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    • 3. 发明申请
    • PRIMERLESS MULTILAYER ADHESIVE FILM FOR BONDING GLASS SUBSTRATES
    • 用于粘结玻璃基材的无粘结多层粘合膜
    • US20140255679A1
    • 2014-09-11
    • US14349912
    • 2012-10-05
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Siegfried R. GoebSilke D. MechernichSteffen TraserClaudia TorreJan D. Forster
    • C09J7/02
    • C09J7/0217B32B7/12B32B15/046B32B17/06B32B2457/12C03C27/048C08F220/18C09J7/00C09J7/10C09J7/385C09J133/062C09J143/04C09J151/003C09J2201/36C09J2203/322C09J2205/114C09J2433/00C09J2451/00C09J2483/00Y10T428/249954Y10T428/249978Y10T428/287Y10T428/2891C08F2220/1858C08F220/06C08F222/1006
    • A multilayer pressure sensitive adhesive (PSA) film having a first pressure sensitive adhesive layer for bonding glass substrates and at least a second opposing layer, the first pressure sensitive adhesive layer being a polymerization reaction product of a precursor comprising a monomer or a partially prepolymerized monomer, in particular a (meth)acrylate based monomer, having a curable ethylenically unsaturated group, whereas the precursor further comprises an oligomeric organofunctional silane having at least 2 Si atoms, in particular 2 to 10 Si atoms, wherein the monomer having a curable ethylenically unsaturated further has a coupling group with a Zerewitinow-active H-atom and wherein the oligomeric organofunctional silane has at least one coupling group which is reactive to the coupling group of the monomer having a curable ethylenically unsaturated group, or wherein the oligomeric organofunctional silane has at least one coupling group with a Zerewitinow-active H-atom and wherein the monomer having a curable ethylenically unstaurated further has a coupling group which is reactive to the coupling group of the oligomeric organofunctional silane; with the proviso that if the monomer having a curable ethylenically unsaturated group further has a coupling group with a Zerewitinow-active H-atom which is selected to be —OH, then the coupling group of the oligomeric organofunctional silane which is reactive to the coupling group of the monomer having a curable ethylene group cannot be selected to be an amino group.
    • 一种多层压敏粘合剂(PSA)膜,其具有用于粘合玻璃基板的第一压敏粘合剂层和至少第二相对层,所述第一压敏粘合剂层是包含单体或部分预聚单体的前体的聚合反应产物 ,特别是具有可固化的烯属不饱和基团的(甲基)丙烯酸酯基单体,而前体还包含具有至少2个Si原子,特别是2至10个Si原子的低聚有机官能硅烷,其中具有可固化烯属不饱和基团的单体 还具有具有齐维诺诺活性H原子的偶联基团,并且其中所述低聚有机官能硅烷具有至少一个与具有可固化烯键式不饱和基团的单体的偶联基团反应的偶联基团,或其中所述低聚有机官能硅烷具有 至少一个具有Zerewitinow活性H原子的偶联基团,其中 具有非饱和可固化烯键式的单体还具有与低聚有机官能硅烷的偶联基团反应的偶联基团; 条件是如果具有可固化烯键式不饱和基团的单体还具有与选择为-OH的齐维诺诺活性H原子的偶联基团,则与偶联基团反应的低聚有机官能硅烷的偶联基团 的具有可固化的亚乙基的单体不能选择为氨基。
    • 5. 发明申请
    • MULTILAYER PRESSURE-SENSITIVE ADHESIVE FILMS WITH A (METH)ACRYLIC-BASED ELASTOMERIC MATERIAL
    • 具有(甲基)丙烯酸的弹性体材料的多层压敏粘合膜
    • US20140367040A1
    • 2014-12-18
    • US14344800
    • 2012-09-24
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Steffen TraserJan D. ForsterChristiane StrerathJayshree SethArlin L. WeikelMaureen A. KavanaghJason D. ClapperKevin M. LewandowskiZhong Chen
    • C09J7/02
    • The present invention is directed to a multilayer pressure sensitive adhesive (PSA) film, having a first pressure sensitive adhesive layer and at least an opposing layer, wherein the first pressure sensitive adhesive layer comprises a pressure-sensitive adhesive composition with a (meth)acrylic-based elastomeric material comprising a reaction product of polymerizable material comprising: (a) a first monomer which is an alkyl (meth)acrylate ester of a primary alcohol R1—OH, the alkyl (meth)acrylate ester being of Formula (I) CH2═C(R2)—(CO)—OR1 (I) wherein R1 is an alkyl having 14 to 25 carbon atoms and the primary alcohol R1—OH has an iso index equal to at least 2 but no greater than 4; R2 is hydrogen or methyl; and (b) a second monomer having an ethylenically unsaturated group; wherein the at least one opposing layer comprises at least one filler material. The invention is also directed to a method for the manufacturing of such a multilayer PSA film and its use.
    • 本发明涉及具有第一压敏粘合剂层和至少相对层的多层压敏粘合剂(PSA)膜,其中第一压敏粘合剂层包含具有(甲基)丙烯酸类的压敏粘合剂组合物 其包含可聚合材料的反应产物,其包含:(a)第一单体,其为伯醇R 1 -OH的(甲基)丙烯酸烷基酯,(I)(甲基)丙烯酸烷基酯 ≡C(R2) - (CO)-OR1(Ⅰ)其中R1是具有14-25个碳原子的烷基,伯醇R1-OH具有等于至少2但不大于4的iso指数; R2是氢或甲基; 和(b)具有烯属不饱和基团的第二单体; 其中所述至少一个相对层包括至少一种填料。 本发明还涉及制造这种多层PSA膜的方法及其用途。