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    • 1. 发明申请
    • SLURRY BED LOOP REACTOR AND USE THEREOF
    • 浆液循环反应器及其用途
    • US20090197979A1
    • 2009-08-06
    • US12303061
    • 2007-05-31
    • Zhanzhu ZhangLifeng HuXiaojin TangShaobing WangShuandi HouJunyi MaoHongliang Qu
    • Zhanzhu ZhangLifeng HuXiaojin TangShaobing WangShuandi HouJunyi MaoHongliang Qu
    • C07C27/06B01J8/20
    • B01J8/228B01J8/006B01J8/226B01J2208/0084
    • The present invention relates to a slurry bed loop reactor comprising a riser and at least one downcomer (3), wherein two ends of the riser are connected to two ends of the downcomer (3) via lines (16) and (7), respectively. The riser comprises a reaction section (1) and a settling section (2) with an increased tube diameter disposed on the reaction section (1). A gas outlet (13) exists at the top of the settling section (2). Each of the downcomers (3) is divided into a filtrate section (5) and a slurry section (6) by filter medium (4), wherein the filtrate section (5) is connected to a liquid outlet (10); two ends of the slurry section (6) are respectively connected to two ends of the riser, and the filtrate region (5) may further be connected to a back purging system. When used in a gas-liquid-solid three phases reaction system, the reactor can realize successive separation of gas, liquid and solid particles in slurry, and realize the back purging regeneration of filter tubes without influencing the reaction processes. In addition, said reactor has the advantages of high separation efficiency, simple structure, flexible and easy operation
    • 本发明涉及一种包括提升管和至少一个降液管(3)的淤浆床回路反应器,其中提升管的两端分别经由管线(16)和(7)连接到降液管(3)的两端 。 提升管包括反应部分(1)和设置在反应部分(1)上的具有增加的管直径的沉降部分(2)。 气体出口(13)存在于沉降段(2)的顶部。 每个下降管(3)通过过滤介质(4)分成滤液部分(5)和浆料部分(6),其中滤液部分(5)连接到液体出口(10); 浆料部分(6)的两端分别连接到提升管的两端,并且滤液区域(5)还可以连接到背部清洗系统。 当用于气 - 液 - 固三相反应体系时,反应器可以实现浆液中气体,液体和固体颗粒的连续分离,实现过滤管的后吹扫再生,而不影响反应过程。 此外,所述反应器具有分离效率高,结构简单,操作灵活方便的优点
    • 2. 发明授权
    • Slurry bed loop reactor and use thereof
    • 泥浆床回路反应器及其用途
    • US07919536B2
    • 2011-04-05
    • US12303061
    • 2007-05-31
    • Zhanzhu ZhangLifeng HuXiaojin TangShaobing WangShuandi HouJunyi MaoHongliang Qu
    • Zhanzhu ZhangLifeng HuXiaojin TangShaobing WangShuandi HouJunyi MaoHongliang Qu
    • C07C27/00
    • B01J8/228B01J8/006B01J8/226B01J2208/0084
    • The present invention relates to a slurry bed loop reactor comprising a riser and at least one downcomer (3), wherein two ends of the riser are connected to two ends of the downcomer (3) via lines (16) and (7), respectively. The riser comprises a reaction section (1) and a settling section (2) with an increased tube diameter disposed on the reaction section (1). A gas outlet (13) exists at the top of the settling section (2). Each of the downcomers (3) is divided into a filtrate section (5) and a slurry section (6) by filter medium (4), wherein the filtrate section (5) is connected to a liquid outlet (10); two ends of the slurry section (6) are respectively connected to two ends of the riser, and the filtrate region (5) may further be connected to a back purging system. When used in a gas-liquid-solid three phases reaction system, the reactor can realize successive separation of gas, liquid and solid particles in slurry, and realize the back purging regeneration of filter tubes without influencing the reaction processes. In addition, said reactor has the advantages of high separation efficiency, simple structure, flexible and easy operation.
    • 本发明涉及一种包括提升管和至少一个降液管(3)的淤浆床回路反应器,其中提升管的两端分别经由管线(16)和(7)连接到降液管(3)的两端 。 提升管包括反应部分(1)和设置在反应部分(1)上的具有增加的管直径的沉降部分(2)。 气体出口(13)存在于沉降段(2)的顶部。 每个下降管(3)通过过滤介质(4)分成滤液部分(5)和浆料部分(6),其中滤液部分(5)连接到液体出口(10); 浆料部分(6)的两端分别连接到提升管的两端,并且滤液区域(5)还可以连接到背部清洗系统。 当用于气 - 液 - 固三相反应体系时,反应器可以实现浆液中气体,液体和固体颗粒的连续分离,实现过滤管的后吹扫再生,而不影响反应过程。 此外,所述反应器具有分离效率高,结构简单,操作灵活方便的优点。
    • 3. 发明授权
    • Catalytic conversion method of increasing the yield of lower olefin
    • 提高低级烯烃产率的催化转化方法
    • US08608944B2
    • 2013-12-17
    • US12158145
    • 2006-12-19
    • Zheng LiJun LongShuandl HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • Zheng LiJun LongShuandl HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • C10G47/32C10G11/04C10G49/08
    • C10G11/18C07C4/06C10G11/05Y02P20/52Y02P20/584C07C11/06C07C11/04
    • A catalytic conversion process for increasing the light olefin yields, which comprises bringing a hydrocarbon oil feedstock into contact with a catalytic conversion catalyst in a catalytic conversion reactor including one or more reaction zones to carry out the reaction, wherein the hydrocarbon oil feedstock is subjected to the catalytic conversion reaction in the presence of an inhibitor; and separating the reactant vapor optionally containing the inhibitor from the coke deposited catalyst, wherein a target product containing ethylene and propylene is obtained by separating the reactant vapor, and the coke deposited catalyst is stripped and regenerated for recycle use by being returned to the reactor. The process can weaken the further converting reaction of produced light olefins such as ethylene and propylene to 50-70% of the original level by injecting the inhibitor; thereby it can increase the yields of the target products. When vacuum gas oil is used as the feedstock, the yield of ethylene is as high as 8.73 wt % and that of propylene is as high as 29.30 wt %, increasing by 14.4% and 26.6% respectively comparing to those obtained without the inhibitor being injected.
    • 一种用于增加轻质烯烃产率的催化转化方法,其包括在包含一个或多个反应区的催化转化反应器中使烃油原料与催化转化催化剂接触以进行反应,其中烃油原料经受 在抑制剂存在下的催化转化反应; 以及将任选地含有抑制剂的反应物蒸气与焦炭沉积催化剂分离,其中通过分离反应物蒸气获得含有乙烯和丙烯的目标产物,并将焦炭沉积的催化剂通过返回到反应器中被汽提并再生再循环使用。 该方法可以通过注射抑制剂来削弱生产的轻质烯烃如乙烯和丙烯的进一步转化反应,达到原始水平的50-70%; 从而可以提高目标产品的产量。 当使用减压瓦斯油作为原料时,乙烯的产率高达8.73重量%,丙烯的产率高达29.30重量%,分别比不注入抑制剂的那些获得的增加了14.4%和26.6% 。
    • 4. 发明申请
    • CATALYTIC CONVERSION APPARATUS
    • 催化转换装置
    • US20090117017A1
    • 2009-05-07
    • US12295523
    • 2007-03-30
    • Jun LongKejia XuShuandi HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • Jun LongKejia XuShuandi HouZhijian DaChaogang XieJiushun ZhangZhanzhu Zhang
    • B01J8/04
    • C10G11/18B01J8/0055B01J8/0065B01J8/1827B01J8/26B01J2219/00038C10G2300/4093C10G2400/20Y02P30/40Y02P30/446
    • The present invention relates to a catalytic conversion apparatus, characterized in that said apparatus comprises at least one feed oil cracking riser reactor, a dense bed reactor, a disengager, and a stripper, wherein said stripper locates below said dense bed reactor and communicates directly with the lower part of the dense bed reactor or through a fluid-communicating channel, the outlet of at least one of said riser reactor(s) communicates with the lower part of said dense bed reactor or any part of said fluid-communicating channel, the outlet of said dense bed reactor communicates with the inlet of a gas-solid separating apparatus located in said disengager through said disengager and/or through an optional transporting channel, the catalyst outlet of said disengager communicates with at least one position selected from the upper part of said stripper, any part of said fluid-communicating channel, and the lower part of said dense bed reactor, through at least one catalyst transporting channel. The catalytic conversion apparatus according to the present invention sets up at least one riser reactor and a dense bed reactor to carry out further cracking of the intermediate products, produced from the feed oil by the cracking reaction in the riser, in the dense bed reactor. Moreover, the spent catalysts discharged from the outlet of the dense bed reactor can be introduced into the stripper via a specific catalyst transporting channel, so as to maintain higher activity and temperature of the catalyst in the dense bed reactor and be advantageous to deeper cracking of the intermediate products in the dense bed reactor so as to produce more light olefins, particularly propylene.
    • 催化转化装置技术领域本发明涉及一种催化转化装置,其特征在于,所述装置包括至少一个进料油裂解提升反应器,致密床反应器,分离器和汽提塔,其中所述汽提器位于所述致密床反应器下方并直接与 所述致密床反应器的下部或通过流体连通通道,所述提升管反应器中的至少一个的出口与所述致密床反应器的下部或所述流体连通通道的任何部分连通, 所述致密床反应器的出口通过所述分离器和/或通过可选的输送通道与位于所述分离器中的气固分离装置的入口连通,所述分离器的催化剂出口与选自上部的至少一个位置 的所述汽提器,所述流体连通通道的任何部分和所述致密床反应器的下部,通过至少一个催化剂运输 丁通道。 根据本发明的催化转化装置设置至少一个提升管反应器和致密床反应器,以进一步裂化由致密床反应器中的提升管中的裂化反应由进料油产生的中间产物。 此外,从致密床反应器出口排出的废催化剂可以通过特定的催化剂输送通道引入汽提塔,以保持催化剂在致密床反应器中的较高的活性和温度,并且有利于较深的开裂 在密床反应器中的中间产物,以产生更多的轻质烯烃,特别是丙烯。
    • 9. 发明授权
    • Slurry bed loop reactor and use thereof
    • 浆床回路反应器及其用途
    • US08263007B2
    • 2012-09-11
    • US13038650
    • 2011-03-02
    • Zhanzhu ZhangLifeng HuXiaojin TangShaobing WangShuandi HouJunyi MaoHongliang Qu
    • Zhanzhu ZhangLifeng HuXiaojin TangShaobing WangShuandi HouJunyi MaoHongliang Qu
    • B01J8/20
    • B01J8/228B01J8/006B01J8/226B01J2208/0084
    • The present invention relates to a slurry bed loop reactor comprising a riser and at least one downcomer (3), wherein two ends of the riser are connected to two ends of the downcomer (3) via lines (16) and (7), respectively. The riser comprises a reaction section (1) and a settling section (2) with an increased tube diameter disposed on the reaction section (1). A gas outlet (13) exists at the top of the settling section (2). Each of the downcomers (3) is divided into a filtrate section (5) and a slurry section (6) by filter medium (4), wherein the filtrate section (5) is connected to a liquid outlet (10); two ends of the slurry section (6) are respectively connected to two ends of the riser, and the filtrate region (5) may further be connected to a back purging system. When used in a gas-liquid-solid three phases reaction system, the reactor can realize successive separation of gas, liquid and solid particles in slurry, and realize the back purging regeneration of filter tubes without influencing the reaction processes. In addition, said reactor has the advantages of high separation efficiency, simple structure, flexible and easy operation.
    • 本发明涉及一种包括提升管和至少一个降液管(3)的淤浆床回路反应器,其中提升管的两端分别经由管线(16)和(7)连接到降液管(3)的两端 。 提升管包括反应部分(1)和设置在反应部分(1)上的具有增加的管直径的沉降部分(2)。 气体出口(13)存在于沉降段(2)的顶部。 每个下降管(3)通过过滤介质(4)分成滤液部分(5)和浆料部分(6),其中滤液部分(5)连接到液体出口(10); 浆料部分(6)的两端分别连接到提升管的两端,并且滤液区域(5)还可以连接到背部清洗系统。 当用于气 - 液 - 固三相反应体系时,反应器可以实现浆液中气体,液体和固体颗粒的连续分离,实现过滤管的后吹扫再生,而不影响反应过程。 此外,所述反应器具有分离效率高,结构简单,操作灵活方便的优点。
    • 10. 发明申请
    • SLURRY BED LOOP REACTOR AND USE THEREOF
    • 浆液循环反应器及其用途
    • US20110165029A1
    • 2011-07-07
    • US13038650
    • 2011-03-02
    • Zhanzhu ZHANGLifeng HUXiaojin TANGShaobing WANGShuandi HOUJunyi MAOHongliang QU
    • Zhanzhu ZHANGLifeng HUXiaojin TANGShaobing WANGShuandi HOUJunyi MAOHongliang QU
    • B01J8/18
    • B01J8/228B01J8/006B01J8/226B01J2208/0084
    • The present invention relates to a slurry bed loop reactor comprising a riser and at least one downcomer (3), wherein two ends of the riser are connected to two ends of the downcomer (3) via lines (16) and (7), respectively. The riser comprises a reaction section (1) and a settling section (2) with an increased tube diameter disposed on the reaction section (1). A gas outlet (13) exists at the top of the settling section (2). Each of the downcomers (3) is divided into a filtrate section (5) and a slurry section (6) by filter medium (4), wherein the filtrate section (5) is connected to a liquid outlet (10); two ends of the slurry section (6) are respectively connected to two ends of the riser, and the filtrate region (5) may further be connected to a back purging system. When used in a gas-liquid-solid three phases reaction system, the reactor can realize successive separation of gas, liquid and solid particles in slurry, and realize the back purging regeneration of filter tubes without influencing the reaction processes. In addition, said reactor has the advantages of high separation efficiency, simple structure, flexible and easy operation
    • 本发明涉及一种包括提升管和至少一个降液管(3)的淤浆床回路反应器,其中提升管的两端分别经由管线(16)和(7)连接到降液管(3)的两端 。 提升管包括反应部分(1)和设置在反应部分(1)上的具有增加的管直径的沉降部分(2)。 气体出口(13)存在于沉降段(2)的顶部。 每个下降管(3)通过过滤介质(4)分成滤液部分(5)和浆料部分(6),其中滤液部分(5)连接到液体出口(10); 浆料部分(6)的两端分别连接到提升管的两端,并且滤液区域(5)还可以连接到背部清洗系统。 当用于气 - 液 - 固三相反应体系时,反应器可以实现浆液中气体,液体和固体颗粒的连续分离,实现过滤管的后吹扫再生,而不影响反应过程。 此外,所述反应器具有分离效率高,结构简单,操作灵活方便的优点