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1. 发明申请

WO2002060968A1 PERFLUOROELASTOMERS HAVING A LOW GLASS TRANSITION TEMPERATURE AND METHOD OF MAKING THEM 审中-公开
标题翻译：具有低玻璃化转变温度的全氟聚合物及其制备方法
公开(公告)号：WO2002060968A1
公开(公告)日：2002-08-08
申请号：PCT/US2001/003195
申请日：2001-01-31
申请人： 3M INNOVATIVE PROPERTIES COMPANY , COGGIO, William, D. , GROOTAERT, Werner, M. A. , HINTZER, Klaus , MARZ, Franz , PALLARINO, Richard, V. , VAN GOOL, Guy , WORM, Allan, T. , HARE, Erik, D.
发明人： COGGIO, William, D. , GROOTAERT, Werner, M. A. , HINTZER, Klaus , MARZ, Franz , PALLARINO, Richard, V. , VAN GOOL, Guy , WORM, Allan, T. , HARE, Erik, D.
IPC分类号： C08F214/26
CPC分类号： C08F214/18 , C08F14/26 , C08F214/262 , C08F2/16
摘要： A method of making a curable fluoroelastomer is disclosed. The method comprises the steps of preemulsifying at least one perfluorovinylether in water, and copolymerizing the preemulsified perfluorovinylether with a gaseous fluorinated monomer in the presence of a cure site monomer. The method provides a fluoroelastomer having a glass transition temperature of less than -10°C. Also disclosed is a fluoroelastomer that consists essentially of a perfluorovinylether of formula (I) as defined below, a cure site component, perfluoromethylvinylether, and tetrafluoroethylene and/or chlorotrifluoroethylene.
摘要翻译：公开了一种制备可固化的含氟弹性体的方法。该方法包括在水中预乳化至少一种全氟乙烯基醚的步骤，以及在固化部位单体存在下使预乳化的全氟乙烯基醚与气态氟化单体共聚。该方法提供了玻璃化转变温度低于-10℃的含氟弹性体。还公开了一种含氟弹性体，其主要由以下定义的式（I）的全氟乙烯基醚，固化部位组分，全氟甲基乙烯基醚和四氟乙烯和/或三氟氯乙烯。

2. 发明申请

WO2004009660A1 FLUOROPOLYMERS HAVING IMPROVED COMPRESSION SET 审中-公开
标题翻译：具有改进压缩组的氟聚合物
公开(公告)号：WO2004009660A1
公开(公告)日：2004-01-29
申请号：PCT/US2003/014842
申请日：2003-05-13
申请人： 3M INNOVATIVE PROPERTIES COMPANY
发明人： COGGIO, William D., , SCOTT, Peter, J. , HINTZER, Klaus , HARE, Erik, D.
IPC分类号： C08F214/18
CPC分类号： C08F214/16 , C08F214/265
摘要： The present invention provides a curable composition comprising a fluoropolymer comprising interpolymerized units derived from (i) CF 2 =CF-R f , wherein R f is fluorine or a C 1 -C 8 perfluoroalkyl, (ii) at least about 10 mole percent of a hydrogen-containing C 2 -C 9 olefin, based on the total moles of said CF 2 =CFR f and said olefin, (iii) an average of two or more bromine atoms including one or more terminal bromine atom(s) per fluoropolymer chain, (iv) optionally CX 2 =CX-R, wherein each X is independently H, F, or Cl and R is a halogen or a C 1 -C 8 alkyl or alkenyl group that may include one or more ether linkage(s), (v) optionally a bromine-containing cure site monomer; (b) optionally, a peroxide curing agent; and (c) optionally, a crosslinking co-agent.The invention also provides methods of making and using such fluoropolymer compositions.
摘要翻译：本发明提供一种可固化组合物，其包含含氟聚合物，其包含衍生自（i）CF 2 = CF-R f的共聚单元，其中Rf为氟或C1-C8全氟烷基，（ii）至少约10摩尔％的含氢C2 -C9烯烃，基于所述CF 2 = CFR f和所述烯烃的总摩尔数，（iii）平均每个含氟聚合物链包括一个或多个末端溴原子的两个或更多个溴原子，（iv）任选地CX2 = CX -R，其中每个X独立地是H，F或Cl，R是可以包括一个或多个醚键的卤素或C 1 -C 8烷基或烯基，（v）任选的含溴固化位点单体; （b）任选地，过氧化物固化剂; 和（c）任选的交联助剂。本发明还提供制备和使用这种含氟聚合物组合物的方法。

3. 发明授权

EP1373341B1 PERFLUOROELASTOMERS HAVING A LOW GLASS TRANSITION TEMPERATURE AND METHOD OF MAKING THEM 有权
标题翻译： PERFLUOROELASTOMERE低玻璃化温度及其HERSTELUNGSVERFAHREN
公开(公告)号：EP1373341B1
公开(公告)日：2007-06-06
申请号：EP01905296.8
申请日：2001-01-31
申请人： 3M Innovative Properties Company
发明人： COGGIO, William 3M Europe s.a. , GROOTAERT, Werner, M. A. , HINTZER, Klaus 3M Europe s.a. , MARZ, Franz , PALLARINO, Richard 3M Europe s.a. , VAN GOOL, Guy , WORM, Allan 3M Europe s.a. , HARE, Erik, D.
IPC分类号： C08F214/26 , C08F14/26
CPC分类号： C08F214/18 , C08F14/26 , C08F214/262 , C08F2/16
摘要： A method of making a curable fluoroelastomer is disclosed. The method comprises the steps of preemulsifying at least one perfluorovinylether in water, and copolymerizing the preemulsified perfluorovinylether with a gaseous fluorinated monomer in the presence of a cure site monomer. The method provides a fluoroelastomer having a glass transition temperature of less than -10°C. Also disclosed is a fluoroelastomer that consists essentially of a perfluorovinylether of formula (I) as defined below, a cure site component, perfluoromethylvinylether, and tetrafluoroethylene and/or chlorotrifluoroethylene.

4. 发明授权

EP1240125B2 FLUORINE CONTAINING VINYL ETHERS 有权
标题翻译： FLUOR含乙烯基醚
公开(公告)号：EP1240125B2
公开(公告)日：2016-04-20
申请号：EP00926297.3
申请日：2000-04-20
申请人： 3M Innovative Properties Company
发明人： WORM, Allan, T. , MOORE, George, G., I. , GUERRA, Miguel, A. , SCHWERTFEGER, Werner , HINTZER, Klaus , QUI, Zai-Ming , HARE, Erik, D.
IPC分类号： C07C67/307 , C07C41/18 , C07C41/24 , C07C41/48
CPC分类号： C07C41/24 , C07C41/18 , C07C41/48 , C07C67/307 , C07C2601/14 , C07C69/708 , C07C43/17 , C07C43/192 , C07C43/313

5. 发明公开

EP1373341A1 PERFLUOROELASTOMERS HAVING A LOW GLASS TRANSITION TEMPERATURE AND METHOD OF MAKING THEM 有权
标题翻译：具有低玻璃化转变温度的全氟弹性体及其制造方法
公开(公告)号：EP1373341A1
公开(公告)日：2004-01-02
申请号：EP01905296.8
申请日：2001-01-31
申请人： 3M Innovative Properties Company
发明人： COGGIO, William, D. , GROOTAERT, Werner, M. A. , HINTZER, Klaus , MARZ, Franz , PALLARINO, Richard, V. , VAN GOOL, Guy , WORM, Allan, T. , HARE, Erik, D.
IPC分类号： C08F214/26 , C08F14/26
CPC分类号： C08F214/18 , C08F14/26 , C08F214/262 , C08F2/16
摘要： A method of making a curable fluoroelastomer is disclosed. The method comprises the steps of preemulsifying at least one perfluorovinylether in water, and copolymerizing the preemulsified perfluorovinylether with a gaseous fluorinated monomer in the presence of a cure site monomer. The method provides a fluoroelastomer having a glass transition temperature of less than -10°C. Also disclosed is a fluoroelastomer that consists essentially of a perfluorovinylether of formula (I) as defined below, a cure site component, perfluoromethylvinylether, and tetrafluoroethylene and/or chlorotrifluoroethylene.
摘要翻译：公开了制造可固化含氟弹性体的方法。该方法包括在水中预乳化至少一种全氟乙烯基醚，并在固化位点单体存在下将预乳化的全氟乙烯基醚与气态氟化单体共聚合的步骤。该方法提供了具有小于-10℃的玻璃化转变温度的含氟弹性体。还公开了基本由如下定义的式（I）的全氟乙烯基醚，固化部位组分，全氟甲基乙烯基醚和四氟乙烯和/或三氟氯乙烯组成的含氟弹性体。

6. 发明公开

EP1349892A2 COMPOSITION AND METHOD FOR MAKING A FLUOROELASTOMER 有权
标题翻译：组成为FLUOR弹性体生产
公开(公告)号：EP1349892A2
公开(公告)日：2003-10-08
申请号：EP01990745.0
申请日：2001-11-29
申请人： 3M Innovative Properties Company
发明人： HARE, Erik, D. , COGGIO, William, D. , HINTZER, Klaus , KOLB, Robert, E. , SCOTT, Peter, J. , VERSCHUERE, Alain , KASPAR, Harald
IPC分类号： C08L27/12 , C08K5/54 , C08F8/42 , B32B27/30 , C08J3/24 , C08J7/04 , C08F14/18 , C08F8/18
CPC分类号： C08K5/56 , B32B25/08 , B32B25/14 , C08F214/262 , C08F214/265 , C08K5/14 , C08K5/541 , C08K5/5415 , C08K5/544 , C08K5/57 , C08L27/12 , C08L83/04 , C08L83/06 , C08L2666/14
摘要： A composition and method for making a fluoroelastomer is disclosed. The composition comprises a fluoroelastomer containing chlorine and an organic compound containing at least an hydride function. The hydride function has the formula MH where M is Si, Ge, Sn or Pb.

7. 发明授权

EP1539844B1 FLUOROPOLYMERS HAVING IMPROVED COMPRESSION SET 有权
标题翻译：采用改善的压缩SET含氟聚合物
公开(公告)号：EP1539844B1
公开(公告)日：2007-11-14
申请号：EP03765429.0
申请日：2003-05-13
申请人： 3M Innovative Properties Company
发明人： COGGIO, William D., , SCOTT, Peter, J. , HINTZER, Klaus , HARE, Erik, D.
IPC分类号： C08F214/18 , C08F214/26 , C08F214/16 , C08K5/00
CPC分类号： C08F214/16 , C08F214/265
摘要： The present invention provides a curable composition comprising a fluoropolymer comprising interpolymerized units derived from (i) CF2=CF-Rf, wherein Rf is fluorine or a C1-C8 perfluoroalkyl, (ii) at least about 10 mole percent of a hydrogen-containing C2-C9 olefin, based on the total moles of said CF2=CFRf and said olefin, (iii) an average of two or more bromine atoms including one or more terminal bromine atom(s) per fluoropolymer chain, (iv) optionally CX2=CX-R, wherein each X is independently H, F, or Cl and R is a halogen or a C1-C8 alkyl or alkenyl group that may include one or more ether linkage(s), (v) optionally a bromine-containing cure site monomer; (b) optionally, a peroxide curing agent; and (c) optionally, a crosslinking co-agent.The invention also provides methods of making and using such fluoropolymer compositions.

8. 发明授权

EP1349892B1 COMPOSITION FOR MAKING A FLUOROELASTOMER 有权
标题翻译：组成为FLUOR弹性体生产
公开(公告)号：EP1349892B1
公开(公告)日：2007-07-11
申请号：EP01990745.0
申请日：2001-11-29
申请人： 3M Innovative Properties Company
发明人： HARE, Erik, D. , COGGIO, William, D. , HINTZER, Klaus , KOLB, Robert, E. , SCOTT, Peter, J. , VERSCHUERE, Alain , KASPAR, Harald
IPC分类号： C08L27/12 , C08K5/54 , C08F8/42 , B32B27/30 , C08J3/24 , C08J7/04 , C08F14/18 , C08F8/18
CPC分类号： C08K5/56 , B32B25/08 , B32B25/14 , C08F214/262 , C08F214/265 , C08K5/14 , C08K5/541 , C08K5/5415 , C08K5/544 , C08K5/57 , C08L27/12 , C08L83/04 , C08L83/06 , C08L2666/14
摘要： A composition and method for making a fluoroelastomer is disclosed. The composition comprises a fluoroelastomer containing chlorine and an organic compound containing at least an hydride function. The hydride function has the formula MH where M is Si, Ge, Sn or Pb.

9. 发明公开

EP1539844A1 FLUOROPOLYMERS HAVING IMPROVED COMPRESSION SET 有权
标题翻译：采用改善的压缩SET含氟聚合物
公开(公告)号：EP1539844A1
公开(公告)日：2005-06-15
申请号：EP03765429.0
申请日：2003-05-13
申请人： 3M Innovative Properties Company
发明人： COGGIO, William D., , SCOTT, Peter, J. , HINTZER, Klaus , HARE, Erik, D.
IPC分类号： C08F214/18 , C08F214/26 , C08F214/16 , C08K5/00
CPC分类号： C08F214/16 , C08F214/265
摘要： The present invention provides a curable composition comprising a fluoropolymer comprising interpolymerized units derived from (i) CF2=CF-Rf, wherein Rf is fluorine or a C1-C8 perfluoroalkyl, (ii) at least about 10 mole percent of a hydrogen-containing C2-C9 olefin, based on the total moles of said CF2=CFRf and said olefin, (iii) an average of two or more bromine atoms including one or more terminal bromine atom(s) per fluoropolymer chain, (iv) optionally CX2=CX-R, wherein each X is independently H, F, or Cl and R is a halogen or a C1-C8 alkyl or alkenyl group that may include one or more ether linkage(s), (v) optionally a bromine-containing cure site monomer; (b) optionally, a peroxide curing agent; and (c) optionally, a crosslinking co-agent.The invention also provides methods of making and using such fluoropolymer compositions.

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