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    • 3. 发明专利
    • ITMI990415A1
    • 2000-09-02
    • ITMI990415
    • 1999-03-02
    • AGENCY IND SCIENCE TECHN
    • KIMURA KUNIOSHIN DAE-YONG
    • C03C11/00C03C17/25
    • Disclosed is a method for the preparation of fine hollow glass spheres coated with titanium dioxide from particles of a volcanic vitreous deposit sand occurring in nature. The method comprises the steps of: (a) dispersing the starting particles in an aqueous medium containing hydrogen chloride (or sulfuric acid) and titanium chloride (or titanium sulfate); (b) admixing the aqueous dispersion of the particles with an aqueous alkaline solution such as a solution of ammonium hydrogencarbonate to effect hydrolysis of the titanium chloride (or sulfate) into hydrous titanium oxide forming a coating layer on the particles; and (c) subjecting the particles coated with hydrous titanium oxide to a heat treatment for expansion of the vitreous particles into hollow glass spheres with simultaneous conversion of the hydrous titanium oxide into titanium dioxide forming a coating layer on the hollow glass spheres.
    • 4. 发明专利
    • IT1308634B1
    • 2002-01-09
    • ITMI990415
    • 1999-03-02
    • AGENCY IND SCIENCE TECHN
    • KIMURA KUNIOSHIN DAE-YONG
    • C03C11/00C03C17/25
    • Disclosed is a method for the preparation of fine hollow glass spheres coated with titanium dioxide from particles of a volcanic vitreous deposit sand occurring in nature. The method comprises the steps of: (a) dispersing the starting particles in an aqueous medium containing hydrogen chloride (or sulfuric acid) and titanium chloride (or titanium sulfate); (b) admixing the aqueous dispersion of the particles with an aqueous alkaline solution such as a solution of ammonium hydrogencarbonate to effect hydrolysis of the titanium chloride (or sulfate) into hydrous titanium oxide forming a coating layer on the particles; and (c) subjecting the particles coated with hydrous titanium oxide to a heat treatment for expansion of the vitreous particles into hollow glass spheres with simultaneous conversion of the hydrous titanium oxide into titanium dioxide forming a coating layer on the hollow glass spheres.