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    • 2. 发明申请
    • ARTICLES SUBJECT TO ICE FORMATION COMPRISING A REPELLENT SURFACE
    • 受制于包括拒斥表面的冰形成的物品
    • WO2017074708A1
    • 2017-05-04
    • PCT/US2016/056742
    • 2016-10-13
    • 3M INNOVATIVE PROPERTIES COMPANY
    • ELSBERND, Cheryl L.S.MEULER, Adam J.IZZI, Guglielmo MemoMALMBERG, Zachary J.MUEHLE, Thomas E.S.LI, Jian
    • C09D7/00C09D5/00
    • C09D5/00C09D7/00
    • Articles subject to ice formation during normal use are described. The article comprises a repellent surface such that the receding contact angle of the surface with water ranges from 90 degrees to 135 degrees. The repellent surface comprises a fluorochemical material, typically in combination with a non-fluorinated organic polymeric binder. The fluorochemical material is preferably a compound having the formula: (R f -L-P) n A R f is a fluorinated group; L is independently an organic divalent linking group; P is a catenary, divalent heteroatom-containing carbonyl moiety, such as -C(0)0-; A is hydrocarbon moiety; and n typically ranges from 1 to 3. Also described are methods of making an article comprising providing an article subject to ice formation during normal use and providing a liquid repellent surface, as described herein, on at least a portion of the article.
    • 描述了在正常使用期间容易结冰的物品。 所述制品包含排斥表面,使得所述表面与水的后退接触角在90度至135度的范围内。 防水表面包含含氟化合物材料,通常与非氟化有机聚合物粘合剂组合。 含氟化合物材料优选为具有下式的化合物:(Rf-L-P)n Rf f为氟化基团; L独立地为有机二价连接基团; P为含链二价含杂原子的羰基部分,例如-C(O)O-; A是烃部分; 并且n通常在1至3的范围内。还描述了制造制品的方法,包括提供在正常使用期间经受制冰的制品,并且在制品的至少一部分上提供如本文所述的防液表面。 p>
    • 3. 发明申请
    • FLUID CONTROL FILMS WITH HYDROPHILIC SURFACES, METHODS OF MAKING SAME, AND PROCESSES FOR CLEANING STRUCTURED SURFACES
    • 具有水力表面的流体控制膜,其制造方法和清洁结构表面的方法
    • WO2015164468A1
    • 2015-10-29
    • PCT/US2015/027025
    • 2015-04-22
    • 3M INNOVATIVE PROPERTIES COMPANY
    • MEULER, Adam J.CLEAR, Susannah C.SWANSON, Steven P.HALVERSON, Kurt J.RIDDLE, Justin A.ARMSTRONG, Paul B.NELSON, Caleb T.JARIWALA, Chetan P.
    • C08J5/18B32B3/26B32B3/30C03C17/30
    • F25D21/14B08B1/006B08B3/10B32B7/06B32B7/12C08J5/18F15D1/003F15D1/0085
    • A fluid control film is provided that includes fluid control channels extending along a channel longitudinal axis. Each of the fluid control channels has a surface and is configured to allow capillary movement of liquid in the channels. The fluid control film further includes a hydrophilic surface treatment covalently bonded to at least a portion of the surface of the fluid control channels. The fluid control film exhibits a capillary rise percent recovery of at least ten percent. Typically, the hydrophilic surface treatment includes functional groups selected from a non-zwitterionic sulfonate, a non-zwitterionic carboxylate, a zwitterionic sulfonate, a zwitterionic carboxylate, a zwitterionic phosphate, a zwitterionic phosphonic acid, and/or a zwitterionic phosphonate. A process for forming a fluid control film is also provided. Further, a process for cleaning a structured surface is provided, including providing a structured surface and a hydrophilic surface treatment covalently bonded to at least a portion of the structured surface, and soiling the structured surface with a material. The process also includes removing the material by at least one of submerging the structured surface in an aqueous fluid, rinsing the structured surface with an aqueous fluid, condensing an aqueous fluid on the structure surface, or wiping the structured surface with a cleaning implement.
    • 提供流体控制膜,其包括沿着通道纵向轴线延伸的流体控制通道。 每个流体控制通道具有表面并且被构造成允许液体在通道中的毛细管移动。 流体控制膜还包括共价键合到流体控制通道的表面的至少一部分的亲水性表面处理。 流体控制膜表现出至少10%的毛细管上升百分比回收率。 通常,亲水表面处理包括选自非两性离子磺酸盐,非两性离子羧酸盐,两性离子磺酸盐,两性离子羧酸盐,两性离子磷酸盐,两性离子膦酸和/或两性离子膦酸盐的官能团。 还提供了一种用于形成流体控制膜的工艺。 此外,提供了一种用于清洁结构化表面的方法,包括提供结构化表面和共价键合到结构化表面的至少一部分的亲水表面处理,并且用材料污染结构化表面。 该方法还包括通过将结构化表面浸没在水性流体中的至少一种来去除材料,用水性流体冲洗结构化表面,在结构表面上冷凝水性流体,或用清洁工具擦拭结构化表面。