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1. 发明公开

EP0010807A1 Derivatives of branched-chain monocarboxylic acids, engine lubricating oils, lubricant compositions for polymers, wax compositions in which these derivatives are incorporated and a process for preparing said branched-chain monocarboxylic acids 失效
标题翻译：的支化的一元羧酸，发动机润滑油，用于聚合物的润滑剂组合物，蜡组合物，其中这些衍生物都包括在内，并在使这些支化单羧酸的方法衍生物。
公开(公告)号：EP0010807A1
公开(公告)日：1980-05-14
申请号：EP79200612.4
申请日：1979-10-25
申请人： AKZO N.V.
发明人： Zeilstra, Jacobus Johannes , Bik, Joannes Dominicus , De Klein, Willem Jan , Vis, Jan
IPC分类号： C07C53/128 , C07C51/00 , C07C69/22 , C07C103/44 , C07D295/12 , C08G65/32 , C08K5/04 , C08K5/16 , C08L91/00
CPC分类号： C07D295/13 , C07C53/126 , C07C53/128 , C10M105/32 , C10M129/26 , C10M129/92 , C10M129/95 , C10M133/16 , C10M133/56 , C10M2207/125 , C10M2207/129 , C10M2207/28 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/289 , C10M2209/103 , C10M2209/104 , C10M2209/109 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/224 , C10M2215/227 , C10M2215/26 , C10M2215/28 , C10M2217/046 , C10M2217/06 , C10N2210/00 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2220/02 , C10N2240/62
摘要： Derivatives of branched-chain monocarboxylic acids are disclosed. Such derivatives are selected from the group consisting of

a) esters of phenols or aromatic, aliphatic or cycloaliphatic alcohols having at least 1 to 10 primary or secondary hydroxyl groups;
b) amides of ammonia or aliphatic, cycloaliphatic or aromatic amines having at least 1 to 15 primary or secondary amino groups;
c) salts of alkali metals or alkaline earth metals, amphoteric metals, heavy metals, of ammonium or of a compound containing a tertiary amino group.

The branched-chain monocarboxylic acids are telomeric acids obtained by the free radical addition of 1 mole of acetic anhydride to at least three moles of hexene and/ or higher olefins containing up to 30 or more carbon atoms (C 301 ) in the presence of a trivalent manganese compound. The products of this invention are suitable for use in engine lubricating oils, lubricant compositions for polymers and wax compositions.
摘要翻译：的支链一元羧酸的衍生物是游离缺失盘。搜索衍生物选自酚或芳族，脂族或环脂族醇的）酯具有至少1至10个伯或仲羟基基团中选择; b）具有至少1〜15的伯或仲氨基的氨或脂肪族，脂环族或芳族胺的酰胺; C）碱金属或碱土金属，两性金属，重金属，铵或含有叔氨基的化合物的盐。该变白链一元羧酸是通过自由基加成1倍摩尔的乙酸酐，以己烯中的至少三摩尔和/或更高的烯烃中的三价的存在下含有多达30个或更多碳原子（C30 +）获得端粒酸锰化合物。本发明的产品适合于在发动机中使用的润滑油，润滑油组合物为聚合物和蜡的组合物。

3. 发明公开

EP0032777A2 Process for the preparation of sulphur-containing additives for use in lubricant compositions and a lubricant composition in which there is incorporated a sulphur-containing additive 失效
标题翻译：一种制备含硫添加剂用于润滑剂组合物和在其中添加硫添加剂的润滑剂组合物的方法。
公开(公告)号：EP0032777A2
公开(公告)日：1981-07-29
申请号：EP81200065.1
申请日：1981-01-20
申请人： AKZO N.V.
发明人： De Klein, Willem Jan , Vis, Jan
IPC分类号： C08F2/38 , C08F8/34 , B01J31/20 , C10M1/38
CPC分类号： C10M135/02 , C08F2/38 , C10M2219/02 , C10M2219/024 , C10M2221/041
摘要： A process for the preparation of sulphur-containing additives for use in lubricant compositions, in which process an organic carboxylic acid, an ester and/or amide derived therefrom is/are sulphurized in a manner known in itself.
The carboxylic acid or the acid from which the ester and/or amide are/is derived is obtained by telomerization under inert conditions of an ethylenically unsaturated compound in the presence of an at least trivalent manganese compound with a carbonyl compound whose alpha-carbon atom carries at least one hydrogen atom, with the proviso that

a. the carbonyl compound contains at least 60% by weight of a carboxylic anhydride;
b. a trivalent manganese compound is present in an amount of 10- 3 to 10 -10 moles;
c. the molar ratio of the converted amount of ethylenically unsaturated compounds to said trivalent manganese compound is at least 4.

There is also provided a lubricant composition in which there is incorporated a sulphur-containing additive obtained by the above-process.
摘要翻译：一种制备含硫添加剂用于润滑剂组合物，在有机羧酸的哪个进程的进程为酯和/或酰胺衍生的从被/在本身已知的方式硫化。 ... 的羧酸或从其中酯和/或酰胺衍生是通过调聚反应在至少三价的锰化合物的存在下烯属不饱和化合物与是谁的羰基化合物的惰性条件下获得的/酸 α-碳原子带有至少一个氢原子，条件是...一个。的羰基化合物含有按重量计的羧酸酐中的至少60％; ...湾三价锰化合物的存在以10个摩尔<1> <0>量< - - > <3> 10 <>; ...℃。烯属不饱和化合物对所述三价锰化合物中的转化量的摩尔比为至少第四... 由此提供其中存在并入通过上述方法得到的含硫的添加剂的润滑剂组合物。

4. 发明公开

EP0011325A1 Resin composition having improved internal and external lubricating properties 失效
标题翻译：合成树脂组合物具有改善的内部和外部的润滑性能。
公开(公告)号：EP0011325A1
公开(公告)日：1980-05-28
申请号：EP79200613.2
申请日：1979-10-25
申请人： AKZO N.V.
发明人： Zeilstra, Jacobus Johannes , Bik, Joannes Dominicus , De Klein, Willem Jan , Vis, Jan
IPC分类号： C08L27/06 , C08K5/09 , C08K5/10 , C08K5/20 , C08K5/29 , C10M7/28 , B29C1/04 , C07C69/22
CPC分类号： C08K5/0016 , C08L27/06
摘要： The present disclosure relates to a resin composition having improved internal and external lubricating properties. The resin compositions comprises polyvinyl chloride or a copolymer thereof and one or more branched-chain mono- carboxylic acids and/or derivatives thereof. Such derivatives are selected from the group consisting of

a) esters of phenols or aromatic, aliphatic or cycloaliphatic alcohols having at least 1 to 10 primary or secondary hydroxyl groups;
b) amides of ammonia or aliphatic, cycloaliphatic or aromatic amines having at least 1 to 15 primary or secondary amino groups;
c) salts of alkali metals or alkaline earth metals, amphoteric metals, heavy metals, of ammonium or of a compound containing a tertiary amino group.

The branched-chain monocarboxylic acids are telomeric acids obtained by the free radical addition of 1 mole of acetic anhydride to at least three moles of hexene and/or higher olefins containing up to 30 or more carbon atoms (C30.) in the presence of a trivalent manganese compound.

5. 发明授权

EP0032777B1 Process for the preparation of sulphur-containing additives for use in lubricant compositions and a lubricant composition in which there is incorporated a sulphur-containing additive 失效
标题翻译：制备用于润滑剂组合物的含硫添加剂的方法和含有含硫添加剂的润滑剂组合物
公开(公告)号：EP0032777B1
公开(公告)日：1984-12-05
申请号：EP81200065.1
申请日：1981-01-20
申请人： AKZO N.V.
发明人： De Klein, Willem Jan , Vis, Jan
IPC分类号： C08F2/38 , C08F8/34 , B01J31/20 , C10M1/38
CPC分类号： C10M135/02 , C08F2/38 , C10M2219/02 , C10M2219/024 , C10M2221/041

6. 发明授权

EP0011325B1 Resin composition having improved internal and external lubricating properties 失效
标题翻译：具有改进的内部和外部润滑性能的树脂组合物
公开(公告)号：EP0011325B1
公开(公告)日：1983-06-08
申请号：EP79200613.2
申请日：1979-10-25
申请人： AKZO N.V.
发明人： Zeilstra, Jacobus Johannes , Bik, Joannes Dominicus , De Klein, Willem Jan , Vis, Jan
IPC分类号： C08L27/06 , C08K5/09 , C08K5/10 , C08K5/20 , C08K5/29 , C10M7/28 , B29C1/04 , C07C69/22
CPC分类号： C08K5/0016 , C08L27/06

7. 发明公开

EP0032777A3 Process for the preparation of sulphur-containing additives for use in lubricant compositions and a lubricant composition in which there is incorporated a sulphur-containing additive 失效
标题翻译：制备用于润滑剂组合物的含硫添加剂的方法和含有含硫添加剂的润滑剂组合物
公开(公告)号：EP0032777A3
公开(公告)日：1981-08-05
申请号：EP81200065
申请日：1981-01-20
申请人： AKZO N.V.
发明人： De Klein, Willem Jan , Vis, Jan
IPC分类号： C08F02/38 , C08F08/34 , B01J31/20 , C10M01/38 , C08F10/00
CPC分类号： C10M135/02 , C08F2/38 , C10M2219/02 , C10M2219/024 , C10M2221/041
摘要： A process for the preparation of sulphur-containing additives for use in lubricant compositions, in which process an organic carboxylic acid, an ester and/or amide derived therefrom is/are sulphurized in a manner known in itself. The carboxylic acid or the acid from which the ester and/or amide are/is derived is obtained by telomerization under inert conditions of an ethylenically unsaturated compound in the presence of an at least trivalent manganese compound with a carbonyl compound whose alpha-carbon atom carries at least one hydrogen atom, with the proviso that
a. the carbonyl compound contains at least 60% by weight of a carboxylic anhydride; b. a trivalent manganese compound is present in an amount of 10- 3 to 10 -10 moles; c. the molar ratio of the converted amount of ethylenically unsaturated compounds to said trivalent manganese compound is at least 4. There is also provided a lubricant composition in which there is incorporated a sulphur-containing additive obtained by the above-process.

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