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1. 发明授权

KR101549731B1 (메타)아크릴계 공중합체, 그 제조방법 및 이를 포함하는 성형품 有权
标题翻译：用于制备它们的甲基丙烯酸共聚物方法和包含其的制品
公开(公告)号：KR101549731B1
公开(公告)日：2015-09-02
申请号：KR1020120157666
申请日：2012-12-28
申请人： 제일모직주식회사
发明人： 장주현 , 권기혜 , 김보은 , 강용희 , 구자관 , 김만석 , 김일진 , 박광수
IPC分类号： C08F220/10 , C08F230/02 , C08L33/04 , C08L43/02
摘要： 본발명의 (메타)아크릴계공중합체는하기화학식 1로표시되는인계 (메타)아크릴계단량체, 및단관능성불포화단량체를포함하는단량체혼합물의공중합체인것을특징으로한다. 상기 (메타)아크릴계공중합체는굴절률이개선되고우수한난연성, 투명성, 내스크래치성및 친환경성을갖는다. [화학식 1]상기화학식 1에서, R은수소원자또는메틸기이고, R는치환또는비치환된탄소수 1 내지 20의탄화수소기이고, R및 R는각각독립적으로치환또는비치환된탄소수 6 내지 20의환형탄화수소기이며, m은 1 내지 10의정수이고, n은 0 내지 5의정수이다.

2. 发明公开

KR1020140086775A 열가소성 수지 조성물 및 이를 포함하는 성형품 无效
标题翻译：热塑性树脂组合物和包含其的制品
公开(公告)号：KR1020140086775A
公开(公告)日：2014-07-08
申请号：KR1020120157679
申请日：2012-12-28
申请人： 제일모직주식회사
发明人： 장주현 , 김보은 , 김일진 , 박광수 , 강용희 , 김만석 , 센틸쿠마르나타라잔 , 이조원
IPC分类号： C08L69/00 , C08L33/04 , C08L51/04 , C08F230/02
摘要： A thermoplastic resin composition of the present invention comprises: a polycarbonate resin (A); and (meta)acrylic copolymers in which a monomer mixture including monofunctional unsaturated monomers and (meta)acrylic monomers are polymerized. The thermoplastic resin composition has excellent flame retardancy, transparency, heat resistance and scratch resistance and is environmentally friendly. In chemical formula 1, R_1 is a hydrogen atom or a methyl group. R_2 is a substituted or nonsubstituted hydrocarbon group of C1-C20. R_3 and R_4 are a substituted or nonsubstituted cyclic hydrocarbon group of C6-C20, respectively. m is an integer of 1-20. And n is an integer of 0-5.
摘要翻译：本发明的热塑性树脂组合物包含：聚碳酸酯树脂（A）; 和（甲基）丙烯酸共聚物，其中包含单官能不饱和单体和（间）丙烯酸单体的单体混合物聚合。热塑性树脂组合物具有优异的阻燃性，透明性，耐热性和耐刮擦性，并且是环境友好的。在化学式1中，R 1是氢原子或甲基。 R 2是C 1 -C 20的取代或未取代的烃基。 R_3和R_4分别是C6-C20的取代或非取代的环状烃基。 m是1-20的整数。 n是0-5的整数。

3. 发明公开

KR1020140086765A (메타)아크릴계 공중합체, 그 제조방법 및 이를 포함하는 성형품 有权
标题翻译：（METH）丙烯酸共聚物，其制备方法和包含它们的物质
公开(公告)号：KR1020140086765A
公开(公告)日：2014-07-08
申请号：KR1020120157666
申请日：2012-12-28
申请人： 제일모직주식회사
发明人： 장주현 , 권기혜 , 김보은 , 강용희 , 구자관 , 김만석 , 김일진 , 박광수
IPC分类号： C08F220/10 , C08F230/02 , C08L33/04 , C08L43/02
摘要： A (meta)acrylic copolymer of the present invention is a copolymer of a monomer mixture comprising a monofunctional unsaturated monomer and a phosphorus based (meta)acrylic monomer represented by chemical formula 1. The (meta)acrylic copolymer improves refractive index and has excellent flame retardant, transparency, scratch resistance and environmental performance. In chemical formula 1, R_1 is a hydrogen atom or a methyl group. R_2 is a substituted or non-substituted hydrocarbon group of C1-C20. R_3 and R_4 are a substituted or non-substituted cyclic hydrocarbon group of C6-C20, respectively. m is an integer of 1-10. And n is an integer of 0-5.
摘要翻译：本发明的（甲基）丙烯酸共聚物是包含单官能不饱和单体和由化学式1表示的磷基（甲基）丙烯酸单体的单体混合物的共聚物。（间）丙烯酸共聚物改善折射率并具有优异的火焰阻燃，透明，耐刮擦和环保性能。在化学式1中，R 1是氢原子或甲基。 R 2是C 1 -C 20的取代或未取代的烃基。 R 3和R 4分别是C 6 -C 20的取代或未取代的环状烃基。 m为1-10的整数。 n是0-5的整数。

4. 发明公开

KR1020140092485A 열가소성 수지 조성물 및 이를 이용한 성형품 无效
标题翻译：热塑性树脂组合物和使用其的成型品
公开(公告)号：KR1020140092485A
公开(公告)日：2014-07-24
申请号：KR1020120157575
申请日：2012-12-28
申请人： 제일모직주식회사
发明人： 권기혜 , 김인철 , 김보은 , 장주현 , 홍창민
IPC分类号： C08L69/00 , C08L51/04 , C08L51/08 , C08L25/08
CPC分类号： C08L69/00 , C08L25/12 , C08L51/04 , C08L83/04
摘要： The present invention relates to a thermoplastic resin composition comprising 30-98 wt% of polycarbonate resin (A), 1-50 wt% of a rubber-modified acrylic graft copolymer (B), and 1-70 wt% of a branched copolymer including a silicone-based compound (C); and a molded product using the thermoplastic resin composition.
摘要翻译：本发明涉及包含30-98重量％的聚碳酸酯树脂（A），1-50重量％的橡胶改性的丙烯酸接枝共聚物（B）和1-70重量％的支链共聚物的热塑性树脂组合物，包括硅氧烷类化合物（C）; 和使用该热塑性树脂组合物的成型体。

5. 发明公开

KR1020140074087A 열가소성 수지 및 이를 포함하는 성형품 无效
标题翻译：热塑性树脂及其制品
公开(公告)号：KR1020140074087A
公开(公告)日：2014-06-17
申请号：KR1020120142297
申请日：2012-12-07
申请人： 제일모직주식회사
发明人： 장주현 , 정진화 , 강용희 , 권기혜 , 김만석 , 김일진 , 박광수 , 구자관 , 김보은
IPC分类号： C08L69/00 , C08L33/04 , C08L51/04 , C08J5/00
摘要： The present invention relates to a thermoplastic resin comprising: a polycarbonate resin; and a resin including a phosphorous heterocyclic group. An embodiment of the present invention comprises: (A) a polycarbonate resin; and (B) a (meth)acrylic copolymer including a phosphorous heterocyclic group. The (meth)acrylic copolymer (B) comprises: (b1) a phosphorous (meth)acrylic monomer including a phosphorous heterocyclic group; (b2) a (meth)acrylic monomer containing a biphenyl group having a refractive index of 1.580 to 1.700; and (b3) a unit derived from a monomer including an unsaturated monomer. The thermoplastic resin has excellent flame retardancy and transparency and has heat resistance, scratch resistance, and eco-friendliness.
摘要翻译：本发明涉及热塑性树脂，其包含：聚碳酸酯树脂; 以及包含磷杂环基的树脂。本发明的实施方案包括：（A）聚碳酸酯树脂; 和（B）包含磷杂环基的（甲基）丙烯酸共聚物。（甲基）丙烯酸共聚物（B）包括：（b1）包含磷杂环基的磷（甲基）丙烯酸单体; （b2）含有折射率为1.580〜1.700的联苯基的（甲基）丙烯酸系单体; 和（b3）衍生自包含不饱和单体的单体的单元。热塑性树脂具有优异的阻燃性和透明性，并且具有耐热性，耐刮擦性和环保性。

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