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    • 4. 发明申请
    • COMPOSITIONS AND METHODS FOR SELECTIVE REMOVAL OF METAL OR METAL ALLOY AFTER METAL SILICIDE FORMATION
    • 金属硅化物形成后选择性去除金属或金属合金的组合物和方法
    • WO2006138235A2
    • 2006-12-28
    • PCT/US2006/022859
    • 2006-06-13
    • ADVANCED TECHNOLOGY MATERIALS, INC.BERNHARD, David D.WANG, WeihuaBAUM, Thomas H.
    • BERNHARD, David D.WANG, WeihuaBAUM, Thomas H.
    • H01L21/00
    • H01L21/32134C23F1/26C23F1/28
    • An aqueous metal etching composition useful for removal of metals such as nickel, cobalt, titanium, tungsten, and alloys thereof, after formation of metal silicides via rapid thermal annealing during complementary metal-oxide-semiconductor (CMOS) transistor fabrication. The aqueous metal etching composition is also useful for selective removal of metal silicides and/or metal nitrides for wafer re-work. In one formulation, the aqueous metal etching composition contains oxalic acid, and a chloride-containing compound, and in other formulations, the composition contains an oxidizer, such as hydrogen peroxide, and a fluoride source, e.g., borofluoric acid. The composition in another specific formulation contains borofluoric acid and boric acid for effective etching of nickel, cobalt, titanium, tungsten, metal alloys, metal silicides and metal nitrides, without attacking the dielectric and the substrate.
    • 在互补金属氧化物半导体(CMOS)晶体管制造中通过快速热退火形成金属硅化物之后,可用于去除诸如镍,钴,钛,钨及其合金的金属的含水金属蚀刻组合物。 含水金属蚀刻组合物还可用于选择性去除金属硅化物和/或金属氮化物用于晶片再加工。 在一种配方中,含水金属蚀刻组合物含有草酸和含氯化合物,并且在其它配方中,该组合物含有氧化剂,例如过氧化氢和氟化物源,例如硼氟酸。 另一具体制剂中的组合物含有硼氟酸和硼酸,用于有效地蚀刻镍,钴,钛,钨,金属合金,金属硅化物和金属氮化物,而不侵蚀电介质和基底。