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    • 1. 发明申请
    • CHEMICAL SENSOR
    • 化学传感器
    • WO0165248A2
    • 2001-09-07
    • PCT/GB0100793
    • 2001-02-22
    • ACCENTUS PLCPEAT ROBERTRHODES HEDLEY GRAHAMTURNER ANDREW DEREK
    • PEAT ROBERTRHODES HEDLEY GRAHAMTURNER ANDREW DEREK
    • G01N27/38
    • G01N27/38
    • A sensor for detecting chemical properties of a liquid, for example in an oil well, includes a glass pH electrode (22a) and a reference electrode (22c). The glass electrode (22a) consists of a narrow sensor electrode (30) on the surface of an electrically insulating substrate (20), a layer of glass (36) covering the sensor electrode (30), and two cleaning electrodes (32, 33) one extending along each side of the sensor electrode along its entire sensing length. The cleaning electrodes (32, 33) are not covered by the layer of glass, and are no more than 3 mm apart from each other. Application of a voltage between them generates gas bubbles by electrolysis that dislodge any fouling from the glass electrode (22a). The sensor electrode (30) may be of zigzag form, with the cleaning electrodes (32, 33) interdigitated between the successive parts of the zigzag. A hydrophilic membrane (24) of sulphonated microporous PVdF provides further protection against fouling of the electrodes (22) by oil. This provides a compact, solid state sensor, which can be cleaned in situ.
    • 用于检测液体的化学性质的传感器,例如在油井中,包括玻璃pH电极(22a)和参考电极(22c)。 玻璃电极(22a)由电绝缘基板(20)的表面上的窄传感器电极(30),覆盖传感器电极(30)的玻璃层(36)和两个清洁电极(32,33 )沿其整个感测长度沿传感器电极的每一侧延伸。 清洁电极(32,33)不被玻璃层覆盖,并且彼此不超过3毫米。 在它们之间施加电压通过电解产生气泡,从玻璃电极(22a)排出任何结垢。 传感器电极(30)可以是锯齿形,其中清洁电极(32,33)在之字形的连续部分之间交错。 磺化微孔PVdF的亲水膜(24)进一步防止电极(22)被油污染。 这提供了一种紧凑的固态传感器,可以在原位清洁。
    • 3. 发明专利
    • BR0108851A
    • 2003-05-06
    • BR0108851
    • 2001-02-22
    • ACCENTUS PLC
    • PEAT ROBERTRHODES HEDLEY GRAHAMTURNER ANDREW DEREK
    • G01N27/38
    • A sensor for detecting chemical properties of a liquid, for example in an oil well, includes a glass pH electrode (22a) and a reference electrode (22c). The glass electrode (22a) consists of a narrow sensor electrode (30) on the surface of an electrically insulating substrate (20), a layer of glass (36) covering the sensor electrode (30), and two cleaning electrodes (32, 33) one extending along each side of the sensor electrode along its entire sensing length. The cleaning electrodes (32, 33) are not covered by the layer of glass, and are no more than 3 mm apart from each other. Application of a voltage between them generates gas bubbles by electrolysis that dislodge any fouling from the glass electrode (22a). The sensor electrode (30) may be of zigzag form, with the cleaning electrodes (32,33) interdigitated between the successive parts of the zigzag. A hydrophilic membrane (24) of sulphonated microporous PVdF provides further protection against fouling of the electrodes (22) by oil. This provides a compact, solid state sensor, which can be cleaned in situ.
    • 4. 发明专利
    • NO20024124L
    • 2002-10-31
    • NO20024124
    • 2002-08-29
    • ACCENTUS PLC
    • PEAT ROBERTRHODES HEDLEY GRAHAMTURNER ANDREW DEREK
    • G01N27/38G01N
    • A sensor for detecting chemical properties of a liquid, for example in an oil well, includes a glass pH electrode (22a) and a reference electrode (22c). The glass electrode (22a) consists of a narrow sensor electrode (30) on the surface of an electrically insulating substrate (20), a layer of glass (36) covering the sensor electrode (30), and two cleaning electrodes (32, 33) one extending along each side of the sensor electrode along its entire sensing length. The cleaning electrodes (32, 33) are not covered by the layer of glass, and are no more than 3 mm apart from each other. Application of a voltage between them generates gas bubbles by electrolysis that dislodge any fouling from the glass electrode (22a). The sensor electrode (30) may be of zigzag form, with the cleaning electrodes (32,33) interdigitated between the successive parts of the zigzag. A hydrophilic membrane (24) of sulphonated microporous PVdF provides further protection against fouling of the electrodes (22) by oil. This provides a compact, solid state sensor, which can be cleaned in situ.
    • 5. 发明专利
    • NO20024124D0
    • 2002-08-29
    • NO20024124
    • 2002-08-29
    • ACCENTUS PLC
    • PEAT ROBERTRHODES HEDLEY GRAHAMTURNER ANDREW DEREK
    • G01N27/38G01N
    • A sensor for detecting chemical properties of a liquid, for example in an oil well, includes a glass pH electrode (22a) and a reference electrode (22c). The glass electrode (22a) consists of a narrow sensor electrode (30) on the surface of an electrically insulating substrate (20), a layer of glass (36) covering the sensor electrode (30), and two cleaning electrodes (32, 33) one extending along each side of the sensor electrode along its entire sensing length. The cleaning electrodes (32, 33) are not covered by the layer of glass, and are no more than 3 mm apart from each other. Application of a voltage between them generates gas bubbles by electrolysis that dislodge any fouling from the glass electrode (22a). The sensor electrode (30) may be of zigzag form, with the cleaning electrodes (32,33) interdigitated between the successive parts of the zigzag. A hydrophilic membrane (24) of sulphonated microporous PVdF provides further protection against fouling of the electrodes (22) by oil. This provides a compact, solid state sensor, which can be cleaned in situ.
    • 6. 发明专利
    • Chemical sensor
    • AU3395801A
    • 2001-09-12
    • AU3395801
    • 2001-02-22
    • ACCENTUS PLC
    • PEAT ROBERTRHODES HEDLEY GRAHAMTURNER ANDREW DEREK
    • G01N27/38
    • A sensor for detecting chemical properties of a liquid, for example in an oil well, includes a glass pH electrode (22a) and a reference electrode (22c). The glass electrode (22a) consists of a narrow sensor electrode (30) on the surface of an electrically insulating substrate (20), a layer of glass (36) covering the sensor electrode (30), and two cleaning electrodes (32, 33) one extending along each side of the sensor electrode along its entire sensing length. The cleaning electrodes (32, 33) are not covered by the layer of glass, and are no more than 3 mm apart from each other. Application of a voltage between them generates gas bubbles by electrolysis that dislodge any fouling from the glass electrode (22a). The sensor electrode (30) may be of zigzag form, with the cleaning electrodes (32,33) interdigitated between the successive parts of the zigzag. A hydrophilic membrane (24) of sulphonated microporous PVdF provides further protection against fouling of the electrodes (22) by oil. This provides a compact, solid state sensor, which can be cleaned in situ.
    • 7. 发明专利
    • CHEMICAL SENSOR
    • CA2404359A1
    • 2001-09-07
    • CA2404359
    • 2001-02-22
    • ACCENTUS PLC
    • PEAT ROBERTRHODES HEDLEY GRAHAMTURNER ANDREW DEREK
    • G01N27/38
    • A sensor for detecting chemical properties of a liquid, for example in an oil well, includes a glass pH electrode (22a) and a reference electrode (22c). The glass electrode (22a) consists of a narrow sensor electrode (30) on the surface of an electrically insulating substrate (20), a layer of glass (36) covering the sensor electrode (30), and two cleaning electrodes (32, 33) one extending along each side of the sensor electrode along its entire sensing length. The cleaning electrodes (32, 33) are not covered by the layer of glass, and are no more than 3 mm apart from each other. Application of a voltage between them generates gas bubbles by electrolysis that dislodge any fouling from the glass electrode (22a). The sensor electrode (30) may be of zigzag form, with the cleaning electrodes (32,33) interdigitated between the successive parts of the zigzag. A hydrophilic membrane (24) of sulphonated microporous PVdF provides further protection against fouling of the electrodes (22) by oil. This provides a compact, solid state sensor, which can be cleaned in situ.