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    • 1. 发明授权
    • Lithium ion secondary battery
    • 锂离子二次电池
    • US08900757B2
    • 2014-12-02
    • US13397790
    • 2012-02-16
    • Ikuo OzakiYoshimasa KoishikawaYoshihisa OkudaYuki Takei
    • Ikuo OzakiYoshimasa KoishikawaYoshihisa OkudaYuki Takei
    • H01M4/24H01M4/505H01M4/525H01M10/052H01M4/02H01M4/62
    • H01M10/052H01M4/02H01M4/505H01M4/525H01M4/621H01M2004/021Y02E60/122
    • A positive electrode capable of achieving both of high volumetric energy density and high volumetric power density and a lithium ion secondary battery using the same are provided. A lithium ion secondary battery includes a positive electrode including a current collector with a positive active material mixture layer applied on both faces thereof, the positive active material mixture layer including active material particles, conductive additive particles and a binder. The active material particles used have a value D of an average particle diameter D50 of the active material particles in the range from 1 to 10 μm. The ratio b/a of the volume fraction b of the vacancy volume in the positive active material mixture layer to the volume fraction a of the active material particles in the positive active material mixture layer is in the range of −0.01D+0.57≦b/a≦−0.01D+0.97.
    • 提供能够实现高体积能量密度和高体积功率密度的正极和使用其的锂离子二次电池。 锂离子二次电池包括具有集电体的正极,所述集电体具有施加在其两个面上的正极活性物质混合层,所述正极活性物质混合物层包含活性物质粒子,导电性添加剂粒子和粘合剂。 使用的活性物质粒子的活性物质粒子的平均粒径D50的值D为1〜10μm。 正极活性物质混合层中的活性物质粒子的体积分数b与正极活性物质混合层中的活性物质粒子的体积分数a的体积分数b的比b / a为-0.01D + 0.57< b / a≦̸ -0.01D + 0.97。