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1. 发明专利

JPH10133320A COLOR PHOTOGRAPHIC RECORDING MATERIAL 失效
公开(公告)号：JPH10133320A
公开(公告)日：1998-05-22
申请号：JP15169297
申请日：1997-05-27
申请人： AGFA GEVAERT AG
发明人： MISFELDT MICHAEL DR
IPC分类号： G03C7/00 , C07D277/64 , C07D417/14 , C07D421/14 , C09B23/00 , G03C1/035 , G03C1/16
摘要： PROBLEM TO BE SOLVED: To obtain comparatively high blue sensitivity by forming a silver halide emulsion layer sensitized with a specified monomethine cyanine dye. SOLUTION: The color photographic sensitive material has at least one silver halide emulsion layer spectrally sensitized in the blue region with the monomethinecyanine dye characterized by having the formula in which each of R -R is an H or halogen atom or an alkyl, methoxy, aryl, 1-pyrrolyl, 2- pyrrolyl group or the like; each of R and R is an alkyl, sulfoalkyl, carboxyalkyl, -(CH2 )n -SO2 -NH-SO2 -alkyl group or the like; X is an -O-, -S-, -Se- atom, or the like; (a) is an H atom or an aromatic group or a group necessary to form a condensed benzene ring together with (b); (b) is a group necessary to complete the condensed benzene ring together with (a) or (c); (c) is an H atom or an aromatic group or a group necessary to complete the condensed benzene ring together with (b) or (d); and ((A) is an anion present in some case.

2. 发明专利

JP2000095959A CYANINE DYE 失效
公开(公告)号：JP2000095959A
公开(公告)日：2000-04-04
申请号：JP26010099
申请日：1999-09-14
申请人： AGFA GEVAERT AG
发明人： MISFELDT MICHAEL DR , HERRMANN STEFAN DR
IPC分类号： C09B23/00 , C09B23/01 , C09B23/02 , G03C1/12 , G03C1/14 , G03C1/18 , G03C1/20 , G03C1/29
摘要： PROBLEM TO BE SOLVED: To obtain a cyanine dye having an improved spectral sensitivity and excellent storage stability even under tropical conditions by selecting a cyanine dye represented by a specified formula. SOLUTION: There are provided cyanine dyes represented by formulae I and II. There is also provided a silver halide material containing a cyanine color represented by formula I and a cyanine dye represented by formula II is formula I/formula II mixing ratio of 0.1/10 to 10/0.1, particularly desirably, 1/20 to 20/1. In the formulae, R1 to R6 are each H or a substituent; R5 and R6 or R4 and R5 may be combined with each other to form a fused benzo or naphtho ring; R1 to R3 are each a benzothienyl substituent; X, X1, and X2 are each O, S, Se, CH=CH, C(CH3)2, or NR7; R7 is an alkyl; S1 and S2 are each an alkyl, a sulfoalkyl, a carboxyalkyl, a-(CH2)1-SO2-Y-SO2-alkyl, or the like; 1 is 1-6; Y is NH or methine; R14 to R19 are each H, a halogen, or the like; L and L1 to L3 are each methine; M is a counterion necessary to neutralize the charge; and n is 3, 5, or 7.

3. 发明专利

JPH1115097A COLOR PHOTOGRAPHIC RECORDING MATERIAL 失效
公开(公告)号：JPH1115097A
公开(公告)日：1999-01-22
申请号：JP17532698
申请日：1998-06-09
申请人： AGFA GEVAERT AG
发明人： SINZGER KLAUS DR , HERRMANN STEFAN DR , MISFELDT MICHAEL DR
IPC分类号： G03C7/392 , C09B23/04 , G03C1/16
摘要： PROBLEM TO BE SOLVED: To provide the color photographic recording material enhanced in blue sensitivity. SOLUTION: This color photographic recording material contains at least one of photosensitive silver halide emulsion layers spectrally sensitized by a monomethine cyanine dye represented by the formula in which R is a benzothiophene group combining its 2-, 3-, 4-, 5-, 6-, or 7-position with the benzo ring of a benzothiazole group; each of R and R is a sulfoalkyl or carboxyalkyl or -(CH2 )n -NH-SO2 -alkyl group, (n) being 1-6; each of R -R is an H or halogen atom or an alkyl or heterocyclic group or the like, or R is a residue necessary to complete an optionally substituted condensed benzene ring or naphthalene ring together with R or R ; and M is a cation necessary to balance a charge.

4. 发明专利

JPH11212205A COLOR PHOTOGRAPHIC SILVER HALIDE MATERIAL 失效
公开(公告)号：JPH11212205A
公开(公告)日：1999-08-06
申请号：JP30779298
申请日：1998-10-15
申请人： AGFA GEVAERT AG
发明人： WEIMANN RALF DR , MISFELDT MICHAEL DR , GEIGER MARKUS DR
IPC分类号： G03C7/32 , G03C1/035 , G03C1/16 , G03C7/30 , G03C7/305
摘要： PROBLEM TO BE SOLVED: To give a combination of high sensitivity and low fog to a yellow image dye only having slight secondary light absorption by spectrally sensitizing a blue-sensitive layer by using a specified dye and a specified yellow coupler. SOLUTION: The blue-sensitive layer is spectrally sensitized by using a dye represented by formula I and the yellow coupler represented by formula II and in formula I, each of X1 and X2 is O, S, Se, or NR8 ; each of R1 and R2 or each of R2 and R3 may combine with each other to complete a phenanthroazole or anthroazole and each of R3 and R4 is an H atom; each of R6 and R7 is an H atom or an alkyl or aryl group; and M is a counter ion necessary to cancel a charge in the molecule. In formula II, each of R1 -R3 is, independently, an alkyl group; R4 is an alkyl or cycloalkyl group or the like; R5 is a halogen atom or an alkyl group or the like; (m) is 0, 1, 2, or 3; Z1 is -O- or -NR6 -; and Z2 is -NR7 - or C(R8 )R9 .

5. 发明专利

JPH11242302A COLOR PHOTOGRAPHIC SILVER HALIDE MATERIAL 失效
公开(公告)号：JPH11242302A
公开(公告)日：1999-09-07
申请号：JP35911998
申请日：1998-12-17
申请人： AGFA GEVAERT AG
发明人： LY CUONG DR , MISFELDT MICHAEL DR , TEITSCHEID HEINZ-HORST , DRABER EDGAR DR
IPC分类号： G03C7/00 , G03C1/16 , G03C1/29 , G03C7/36
摘要： PROBLEM TO BE SOLVED: To enhance the stability of a latent image, and especially, the blue- sensitivity of a material based on silver chloride by spectrally sensitizing a blue-sensitive silver halide emulsion with a mixture of at least one kind of specified sensitizing dye and at least one kind of specified sensitizing dye. SOLUTION: At least one of the blue-sensitive silver halide emulsions is spectrally sensitized with a mixture of at least one kind of sensitizing dye represented by formula I and at least one kind of sensitizing dye represented by formula II, and in formula I and II, R1 is an optionally substituted thienyl or such pyrrolyl group or the like; each of R2 and R3 is, independently, an alkyl or sulfoalkyl group or the like; R4 is an H or halogen atom or a benzothienyl group or R1 ;M is a cation or anion necessary to balance a charge in the molecule; each of R5 -R7 is an H atom; each of R8 and R9 is same as R2 and R3 ; and R10 is an optionally substituted thienyl or such benzothienyl group.

6. 发明专利

JPH11212206A COLOR PHOTOGRAPHIC SILVER HALIDE MATERIAL 失效
公开(公告)号：JPH11212206A
公开(公告)日：1999-08-06
申请号：JP30780798
申请日：1998-10-15
申请人： AGFA GEVAERT AG
发明人： WEIMANN RALF DR , MISFELDT MICHAEL DR , GEIGER MARKUS DR
IPC分类号： G03C7/32 , G03C1/16 , G03C7/30 , G03C7/305
摘要： PROBLEM TO BE SOLVED: To give a combination of high sensitivity and low fog to a yellow image dye only having slight secondary light absorption by spectrally sensitizing a blue-sensitive layer by using a specified dye and a specified yellow coupler. SOLUTION: The blue-sensitive layer is spectrally sensitized by using a dye represented by formula I and the yellow coupler represented by formula II and in formula I, R1 is a 2- or 3-thienyl group; each of R2 and R3 is, independently, an alkyl or sulfoalkyl or carboxyalkyl group or the like; each of R4 and R5 is, independently, an H or halogen atom or an alkyl or methoxy or aryl group or the like; Z is -O- or -S-; (n) is 1-6; and X is an ion or ions necessary to cancel a charge in the molecule. In formula II, each of R1 -R3 is, independently, an alkyl group; R4 is an alkyl or cycloalkyl group or the like; R5 is a halogen atom or an alkyl group or the like; (m) is 0, 1, 2 or 3; Z1 is -O- or -NR6 -; and Z2 is -NR7 - or -C(R8 )R9 .

7. 发明专利

JPH1073897A PHOTOGRAPHIC SILVER HALIDE EMULSION 失效
公开(公告)号：JPH1073897A
公开(公告)日：1998-03-17
申请号：JP21122397
申请日：1997-07-23
申请人： AGFA GEVAERT AG
发明人： BERGTHALLER PETER DR , SIEGEL JOERG DR , BORST HANS-ULRICH DR , MISFELDT MICHAEL DR
IPC分类号： G03C7/00 , G03C1/18 , G03C1/28
摘要： PROBLEM TO BE SOLVED: To enable super color sensitization without increasing fog or storage fog by using an aromatic complex having a center transition metal atom present in a specified valence state and having a non-aromatic complex ligand to effect super color sensitization. SOLUTION: An aromatic complex is used as combined with a spectral sensitizing element to realize super color sensitization. The aromatic complex used has a center transition metal atom present in such a valence state which is not the possible max. valence of the metal, and the complex has at least one non-aromatic complex ligand. The transition metals suitable for this method are vanadium, chromium, manganese, iron, cobalt, nickel, molybdenum, rhenium, ruthenium rhodium, tungsten, osmium and iridium. The bonding state of the center transition metal atom in the complex is preferably in a valence state lower by 1 than the valence of the transition metal in a low valence inorg. salt. The suitable non-aromatic complex ligands are, for example, CO, R-N=C and NO, wherein R is an alkyl or aryl group, and CO is preferable.

8. 发明专利

JP2000162749A COLOR PHOTOGRAPHIC COPYING MACHINE MATERIAL 失效
公开(公告)号：JP2000162749A
公开(公告)日：2000-06-16
申请号：JP33005799
申请日：1999-11-19
申请人： AGFA GEVAERT AG
发明人： BERGTHALLER PETER DR , JUNG JUERGEN DR , HAGEMANN JOERG DR , DRABER EDGAR DR , MISFELDT MICHAEL DR
IPC分类号： C07D487/04 , G03C1/12 , G03C1/16 , G03C7/00 , G03C7/20 , G03C7/30 , G03C7/38
摘要： PROBLEM TO BE SOLVED: To use a pyrrolo[1,2-b]-1,2,4-triazole cyan coupler for the red-sensitive silver halide emulsion of the color photographic copying machine material and to eliminate the defects of this coupler and to enable its merit to be exhibited. SOLUTION: This color photographic copying machine material contains red- green- and blue-sensitive emulsions each containing at least one kind of cyan, magenta, and yellow couplers, and at least one kind of pyrrolo[1,2-b]-1,2,4- triazole cyan coupler represented by formula I and a red-sensitized silver halide emulsion functions in combination with at least one kind of blue-sensitive emulsion. In formula I, R1 an H atom or the like; X is a releasable group or the like; Y is an OR2 group or a group represented by formula II; R2 is a group represented by formula III or the like; R3 is an alkyl group; R4 is an H atom or the like; each of R5, R6, R8, and R9 is an H atom or the like; R7 is a substituent; and Z is a residual non-metallic atomic member of a 3-8 membered ring.

9. 发明专利

JP2000129151A CYANINE COLORING MATTER 失效
公开(公告)号：JP2000129151A
公开(公告)日：2000-05-09
申请号：JP27967199
申请日：1999-09-30
申请人： AGFA GEVAERT AG
发明人： MISFELDT MICHAEL DR
IPC分类号： C07D413/14 , C07D417/14 , C07D421/14 , C09B23/00 , C09B23/02 , G03C1/005 , G03C1/14 , G03C1/29
摘要： PROBLEM TO BE SOLVED: To obtain the subject coloring matter containing benzoxazole and having at least one indolyl substituent group, excellent in especially a high spectral sensitivity and simultaneously excellent long-term preservation stability especially under tropical conditions and useful as a color photographic silver halide material, etc. SOLUTION: This coloring matter is represented by formula I [R1 to R6 are each a substituent group, with the proviso that at least one of the residues R1 to R3 is indolyl residue; X is O, S, Se or the like; R7 and R8 are each an alkyl, a sulfoalkyl, a carboxyalkyl or the like; Y is NH or N; (n) is 1, 3, 5 or 7; L is a (substituted) methine; M is a counterion, as necessary, required in order to equalize charges], e.g. a compound represented by formula II. Furthermore, the coloring matter is obtained by dissolving a compound represented by formula III in m-cresol, combining the resultant solution with triethyl orthopropionate, carrying out a reaction at 100 deg.C for about 15 min, then cooling the reactional mixture and subsequently apportioning the compound represented by formula III together with triethylamine.

10. 发明专利

JPH11231453A COLOR PHOTOGRAPHIC SILVER HALIDE MATERIAL 失效
公开(公告)号：JPH11231453A
公开(公告)日：1999-08-27
申请号：JP26906698
申请日：1998-09-08
申请人： AGFA GEVAERT AG
发明人： LY CUONG DR , NIETGEN MARIA , MISFELDT MICHAEL DR , TEITSCHEID HEINZ-HORST , DRABER EDGAR DR , GEIGER MARKUS DR
IPC分类号： G03C7/00 , G03C1/09 , G03C1/16 , G03C7/30 , G03C7/305 , G03C7/38
摘要： PROBLEM TO BE SOLVED: To provide a color photographic silver halide material enhanced in latent image stability and sensitivity. SOLUTION: At least one of blue-sensitive silver halide emulsions is doped with mercury and the color photographic silver halide material is obtd. by subjecting the silver halide emulsion to spectral sensitization with a sensitizing dye represented by the formula, in which each of X1 and X2 is, independently, O, S, or Se atom or an NR group; R is an alkyl or carboxyalkyl group; each of R1 and R2 or R2 and R3 is a residual member for completing phenanthrol or anthrazol ring; remaining R1 or R3 is H atom; each of R4 and R5 is, independently, H atom or an alkyl or aryl group or R4 and R5 may combine with each other to form the residual member of an optionally substituted benzoazole or naphthzoaole or phenanthroazole or anthraazole, and each of S1 and S2 is, independently, an alkyl or sulfoalkyl or carboxyalkyl group; and M is a cation necessary to balance charge.

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