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    • 2. 发明专利
    • Fuel cell system
    • 燃油电池系统
    • JP2014149971A
    • 2014-08-21
    • JP2013018047
    • 2013-02-01
    • Toyota Motor Corpトヨタ自動車株式会社
    • IIO ATSUOSEKIZAWA YOSHIFUMI
    • H01M8/04H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a technique capable of improving the utilization efficiency of a fuel gas in a fuel cell system.SOLUTION: A fuel cell system 100 comprises: a fuel cell 10; a cathode gas supply unit 30; a cathode gas exhaust unit 40; an anode gas supply unit 50; an anode gas circulation unit 60; and a leak gas transmission unit 70. A cathode exhaust gas piping 41 of the cathode gas exhaust unit 40 is provided with a hydrogen separation unit 42 which separates hydrogen which is a leak gas included in a cathode exhaust gas. The hydrogen separated by the hydrogen separation unit 42 is transmitted to the leak gas transmission unit 70 which in turn temporarily stores the hydrogen in a leak gas recovery unit. A control unit 20 circulates the hydrogen of the leak gas transmission unit 70 to an anode 3 of the fuel cell 10 at a prescribed timing via the anode gas circulation unit 60.
    • 要解决的问题:提供能够提高燃料电池系统中的燃料气体的利用效率的技术。解决方案:燃料电池系统100包括:燃料电池10; 阴极气体供给单元30; 阴极气体排出单元40; 阳极气体供给单元50; 阳极气体循环单元60; 和泄漏气体传输单元70.阴极排气单元40的阴极排气管道41设置有氢分离单元42,其分离作为阴极废气中包括的泄漏气体的氢。 由氢分离单元42分离的氢气被传输到泄漏气体传输单元70,泄漏气体传输单元70临时将氢气存储在泄漏气体回收单元中。 控制单元20经由阳极气体循环单元60以预定的时刻将泄漏气体传输单元70的氢气循环到燃料电池10的阳极3。
    • 3. 发明专利
    • Coverage calculation method of catalyst fine particle and catalyst fine particle evaluation method
    • 催化剂微粒和催化剂微粒评估方法的覆盖计算方法
    • JP2013164405A
    • 2013-08-22
    • JP2012028874
    • 2012-02-13
    • Toyota Motor Corpトヨタ自動車株式会社
    • IIO ATSUOTANIGUCHI TAKUMITAKEHIRO NAOKI
    • G01N27/48H01M4/86H01M4/88H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a method for more accurately calculating coverage of an outermost layer of catalyst fine particles for center particles than before, and a catalyst fine particle evaluation method applying the calculation method.SOLUTION: There is provided a method for calculating the coverage of the outermost layer covering the center particles for the center particles in the catalyst fine particles comprising the center particles and the outermost layer. The coverage calculation method includes the steps of: preparing the catalyst fine particles; performing oxygen-reducing reaction measurement for the catalyst fine particle under two or more sweep rate conditions different from one another, and selecting two of the sweep rate conditions to calculate the maintenance rate of current value for a certain potential in the sweeping range under the selected sweep rate conditions; and calculating the coverage from the maintenance rate of current value.
    • 要解决的问题:提供一种更精确地计算中心粒子的催化剂微粒的最外层的覆盖率的方法,以及应用计算方法的催化剂微粒评价方法。提供一种计算方法 覆盖包含中心颗粒和最外层的催化剂细颗粒中的中心颗粒的中心颗粒的最外层的覆盖。 覆盖率计算方法包括以下步骤:制备催化剂细颗粒; 在两个或更多个不同的扫描速率条件下对催化剂细颗粒进行氧还原反应测量,并且选择两个扫描速率条件以计算所选择的扫描范围内某一电位的电流值的维持率 扫频率条件; 并根据当前价值的维护率计算覆盖范围。
    • 4. 发明专利
    • Coverage calculation method of catalyst fine particle and catalyst fine particle evaluation method
    • 催化剂微粒和催化剂微粒评估方法的覆盖计算方法
    • JP2013164404A
    • 2013-08-22
    • JP2012028849
    • 2012-02-13
    • Toyota Motor Corpトヨタ自動車株式会社
    • IIO ATSUOTANIGUCHI TAKUMITAKEHIRO NAOKI
    • G01N27/48B01J23/89G01N27/42H01M4/86H01M4/88H01M8/04H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a method for more accurately calculating coverage of an outermost layer of catalyst fine particles for center particles than before, and a catalyst fine particle evaluation method applying the calculation method.SOLUTION: There is provided a method for calculating the coverage of the outermost layer for the center particles in the catalyst fine particles comprising the center particles and the outermost layer covering the center particles. The coverage calculation method includes the steps of: preparing the catalyst fine particles; calculating an electrochemical surface area of the catalyst fine particle; performing oxygen-reducing reaction measurement for the catalyst fine particle and calculating an amount of hydrogen peroxide generated through the measurement; and calculating the coverage from the electrochemical surface area value and the generation amount value of hydrogen peroxide.
    • 要解决的问题:提供一种更精确地计算中心粒子的催化剂微粒的最外层的覆盖率的方法,以及应用计算方法的催化剂微粒评价方法。提供了一种计算方法 在包含中心颗粒和覆盖中心颗粒的最外层的催化剂细颗粒中的中心颗粒的最外层的覆盖。 覆盖率计算方法包括以下步骤:制备催化剂细颗粒; 计算催化剂微粒的电化学表面积; 对催化剂微粒进行氧还原反应测定,计算通过测定生成的过氧化氢量; 并根据电化学表面积值和过氧化氢的产生量计算覆盖率。
    • 5. 发明专利
    • Fuel cell system
    • 燃油电池系统
    • JP2014093206A
    • 2014-05-19
    • JP2012243398
    • 2012-11-05
    • Toyota Motor Corpトヨタ自動車株式会社
    • IIO ATSUOADACHI MAKOTO
    • H01M8/04H01M4/92H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a fuel cell system that can keep the performance of a fuel cell for long term.SOLUTION: A fuel cell system comprises: a cell unit 20 having an oxidant electrode containing core shell catalyst particles, the cell unit 20 having a core containing at least one material selected from palladium and palladium alloy and a shell which is formed of shell metal containing at least one material selected from platinum and platinum alloy and covers the core; coverage quantitating means 180 for quantitating the coverage of the core shell catalyst particles; first reproducing means 120 for controlling the potential of the oxidant electrode to enhance the coverage of the core shell catalyst particles; determining means 190 for determining whether the coverage of the core shell catalyst particles measured by the coverage quantitating means is within a predetermined first numerical range; and reproduction processing control means 200 for making the first reproducing means execute when it is determined in the determining means that the coverage is within the first numerical range.
    • 要解决的问题:提供能够长期保持燃料电池性能的燃料电池系统。解决方案:一种燃料电池系统,包括:电池单元20,具有含有核壳催化剂颗粒的氧化剂电极,电池单元20 具有含有选自钯和钯合金中的至少一种材料的芯和由包含选自铂和铂合金中的至少一种材料的壳金属形成并覆盖芯的壳; 用于定量核壳催化剂颗粒的覆盖的覆盖定量装置180; 第一再现装置120,用于控制氧化剂电极的电位以增强核壳催化剂颗粒的覆盖; 确定装置190,用于确定由覆盖定量装置测量的核壳催化剂颗粒的覆盖范围是否在预定的第一数值范围内; 以及当在确定装置中确定覆盖率在第一数值范围内时,使第一再现装置执行的再现处理控制装置200。
    • 10. 发明专利
    • Method for producing catalytic composite
    • 生产催化复合材料的方法
    • JP2012157832A
    • 2012-08-23
    • JP2011020128
    • 2011-02-01
    • Toyota Motor Corpトヨタ自動車株式会社
    • IIO ATSUOARAI TATSUYATAKEHIRO NAOKI
    • B01J23/44B01J37/04H01M4/86H01M4/88H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a method for producing a catalytic composite, with which the surface of a catalytic fine particle is not chipped and a dispersed state of the catalytic fine particle is improved.SOLUTION: The method for producing the catalytic composite which contains the catalytic fine particle including a center particle and an outermost layer covering the center particle, and an electrolyte, includes: a step of preparing the catalytic fine particle and the electrolyte; and a step of dispersing and mixing the catalytic fine particle and the electrolyte, at the least, by a ball mill using a ball made of a material having hardness lower than that of the material contained in the outermost layer.
    • 待解决的问题:提供一种催化复合材料的制造方法,催化剂微粒的表面不会碎裂,催化剂微粒的分散状态得到改善。 解决方案:含有包含中心粒子和覆盖中心粒子的最外层的催化剂微粒和电解质的催化剂复合体的制造方法包括:制备催化剂微粒和电解质的工序; 以及通过使用由比最外层所含的材料的硬度低的材料制成的球的球磨机分散和混合催化剂微粒和电解质的步骤。 版权所有(C)2012,JPO&INPIT