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1. 发明申请

WO2016201615A1 ALDEHYDE SCAVENGERS FOR POLYURETHANE FOAMS 审中-公开
标题翻译：聚氨酯泡沫塑料的ALDEHYDE SCAVENGERS
公开(公告)号：WO2016201615A1
公开(公告)日：2016-12-22
申请号：PCT/CN2015/081524
申请日：2015-06-16
申请人： AIR PRODUCTS AND CHEMICALS, INC. , SU, Sheng
发明人： SU, Sheng , BURDENIUC, Juan Jesus , LAL, Gauri Sankar , AL-RASHID, Jennifer E. A. , PANITZSCH, Torsten
IPC分类号： C08G18/00 , C08G18/30 , C08K3/22 , C08K5/20 , C08K5/13 , C08K5/138
CPC分类号： C08G18/72 , C08G18/00 , C08G18/1825 , C08G18/1833 , C08G18/30 , C08G18/3203 , C08G18/4829 , C08G18/6688 , C08G18/7671 , C08G2101/0008 , C08G2101/0083 , C08G2290/00 , C08K3/22 , C08K3/26 , C08K3/28 , C08K3/30 , C08K5/07 , C08K5/13 , C08K5/138 , C08K5/17 , C08K5/20 , C08K5/34922 , C08K2003/285 , C08K2003/3054 , C08L75/04
摘要： A polyurethane composition comprising an aldehyde scavenger, a polyurethane product, and a process for making polyurethane foam are disclosed. The scavenger compounds can reduce, if not eliminate, the emissions of aldehydes from polyurethane foams. The scavenger compounds comprise at least one member selected from the group consisting of: phenol or substituted phenol, a 1, 3-dicarbonyl compound, a polyamine bearing a 1, 3-propanediamino function, melamine, a 1, 2-diaminocycloalkane, an ammonium salt; a compound containing the bisulfite anion, titanium dioxide and aminosiloxane.
摘要翻译：公开了一种包含醛清除剂，聚氨酯产品和制备聚氨酯泡沫的方法的聚氨酯组合物。清除剂化合物可以减少（如果不消除）来自聚氨酯泡沫的醛的排放。清除剂化合物包含至少一种选自苯酚或取代苯酚，1,3-二羰基化合物，带有1,3-丙二氨基官能团的多胺，三聚氰胺，1,2-二氨基环烷烃，铵盐; 含有亚硫酸氢盐阴离子，二氧化钛和氨基硅氧烷的化合物。

2. 发明申请

WO2016205436A1 ALDEHYDE SCAVENGERS MIXTURES FOR POLYURETHANE FOAMS 审中-公开
标题翻译：用于聚氨酯泡沫塑料的ALDEHYDE SCAVENGERS混合物
公开(公告)号：WO2016205436A1
公开(公告)日：2016-12-22
申请号：PCT/US2016/037734
申请日：2016-06-16
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： BURDENIUC, Juan Jesus , LAL, Gauri Sankar , AL-RASHID, Jennifer E.A. , PANITZSCH, Torsten
IPC分类号： C08G18/48 , C08G18/66 , C08G18/76 , C08G18/32 , C08G18/34
CPC分类号： C08G18/089 , C08G18/14 , C08G18/3228 , C08G18/3234 , C08G18/3246 , C08G18/3275 , C08G18/341 , C08G18/4816 , C08G18/4829 , C08G18/4841 , C08G18/6681 , C08G18/7664 , C08G18/7671 , C08J9/0023 , C08J9/0028 , C08J9/12 , C08J2375/08
摘要： A polyurethane composition comprising a mixture comprising at least two aldehyde scavengers, a polyurethane product, and a process for making polyurethane foam are disclosed. The mixture of scavenger compounds can reduce, if not eliminate, the emissions of aldehydes from polyurethane foams. The scavenger compounds comprise at least one member selected from the group consisting of: phenol or substituted phenol, a 1,3-dicarbonyl compound, a polyamine bearing a 1,3- propanediamino function, melamine, a 1,2-diaminocycloalkane, an ammonium salt, and aminosiloxane.
摘要翻译：公开了一种包含至少两种醛清除剂，聚氨酯产品和制备聚氨酯泡沫的方法的混合物的聚氨酯组合物。清除剂化合物的混合物可以减少（如果不能消除）来自聚氨酯泡沫的醛的排放。所述清除剂化合物包含至少一种选自苯酚或取代苯酚，1,3-二羰基化合物，带有1,3-丙二氨基官能团的多胺，三聚氰胺，1,2-二氨基环烷烃，铵盐和氨基硅氧烷。

3. 发明申请

WO2013002963A1 REDUCING EMISSIONS IN POLYURETHANE FOAM 审中-公开
标题翻译：降低聚氨酯泡沫中的排放
公开(公告)号：WO2013002963A1
公开(公告)日：2013-01-03
申请号：PCT/US2012/040652
申请日：2012-06-04
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , THURAU, Courtney Thompson , KELLER, Renee Jo , ARNOLD, Allen Robert, Jr.
发明人： BURDENIUC, Juan Jesus , THURAU, Courtney Thompson , KELLER, Renee Jo , ARNOLD, Allen Robert, Jr.
IPC分类号： B01J31/04 , B01J31/02 , C08G18/18
CPC分类号： B01J31/04 , B01J31/0237 , B01J31/0238 , B01J31/0244 , B01J31/0249 , B01J2231/14 , C08G18/1875 , C08G18/4072 , C08G18/4841 , C08G18/632 , C08G2101/0008 , C08G2101/0083 , C08G2290/00
摘要： This invention disclosure relates to a process to make flexible open cell polyurethane foam with optimum mechanical properties and lowest chemical emissions. Using the selection of tertiary amine catalysts together with a group of carboxylic acids according to this disclosure can produce foam products with optimum properties and lowest chemical emanations.
摘要翻译：本发明涉及制备具有最佳机械性能和最低化学物质排放的柔性开孔聚氨酯泡沫的方法。使用根据本公开的叔胺催化剂与一组羧酸的选择可以生产具有最佳性能和最低化学发射的泡沫产品。

4. 发明申请

WO2016196643A1 REACTIVE AMINE CATALYSTS FOR POLYURETHANE APPLICATIONS 审中-公开
标题翻译：用于聚氨酯应用的反应性胺催化剂
公开(公告)号：WO2016196643A1
公开(公告)日：2016-12-08
申请号：PCT/US2016/035286
申请日：2016-06-01
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： BURDENIUC, Juan Jesus , PANITZSCH, Torsten , XI, Kai , KELLER, Renee Jo
IPC分类号： C08G18/76 , C08G18/18 , C08G18/65
CPC分类号： C08G18/1825 , C07C273/1809 , C08G18/1841 , C08G18/3203 , C08G18/657 , C08G18/7621 , C08G2101/0008 , C08G2101/0083 , C08J9/142 , C08J2205/06 , C08J2375/04
摘要： Tertiary amine catalysts having isocyanate reactive groups that are capable of forming thermally stable covalent bonds able to withstand temperatures up to 120C. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g. indexes as low as 65 but higher than 60) while meeting all physical property requirements; b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25C to 90C); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.
摘要翻译：具有异氰酸酯反应性基团的叔胺催化剂能够形成能够承受温度高达120℃的热稳定共价键。这些催化剂可用于生产具有以下所需特性的聚氨酯泡沫：a）在满足所有物理性能要求的同时，在广泛的环境条件和异氰酸酯指数（例如低至65但高于60的指数）下，化学物质排放量非常低。 b）即使在高于环境温度（温度范围25℃至90℃）的情况下，泡沫暴露于水或水溶液时，b）足够的水解稳定性以保持催化剂共价结合于泡沫体而不浸提叔胺催化剂; 和c）聚氨酯聚合物和其它聚合物（例如聚碳酸酯）之间的稳定的接触界面，其中叔胺催化剂从聚氨酯聚合物到其它聚合物的最小迁移，即使在热和湿度的条件下也在接触点处没有显着的聚合物劣化。

5. 发明申请

WO2016178793A1 DELAYED ACTION GELLING CATALYST COMPOSITIONS AND METHODS FOR MAKING POLYURETHANE POLYMERS 审中-公开
标题翻译：延迟行动胶凝催化剂组合物和制备聚氨酯聚合物的方法
公开(公告)号：WO2016178793A1
公开(公告)日：2016-11-10
申请号：PCT/US2016/026649
申请日：2016-04-08
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： BURDENIUC, Juan Jesus , WENDEL, Stephan Hermann , BRANDL, Christian , PANITZSCH, Torsten , KELLER, Renee Jo
IPC分类号： C08G18/48 , C08G18/63 , C08G18/66 , C08G18/76 , C08G18/20 , C08G18/24 , C08G18/32 , C08G18/34
CPC分类号： C08G18/244 , C08G18/165 , C08G18/1833 , C08G18/1841 , C08G18/2081 , C08G18/24 , C08G18/246 , C08G18/3206 , C08G18/3275 , C08G18/341 , C08G18/4072 , C08G18/4816 , C08G18/4829 , C08G18/4841 , C08G18/632 , C08G18/6674 , C08G18/6688 , C08G18/7621 , C08G18/7664 , C08G2101/0008 , C08G2101/0016 , C08J9/04 , C08J2375/04
摘要： Additives for making polyurethanes are disclosed. The additives are based on combining specific carboxylic acids or carboxylic di-acids together with a gelling catalysts obtained when mixing an isocyanate-reactive tertiary amine catalysts with dimethyl tin di carboxylate salts and/or dimethyltin mercaptide salts.
摘要翻译：公开了制备聚氨酯的添加剂。添加剂基于将特定羧酸或羧酸二酸与将异氰酸酯反应性叔胺催化剂与二甲基二锡二羧酸盐和/或二甲基锡硫醇盐混合时获得的胶凝催化剂组合。

6. 发明申请

WO2013006425A1 ADDITIVES FOR IMPROVING NATURAL OIL BASED POLYURETHANE FOAM PERFORMANCE 审中-公开
标题翻译：改善天然油基聚氨酯泡沫性能的添加剂
公开(公告)号：WO2013006425A1
公开(公告)日：2013-01-10
申请号：PCT/US2012/044892
申请日：2012-06-29
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo , JEON, You-Moon
发明人： BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo , JEON, You-Moon
IPC分类号： C08G18/66 , C08K5/31 , C08K5/315 , C08G18/38
CPC分类号： C08G18/6696 , C08G18/3838 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08J9/0028 , C08J2205/06 , C08J2375/04 , C08K5/31 , C08K5/3155 , C08L75/04
摘要： Polyurethane foam compositions and processes to make flexible polyurethane foams are disclosed. Polyurethane foam is produced in the presence of additives comprising guanidine derivatives. Improvements in physical properties such as air flow, dimensional stability, tensile, tear, elongation and foam hardness is observed when these additives are present in polyurethane formulations. In addition, these additives can minimize polymer degradation under humid ageing conditions resulting in foam products with better mechanical properties.
摘要翻译：公开了聚氨酯泡沫组合物和制备柔性聚氨酯泡沫体的方法。在包含胍衍生物的添加剂的存在下生产聚氨酯泡沫。当这些添加剂存在于聚氨酯配方中时，观察到物理性能如气流，尺寸稳定性，拉伸，撕裂，伸长率和泡沫硬度的改善。此外，这些添加剂可以在潮湿老化条件下使聚合物降解最小化，从而产生具有更好机械性能的泡沫产品。

7. 发明申请

WO2013006413A1 PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM USING NATURAL OIL POLYOLS 审中-公开
标题翻译：使用天然油多酚生产柔性聚氨酯泡沫的方法
公开(公告)号：WO2013006413A1
公开(公告)日：2013-01-10
申请号：PCT/US2012/044860
申请日：2012-06-29
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo
发明人： BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo
IPC分类号： C08G18/30 , C08G18/32 , C08G18/48 , C08G18/66 , C08G18/76
CPC分类号： C08G18/14 , C08G18/302 , C08G18/3206 , C08G18/343 , C08G18/36 , C08G18/4841 , C08G18/6696 , C08G18/7621 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08J2205/06 , C08K5/0008 , C08K5/05 , C08K5/06 , C08K5/20 , C08K5/315 , C08K5/3445 , C08K5/41 , C08K5/45
摘要： A composition and process useful to make flexible polyurethane foams and in particular flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N, N-dimethylacetoacetamide as well as glycols containing hydroxyl numbers OH#
摘要翻译：公开了用于制备柔性聚氨酯泡沫，特别是柔性模塑聚氨酯泡沫的组合物和方法。使用偶极非质子液体如DMSO，DMI，环丁砜，N-甲基 - 乙酰乙酰胺，N，N-二甲基乙酰乙酰胺以及羟基数为OH＃<1100的二醇，作为2-氰基乙酰胺或含有活性的其它类似分子的细胞开放助剂也公开了亚甲基或次甲基以制备聚氨酯泡沫。使用细胞开放助剂的优点导致a）没有泡沫收缩; b）细胞开放剂的使用水平较低; c）泡沫性能重现性d）最佳物理性能。此外，将酸封闭的胺催化剂与开孔剂和开孔剂组合在一起导致较少的腐蚀性混合物，并且提供了不需要机械破碎以进行开孔的方法。

8. 发明申请

WO2016201675A1 TRIMERIZATION CATALYSTS FROM STERICALLY HINDERED SALTS AND TERTIARY AMINES HAVING ISOCYANATE REACTIVE GROUPS 审中-公开
标题翻译：具有异氰酸酯反应性组合的不规则的盐和仲胺的三元催化剂
公开(公告)号：WO2016201675A1
公开(公告)日：2016-12-22
申请号：PCT/CN2015/081809
申请日：2015-06-18
申请人： AIR PRODUCTS AND CHEMICALS, INC. , LENG, Boxun
发明人： LENG, Boxun , BURDENIUC, Juan Jesus , TOBIAS, James Douglas , HOFFMAN, Robert Francis , HU, Xiubing
IPC分类号： C08G18/16 , C08G101/00 , C08G18/18
CPC分类号： C08G18/092 , C08G18/163 , C08G18/1808 , C08G18/1825 , C08G18/225 , C08G18/42 , C08G18/7664 , C08G2101/0025 , C08J9/06 , C08J2205/10 , C08J2207/00
摘要： The present invention provides trimerization catalyst compositions having a sterically hindered carboxylate salt used in combination with a tertiary amine catalysts having isocyanate reactive groups and methods to produce a polyisocyanurate/-polyurethane foam using such trimerization catalyst compositions.
摘要翻译：本发明提供具有与具有异氰酸酯反应性基团的叔胺催化剂组合使用的空间位阻羧酸盐的三聚催化剂组合物和使用这种三聚催化剂组合物制备聚异氰脲酸酯/聚氨酯泡沫的方法。

9. 发明申请

WO2016040783A1 LOW EMISSIONS POLYURETHANE FOAM MADE WITH ISOCYANATE REACTIVE AMINE CRYSTALS 审中-公开
标题翻译：低发射聚氨酯泡沫与异氰酸酯反应性氨基水晶
公开(公告)号：WO2016040783A1
公开(公告)日：2016-03-17
申请号：PCT/US2015/049655
申请日：2015-09-11
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： BURDENIUC, Juan Jesus , PANITZCH, Torsten , KELLER, Renee Jo
IPC分类号： C08G18/66 , C08G18/76 , C08G18/18 , C08G18/32 , C08G18/40 , C08G18/48 , C07C209/60 , C07C211/14 , C08G101/00
CPC分类号： C08G18/1808 , C07C209/48 , C07C211/14 , C07C253/30 , C08G18/0871 , C08G18/14 , C08G18/1825 , C08G18/3275 , C08G18/409 , C08G18/4804 , C08G18/4812 , C08G18/4841 , C08G18/6688 , C08G18/7621 , C08G18/7657 , C08G18/7671 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08J9/0061 , C08J2205/05 , C08J2205/06 , C08J2375/08 , C07C255/24
摘要： Tertiary amine catalysts having isocyanate reactive groups capable of forming thermally stable covalent bonds able to withstand temperatures from 120oC and higher and up to 250oC are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g., indexes as low as 65 but higher than 60); b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25oC to 90oC); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.
摘要翻译：公开了具有能够形成能够承受120℃以上且高达250℃的温度的热稳定共价键的具有异氰酸酯反应性基团的叔胺催化剂。这些催化剂可用于生产具有以下所需特性的聚氨酯泡沫：a）在宽范围的环境条件和异氰酸酯指数（例如低至65但高于60的指数）下的非常低的化学物质排放; b）即使在高于环境温度（温度范围25oC至90oC）的情况下，泡沫暴露于水或水溶液时，b）充分的水解稳定性可保持催化剂共价结合泡沫，而不会浸出叔胺催化剂。和c）聚氨酯聚合物和其它聚合物（例如聚碳酸酯）之间的稳定的接触界面，其中叔胺催化剂从聚氨酯聚合物到其它聚合物的最小迁移，即使在热和湿度的条件下也在接触点处没有显着的聚合物劣化。

10. 发明申请

WO2013074907A1 PROCESSES, PRODUCTS, AND COMPOSITIONS HAVING TETRAALKYLGUANIDINE SALT OF AROMATIC CARBOXYLIC ACID 审中-公开
标题翻译：具有芳香羧酸的四羧基胍盐的方法，产品和组合物
公开(公告)号：WO2013074907A1
公开(公告)日：2013-05-23
申请号：PCT/US2012/065487
申请日：2012-11-16
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , HUHTASAARI, Matti Sakari
发明人： BURDENIUC, Juan Jesus , HUHTASAARI, Matti Sakari
IPC分类号： C08G18/18 , C08G18/32 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/54 , C08G18/63 , C08G18/66 , C08G18/76 , C08G101/00
CPC分类号： C07C63/20 , C08G18/08 , C08G18/1858 , C08G18/1875 , C08G18/3206 , C08G18/3275 , C08G18/4072 , C08G18/42 , C08G18/4841 , C08G18/546 , C08G18/632 , C08G18/6674 , C08G18/6688 , C08G18/7621 , C08G18/7671 , C08G65/00 , C08G2101/0008 , C08G2101/0025 , C08G2101/0083
摘要： Disclosed are processes, products, and compositions having tetraalkylguanidine salt of aromatic acid. The processes include providing a pre-mix comprising an aromatic carboxylic acid component and contacting a tetraalkylguanidine with the aromatic carboxylic acid component in the pre-mix to form the tetraalkylguanidine salt of aromatic carboxylic acid or producing a catalyst composition by contacting the tetraalkylguanidine with the aromatic carboxylic acid component to form the tetraalkylguanidine salt of aromatic carboxylic acid. The compositions include the tetraalkylguanidine salt of aromatic carboxylic acid. The product is formed by the tetraalkylguanidine salt of aromatic carboxylic acid.
摘要翻译：公开了具有芳族酸四烷基胍盐的方法，产品和组合物。该方法包括提供包含芳族羧酸组分的预混物，并将四烷基胍与预混物中的芳族羧酸组分接触以形成芳族羧酸的四烷基胍盐，或通过使四烷基胍与芳族羧酸接触来制备催化剂组合物羧酸组分形成芳族羧酸的四烷基胍盐。组合物包括芳族羧酸的四烷基胍盐。产物由芳族羧酸的四烷基胍盐形成。

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