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1. 发明申请

WO2011096604A1 폐기물을 이용한 칼슘알루미네이트계 클링커 및 그의 제조방법 审中-公开
标题翻译：使用废弃材料的铝酸钙螯合剂及其制造方法
公开(公告)号：WO2011096604A1
公开(公告)日：2011-08-11
申请号：PCT/KR2010/000737
申请日：2010-02-05
申请人： 한국지질자원연구원 , 안지환 , 이성호 , 유광석 , 한기천 , 황선호 , 계상범 , 김형순
发明人： 안지환 , 이성호 , 유광석 , 한기천 , 황선호 , 계상범 , 김형순
IPC分类号： C04B7/48 , C04B7/38 , C04B7/42 , C04B7/43 , C04B18/06 , C04B18/18
CPC分类号： C04B7/367 , C04B7/246 , C04B7/32 , Y02P40/145
摘要： 본 발명은 폐기물을 이용한 칼슘알루미네이트계 클링커 및 그의 제조방법에 관한 것으로, 보다 상세하게는, 석면폐기물, 생활폐기물 소각재, 정수 슬러지, 석고, 형석 및 탄화규소를 적절한 비율로 혼합시킨 다음, 상기 혼합물을 소성하여 제조함으로써 친환경적이고 원가가 저렴한 칼슘알루미네이트계 클링커 및 그의 제조방법에 관한 것이다. 본 발명에 따른 칼슘알루미네이트계 클링커는 소성온도 저감으로 인해 제조과정에 발생되는 이산화탄소의 발생을 줄이고, 폐기물을 이용하여 제조함으로써 친환경적이고 원가가 저렴할 뿐만 아니라, 알칼리 성분을 중화시킬 수 있어 알칼리 성분에 의한 클링커 자체의 품질 저하를 방지하고, 유해한 석면폐기물을 비석면화 시키는 동시에 속경성, 고강도성, 고유동성, 팽창성 등이 우수한 고품질의 시멘트를 제조할 수 있다.
摘要翻译：本发明涉及使用废料的铝酸钙熟料及其制造方法。更具体地说，铝酸钙熟料通过以适当比例混合石棉废料，焚烧生活垃圾灰，净化水泥浆，石膏，萤石和碳化硅，然后煅烧混合物以产生环保且低成本铝酸钙熟料。根据本发明，由于煅烧温度降低和使用废料，在制造铝酸钙熟料的过程中可以减少二氧化碳排放，所得到的铝酸钙熟料是环境友好的并且生产成本低。此外，由于可以中和碱成分，可以除去有害石棉废物的石棉成分，并且具有快速硬化性，高强度，高流动性和高的高品质水泥，因此可以防止由于碱成分导致的熟料本身的质量劣化可扩展性可以制造。

2. 发明公开

KR1020110091177A 이산화탄소가 고정된 생활폐기물 소각 바닥재를 이용한 건축용 자재의 연속 제조 장치 无效
标题翻译：使用固定二氧化碳的城市固体废物焚化底材建造材料的连续制造装置
公开(公告)号：KR1020110091177A
公开(公告)日：2011-08-11
申请号：KR1020100010886
申请日：2010-02-05
申请人： 한국지질자원연구원
发明人： 안지환 , 한기천 , 남성영 , 유광석 , 이성호 , 황선호
IPC分类号： B09B3/00 , C04B18/04 , B27N3/08
CPC分类号： Y02W30/20 , Y02W30/91 , B09B3/00 , B27N3/18 , B27N3/24 , C04B18/0418
摘要： PURPOSE: An apparatus for continuously manufacturing construction materials using incinerated bottom ash is provided to reduce the discharge of carbon dioxide and recycling bottom ash. CONSTITUTION: A raw material(30) containing calcium carbonate which is obtained by drying municipal solid waste-based incinerated bottom ash and a plastic sheath material(20) are continuously transferred on a belt. A secondary drying process is implemented. The secondarily dried materials pass a belt press(50) equipped with a heating unit(40) in order to undergo a compressive shaping process. A cutting process is followed to obtain construction materials. The construction materials are inserted into a packing material and are sealed.
摘要翻译：目的：提供一种用于连续制造使用焚烧炉底灰的建筑材料的设备，以减少二氧化碳的排放和回收底灰。构成：通过干燥基于城市固体废物的焚烧的底灰和塑料护套材料（20）获得的含有碳酸钙的原料（30）在带上连续转移。实施二次干燥处理。二次干燥的材料通过配备有加热单元（40）的带式压榨机（50），以进行压缩成形处理。遵循切割过程获得建筑材料。将建筑材料插入包装材料中并进行密封。

3. 发明公开

KR1020110091169A 플라이 애쉬와 정수슬러지를 이용한 시멘트의 제조방법 无效
标题翻译：使用飞灰和水泥制造水泥的方法
公开(公告)号：KR1020110091169A
公开(公告)日：2011-08-11
申请号：KR1020100010878
申请日：2010-02-05
申请人： 한국지질자원연구원
发明人： 안지환 , 유광석 , 황선호
IPC分类号： C04B18/08 , C04B18/18 , C04B7/48 , C04B28/16
CPC分类号： C04B7/44 , C04B7/48 , C04B18/08 , C04B18/0418 , C04B18/18 , C04B28/16 , C04B7/425
摘要： PURPOSE: A method for manufacturing cement using fly ash and water treatment sludge are provided to reduce cost required for manufacturing the cement and prevent environmental contamination by recycling the fly ash and the water treatment sludge. CONSTITUTION: A method for manufacturing cement includes the following: 20 to 50 weight% of limestone powder and 5 to 10 weight% of water treatment sludge are mixed with 100 weight% of fly ash. The mixture is further pulverized, and the particle sizes of the mixture are between 50 and 100um. The mixture is sintered to obtain clinker at temperature between 1200 and 1400 degrees Celsius. 5 to 20 weight% of gypsum is mixed with the clinker, based on 100 weight% of fly ash to obtain cement. Toxic materials are eliminated from the fly ash by an activated charcoal-based processing process and a heating process.
摘要翻译：目的：提供使用飞灰和水处理污泥制造水泥的方法，以减少制造水泥所需的成本，并通过回收粉煤灰和水处理污泥来防止环境污染。构成：水泥的制造方法包括：将20〜50重量％的石灰石粉和5〜10重量％的水处理污泥与100重量％的飞灰混合。将混合物进一步粉碎，并且混合物的粒径为50至100um。将混合物烧结以在1200至1400摄氏度的温度下获得熟料。将5至20重量％的石膏与熟料混合，基于100重量％的飞灰，得到水泥。通过基于活性炭的加工过程和加热过程从粉煤灰中除去有毒材料。

4. 发明授权

KR101147635B1 ＣａＯ-Ａｌ2Ｏ3-ＳｉＯ2-ＳＯ3-Ｆｅ2Ｏ3 5성분계에서의 폐부산물을 활용한 초속경-고강도 시멘트 제조 방법 有权
标题翻译：具有快速硬化性能的高铝酸钙制备方法和CAO-Al2O3-SIO2-SO3-FE2O3废水处理系统中的高压缩强度
公开(公告)号：KR101147635B1
公开(公告)日：2012-05-23
申请号：KR1020110079870
申请日：2011-08-10
申请人： 한국지질자원연구원
发明人： 유광석 , 안지환 , 이성호 , 황선호
IPC分类号： C04B7/24 , C04B7/44 , C04B7/04
CPC分类号： Y02P40/145
摘要： PURPOSE: A manufacturing method of ultra rapid hardening high strength cement utilizing waste by-products of CaO-Al2O3-SiO2-SO3-Fe2O3 5 component system is provided to synthesize high purity calcium sulfoaluminate at the CaO-Al2O3-SiO2-SO3-Fe2O3 5 component system by controlling content of the waste byproduct. CONSTITUTION: A manufacturing method of ultra rapid hardening high strength cement utilizing waste by-products of CaO-Al2O3-SiO2-SO3-Fe2O3 5 component system produces special cement by applying CM(Calcium Modulus) relational expression from the cement waste byproduct raw material to ratio of sintered product to raw material component. The CM relational expression is CM=100(CaO/(0.70SO3+0.29Fe2O3+ 0.55Al2O3+0.93SiO2));. The special cement comprises calcium sulfoaluminate(4CaO 3Al2O3 SO3)(CSA), Belite(2CaO SiO2)(C2S), and Ferrite(4CaO Al2O3 Fe2O3)(C4AF). Content of CaO included in gypsum is converted into 0.70SO3. The content of CaO included in C4 AF (4CaO-3Al2O3-Fe2O3) is converted into 0.351Fe2O3. The content of CaO included in CSA (4CaO-3Al2O3-SO3) is converted into 0.55Al2O3-0.059Fe2O3. The content of CaO included in C2 S (2CaO-SiO2) is converted into 0.93SiO2.
摘要翻译：目的：利用CaO-Al2O3-SiO2-SO3-Fe2O3 5组分体系的废弃副产物超快硬化高强度水泥的制造方法，在CaO-Al2O3-SiO2-SO3-Fe2O3 5组成体系中合成高纯度磺硅铝酸钙通过控制废物副产物的含量来实现组分体系。构成：利用CaO-Al2O3-SiO2-SO3-Fe2O3 5组分体系的废弃副产物超快速硬化高强度水泥的制造方法，通过从水泥废弃物副产物原料中应用CM（钙模量）关系式产生特殊水泥烧结产品与原料成分的比例。 CM关系式为CM = 100（CaO /（0.70SO3 + 0.29Fe2O3 + 0.55Al2O3 + 0.93SiO2））。特殊水泥包括磺铝酸钙（4CaO 3Al2O3 SO3）（CSA），Belite（2CaO SiO2）（C2S）和铁氧体（4CaO Al2O3 Fe2O3）（C4AF）。包含在石膏中的CaO的含量被转化为0.70SO3。将包含在C4 AF（4CaO-3Al2O3-Fe2O3）中的CaO的含量转化为0.351Fe 2 O 3。将CSA（4CaO-3Al2O3-SO3）中所含的CaO的含量转化为0.55Al2O3-0.059Fe2O3。将包含在C2S（2CaO-SiO2）中的CaO的含量转化为0.93SiO 2。

5. 发明公开

KR1020110091176A 이산화탄소가 고정된 생활폐기물 소각 바닥재를 활용한 건축용 자재 无效
标题翻译：使用固定二氧化碳的城市固体废物焚烧底部建筑材料
公开(公告)号：KR1020110091176A
公开(公告)日：2011-08-11
申请号：KR1020100010885
申请日：2010-02-05
申请人： 한국지질자원연구원
发明人： 안지환 , 유광석 , 이성호 , 한기천 , 황선호
IPC分类号： E04C2/02 , C04B18/08 , B09B3/00 , E01C5/00
CPC分类号： C04B28/005 , Y02W30/96 , C04B18/20 , C04B18/22
摘要： PURPOSE: A construction material using the bottom ashes of domestic waste with carbon dioxide is provided to reduce the emission of carbon dioxide by stably fixing the carbon dioxide. CONSTITUTION: A construction material using the bottom ashes of domestic waste with carbon dioxide is composed as follows. A bottom ash slurry is produced by mixing the bottom ashes of domestic waste with distilled water and stirring the mixture. The slurry is reacted with carbon gas to produce carbon dioxide. The produced carbon dioxide is fixed to a bottom ash gel. The bottom ash gel is dried and is injected as the core of a plastic sheath.
摘要翻译：目的：提供使用二氧化碳生活废物底灰的建筑材料，通过稳定地固定二氧化碳来减少二氧化碳的排放。构成：使用二氧化碳生活废物底灰的建筑材料组成如下。通过将生活垃圾的底部灰分与蒸馏水混合并搅拌混合物来生产底灰浆。浆料与碳气反应生成二氧化碳。将生成的二氧化碳固定在底灰凝胶上。将底灰凝胶干燥并作为塑料护套的芯注入。

6. 发明授权

KR101147634B1 ＣａＯ-Ａｌ2Ｏ3-ＳｉＯ2-ＳＯ3-Ｆｅ2Ｏ3 5성분계에서의 고순도 칼슘설포알루미네이트 합성을 위한 폐부산물의 원료 배합 방법 有权
标题翻译：用于制造CAO-Al2O3-SIO2-SO3-FE2O3系统中的硫酸铝合金水泥的废料原料的混合方法
公开(公告)号：KR101147634B1
公开(公告)日：2012-05-23
申请号：KR1020110079869
申请日：2011-08-10
申请人： 한국지질자원연구원
发明人： 유광석 , 안지환 , 이성호 , 황선호
IPC分类号： C04B7/24 , C04B7/44
CPC分类号： Y02P40/145
摘要： PURPOSE: A raw material of waste by-products mixing method for synthesis of high-purity calcium sulfoaluminate at CaO-Al2O3-SiO2-SO3-Fe2O3 5 component system is provided to control content of the waste byproduct according to lower part CM(Calcium Modulus) relational expression. CONSTITUTION: A material of waste by-products mixing method for synthesis of high-purity calcium sulfoaluminate at CaO-Al2O3-SiO2-SO3-Fe2O3 5 component system synthesize calcium sulfoaluminate(CSA) by applying lower part CM(Calcium Modulus) relational expression to a ratio of sintered product to raw material component. The CM relational expression is 100 (CaO/(0.70SO3+0.29Fe2O3+0.55Al2O3+0.93SiO2));. Content amount of the CaO included in gypsum is converted into 0.70SO3. Content amount of CaO included in C4AF(4CaO-3Al2O3-Fe2O3) is converted into 0.351Fe2O3. The content amount of CaO included in CSA(4CaO-3Al2O3-SO3) is converted into 0.55Al2O3-0.059Fe2O3. The content amount of the CaO included in C2S(2CaO-SiO2) is converted into 0.93SiO2. Each content unit is weight%.
摘要翻译：目的：提供CaO-Al2O3-SiO2-SO3-Fe2O3组分体系中高纯度磺酸铝钙合成废弃物副产物混合原料，根据下部CM（钙模量）控制废弃物副产物含量）关系表达式。构成：在CaO-Al2O3-SiO2-SO3-Fe2O3组分体系合成高纯度磺硅铝酸钙的废副产物混合方法的材料通过将下部CM（钙模量）关系表达式应用于硫磺铝酸钙（CSA）烧结体与原料成分的比例。 CM关系式为100（CaO /（0.70SO3 + 0.29Fe2O3 + 0.55Al2O3 + 0.93SiO2））。包含在石膏中的CaO的含量被转化为0.70SO3。将C4AF（4CaO-3Al2O3-Fe2O3）中含有的CaO的含量转化为0.351Fe 2 O 3。 CSA（4CaO-3Al2O3-SO3）中含有的CaO的含量被转化为0.55Al2O3 -0.059Fe2O3。将包含在C2S（2CaO-SiO2）中的CaO的含量转化为0.93SiO 2。每个内容单元是重量％。

7. 发明授权

KR101089520B1 폐기물을 이용한 칼슘알루미네이트계 클링커 및 그의 제조방법 有权
标题翻译：基于铝酸钙的熟料使用废物及其制备方法
公开(公告)号：KR101089520B1
公开(公告)日：2011-12-05
申请号：KR1020100010880
申请日：2010-02-05
申请人： 한국지질자원연구원
发明人： 유광석 , 안지환 , 황선호 , 이성호 , 계상범 , 김형순
IPC分类号： C04B7/26 , C04B7/48 , C04B7/44 , C04B7/38
CPC分类号： C04B7/44 , C04B7/32 , Y02P40/121 , C04B7/425 , C04B7/427
摘要： 본 발명은 폐기물을 이용한 칼슘알루미네이트계 클링커 및 그의 제조방법에 관한 것으로, 보다 상세하게는, 석면폐기물, 생활폐기물 소각재, 정수 슬러지, 석고, 형석 및 탄화규소를 적절한 비율로 혼합시킨 다음, 상기 혼합물을 소성하여 제조함으로써 친환경적이고 원가가 저렴한 칼슘알루미네이트계 클링커 및 그의 제조방법에 관한 것이다.
본 발명에 따른 칼슘알루미네이트계 클링커는 소성온도 저감으로 인해 제조과정에 발생되는 이산화탄소의 발생을 줄이고, 폐기물을 이용하여 제조함으로써 친환경적이고 원가가 저렴할 뿐만 아니라, 알칼리 성분을 중화시킬 수 있어 알칼리 성분에 의한 클링커 자체의 품질 저하를 방지하고, 유해한 석면폐기물을 비석면화 시키는 동시에 속경성, 고강도성, 고유동성, 팽창성 등이 우수한 고품질의 시멘트를 제조할 수 있다.

8. 发明公开

KR1020110091174A 칼슘클로로알루미네이트 광물을 함유하는 인공토양용 고화재 无效
标题翻译：含有氯化钙的固体人造土壤
公开(公告)号：KR1020110091174A
公开(公告)日：2011-08-11
申请号：KR1020100010883
申请日：2010-02-05
申请人： 한국지질자원연구원
发明人： 안지환 , 유광석 , 한기천 , 황선호 , 이성호
IPC分类号： C09K17/40 , C09K103/00
CPC分类号： C09K17/40 , C02F11/00 , C09K2103/00
摘要： PURPOSE: A solidifying material for artificial soil is provided to prepare high quality artificial soil by solidifying sewage sludge in order to satisfy the moisture content of the sewage sludge and the strength for artificial soil and to improve work environments. CONSTITUTION: A solidifying material for artificial soil containing calcium chloroaluminate mineral includes, based on 100 parts by weight of a solidifying object, 5~10 parts by weight of quicklime, 5~15 parts by weight of calcium chloroaluminate mineral, 5~10 parts by weight of heavy metal absorbents, 0.1~2 parts by weight of citric acids or tartaric acids and 5~10 parts by weight of illite powder. The heavy metal absorbent uses the clean water sludge in which an absorbing membrane is formed on the surface by controlling the Al/Si mole ratio of 1~1.5, wherein the clean water sludge has the particle size of 4,000~6000 cm^2/g and the water content of 3~7%.
摘要翻译：目的：提供人造土固化材料，通过固化污泥来制备高品质人造土，以满足污泥污泥的含水量和人造土强度，改善工作环境。构成：用于含有氯铝酸钙矿物的人造土壤固化材料包括：基于100重量份固化物，5〜10重量份生石灰，5〜15重量份氯铝酸钙矿物，5〜10重量份重金属吸收剂的重量，0.1〜2重量份的柠檬酸或酒石酸和5〜10重量份的伊利石粉末。重金属吸收剂通过控制Al-Si摩尔比为1〜1.5，使用表面形成吸收膜的清洁污泥，其中清洁水泥的粒度为4000〜6000cm ^ 2 / g 含水量3〜7％。

9. 发明公开

KR1020110091172A 중금속 함유 폐기물 처리용 고화재 및 그의 제조방법 无效
标题翻译：用于处理含有重金属的废物的添加剂及其制造方法
公开(公告)号：KR1020110091172A
公开(公告)日：2011-08-11
申请号：KR1020100010881
申请日：2010-02-05
申请人： 한국지질자원연구원
发明人： 유광석 , 안지환 , 이성호 , 황선호 , 한기천
IPC分类号： C09K17/10 , C09K17/08 , C04B18/16 , C04B28/16
CPC分类号： C04B28/06 , Y02W30/91 , C04B7/00 , C04B22/10 , C04B22/142 , C04B22/143 , C04B18/0418 , C09K17/10 , C09K17/06 , C09K17/08 , C09K2103/00
摘要： PURPOSE: A solidifying agent for the disposal of heavy metal-containing waste is provided to ensure a fast ettringite production reaction rate and excellent heavy metal fixation power as well as effective solidification of high moisture-containing sludge. CONSTITUTION: A method for preparing a solidifying agent for the disposal of heavy metal-containing waste comprises: (i) pulverizing alumina mineral so that the brain specific area of the powder is 2,000~5,000 cm^2/g; and (ii) mixing 2~40 parts by weight of alumina mineral, 1~5 parts by weight of insoluble anhydrite powder, 0.5~10 parts by weight of alkali carbonate that is Na2CO3 or K2CO3, and 0.5~10 parts by weight of sulfate that is Al2(SO4)3 based on 100 parts by weight of cement sludge.
摘要翻译：目的：提供一种用于处理含重金属废物的固化剂，以确保钙铝矾石生产反应速度快，重金属固定能力强，以及高含水量污泥的有效凝固。构成：制备用于处理重金属废物的固化剂的方法包括：（i）粉碎氧化铝矿物，使得粉末的脑比面积为2,000〜5,000cm 2 / g; 和（ii）将2〜40重量份的氧化铝矿物，1〜5重量份的不溶硬石膏粉末，0.5〜10重量份的Na 2 CO 3或K 2 CO 3的碱金属碳酸盐和0.5〜10重量份的硫酸盐即基于100重量份水泥污泥的Al2（SO4）3。

10. 发明公开

KR1020110091171A 폐기물을 이용한 칼슘알루미네이트계 클링커 및 그의 제조방법 有权
标题翻译：基于铝酸钙的螯合剂及其制备方法
公开(公告)号：KR1020110091171A
公开(公告)日：2011-08-11
申请号：KR1020100010880
申请日：2010-02-05
申请人： 한국지질자원연구원
发明人： 유광석 , 안지환 , 황선호 , 이성호 , 계상범 , 김형순
IPC分类号： C04B7/26 , C04B7/48 , C04B7/44 , C04B7/38
CPC分类号： C04B7/44 , C04B7/32 , Y02P40/121 , C04B7/425 , C04B7/427
摘要： PURPOSE: Calcium aluminate-based clinker using wastes and a method for manufacturing the same are provided to obtain eco-friendly calcium aluminate-based clinker by mixing asbestos wastes, municipal solid waste incineration ash, water treatment sludge, gypsum, fluorite, and silicon carbide in a pre-set ratio. CONSTITUTION: A method for manufacturing calcium aluminate-based clinker includes the following: 30 to 70 parts by weight of water treatment sludge, 10 to 40 parts by weight of asbestos wastes, 1 to 5 parts by weight of silicon carbide, 5 to 15 parts by weight of gypsum, and 2 to 10 parts by weight of fluorite, based on 100 parts by weight of municipal solid waste incineration ash. The mixture is sintered in a sealed space for 1 to 2 hours at temperature between 1000 and 1300 degrees Celsius. The temperature raising speed of the sintering process is 10 degrees Celsius/min. The gypsum is selected from a group including desulfurization gypsum, phosphogypsum, hydrofluoric acid gypsum, and the mixture of the same. The municipal solid waste incineration ash includes CaO and Cl. The water treatment sludge includes Al_2O_3 and SO_3.
摘要翻译：目的：提供使用废铝的铝酸钙熟料及其制造方法，通过混合石棉废物，城市固体废物焚烧灰，水处理污泥，石膏，萤石和碳化硅来获得环保铝酸钙熟料以预设的比例。构成：一种铝酸钙类熟料的制造方法，其特征在于，含有30〜70重量份水处理污泥，10〜40重量份石棉废料，1〜5重量份碳化硅，5〜15重量份的石膏和2〜10重量份的萤石，基于100重量份的城市固体废物焚烧灰。将混合物在密封空间中在1000至1300摄氏度之间的温度下烧结1至2小时。烧结过程的升温速度为10摄氏度/分钟。石膏选自脱硫石膏，磷石膏，氢氟酸石膏及其混合物。城市固体废物焚烧灰包括CaO和Cl。水处理污泥包括Al_2O_3和SO_3。

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