complexation induced phase split, a pressure induced phase split, evaporation, and extraction, optionally in combination with a nanofiltration step, - removing the crystallized salt from the crystallizer/settler in an aqueous slurry, - optionally, recycling the one or more antisolvents to the crystallizer/settler, and - optionally, recycling mother liquor from the slurry to the first dissolution step and/or to the crystallizer/settler. Preferably, the process is a closed loop process and the salt is sodium chloride. Preferably, the process further comprises a reverse osmosis step before the overflow of the crystallizer/settler is subjected to the separation step.
    • 本发明涉及一种涉及使用抗溶剂的方法,包括以下步骤:如果盐源不是盐水溶液的形式,则将水送入盐源以形成包含所述盐的水溶液, - 进料 将所述水溶液与所述结晶器/沉淀器接触, - 使所述水溶液与一种或多种使溶液至少部分结晶的抗溶剂接触,一种或多种晶体生长抑制剂存在于反溶剂和/或水溶液中,以及 /或一种或多种防垢剂存在于抗溶剂和/或水溶液中; - 将包含一种或多种抗溶剂和盐水溶液的结晶器/沉降器的溢流物经受分离步骤,其中分离出一种或多种抗溶剂 通过一种或多种选自吸附,离子交换,温度变化诱导相分裂,pH值 任选地与纳滤方法组合, - 以水性浆液从结晶器/沉降器中除去结晶的盐, - 任选地,循环使用 向结晶器/沉降器中提供一种或多种抗溶剂,以及 - 任选地将母液从浆料再循环到第一溶解步骤和/或将结晶器/沉降器循环。 优选地,该方法是闭环方法,盐是氯化钠。 优选地,该方法还包括在结晶器/沉降器的溢流进行分离步骤之前的反渗透步骤。