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    • 7. 发明申请
    • (CO)POLYMER MODIFICATION EMPLOYING UNSATURATED t-ALKYL PEROXY ALKENES
    • (CO)聚合物改性使用不饱和的t-ALKYL过氧化物
    • WO1991000300A1
    • 1991-01-10
    • PCT/EP1990001041
    • 1990-06-27
    • AKZO N.V.JELENIC, JerneyMEIJER, John
    • AKZO N.V.
    • C08F08/50
    • C08F8/50C08F110/06C08F110/02
    • Novel organic unsaturated tertiary alkyl peroxy alkenes are disclosed and a process of modifying (co)polymers employing these peroxy alkenes is also disclosed. (Co)polymers are modified by contacting them with one or more of these organic peroxides and decomposing the peroxide. By this process the physical properties of the (co)polymers, such as adhesion to polar substrates and lap shear strength, can be enhanced. According to a preferred embodiment, the modification reaction is carried out in the presence of a coagent whereby the advantageous polymer properties, such as adhesion to polar materials, are further enhanced. Also disclosed are shaped objects manufactured using the modified (co)polymers prepared by the process of the present invention.
    • 公开了新的有机不饱和叔烷基过氧烯烃,还公开了使用这些过氧烯烃改性(共)聚合物的方法。 (Co)聚合物通过使它们与一种或多种这些有机过氧化物接触并分解过氧化物而被改性。 通过该方法,可以提高(共)聚合物的物理性质,例如对极性基材的粘附和搭接剪切强度。 根据优选的实施方案,改性反应在助洗剂的存在下进行,由此有利的聚合物性质如与极性材料的粘合性进一步提高。 还公开了使用通过本发明的方法制备的改性(共)聚合物制造的成形物体。