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    • 2. 发明授权
    • Method of and apparatus for processing metal material
    • 金属材料加工方法及设备
    • US5545264A
    • 1996-08-13
    • US383484
    • 1995-02-02
    • Yotaro Hashimoto
    • Yotaro Hashimoto
    • B22F1/00C01G49/06C01G49/08C23C8/18H01F41/16
    • C23C8/18B22F1/0088C01G49/06C01G49/08H01F41/16C01P2002/72
    • The invention relates to a method and apparatus for processing a metal material. In the present invention, a chlorine hydrocarbon solution, water and surfactant solution are mixed together. As an alternative to chlorine hydrocarbon solution, methylene chloride solution may be used. The mixture solution is heated to generate chlorine hydrocarbon gas, water vapor or steam and surfactant gas. The gas mixture fills a hermetically sealed processing tank and permeates a metal material, particularly, a steel material or iron powder disposed in the processing tank. Thus, impurities in open areas of crystal cells of the metal material are dissolved and removed. Then an indissoluble film composed of anticorrosive rust is formed on the surface of the metal material. Where the metal material is steel or iron powder, the anticorrosive rust primarily comprises triiron tetroxide (Fe.sub.3 O.sub.4). To produce magnetic material by the process of the present invention, iron material such as iron powder is converted into triiron tetroxide (Fe.sub.3 O.sub.4), namely magnetite, or diiron trioxide (.gamma.-Fe.sub.2 O.sub.3), namely maghemite.
    • 本发明涉及一种处理金属材料的方法和装置。 在本发明中,将氯烃溶液,水和表面活性剂溶液混合在一起。 作为氯烃溶液的替代物,可以使用二氯甲烷溶液。 将混合溶液加热以产生氯烃气体,水蒸汽或蒸汽和表面活性剂气体。 气体混合物填充密封的处理槽并渗透金属材料,特别是设置在处理槽中的钢材或铁粉。 因此,金属材料的晶胞的开放区域中的杂质被溶解并除去。 然后在金属材料的表面上形成由防腐蚀锈构成的不溶解膜。 当金属材料为钢铁或铁粉时,防腐蚀锈主要包括四氧化三铁(Fe3O4)。 为了通过本发明的方法制造磁性材料,将诸如铁粉的铁材料转化为四氧化三铁(Fe 3 O 4),即磁铁矿或三氧化二铁(γ-Fe 2 O 3)即磁赤铁矿。
    • 3. 发明授权
    • Method for the disposal of a material
    • 材料处理方法
    • US6017492A
    • 2000-01-25
    • US875705
    • 1997-08-01
    • Yotaro Hashimoto
    • Yotaro Hashimoto
    • A62D3/00A62D3/34A62D3/38A62D101/20A62D101/22B09B3/00A61L2/08A01N9/00
    • A62D3/38B09B3/00A62D2101/20A62D2101/22A62D2203/10
    • A mixture of a methylene chloride solution as a halogen-containing solvent with water is put in a treatment tank to generate vapors. The generated methylene chloride vapor, water vapor, and occasionally surfactant vapor penetrate into a waste synthetic resin film (W). When the interior of the treatment tank (T) is evacuated, chloride ions (Cl-)and methylene free radicals (--CH.sub.2 --) generated from the vapors exhibit an oxidative effect for a longer time more strongly than usual. This breaks a long-chain hydrocarbon molecule constituting the synthetic resin or the like to carbohydrates, alcohols, and water, so that the waste is dissolved or decomposed. Further, harmful components of PCB and fat or oil components of animals, fish and the like are decomposed.
    • PCT No.PCT / JP96 / 00214 Sec。 371日期:1997年8月1日 102(e)日期1997年8月1日PCT提交1996年1月31日PCT公布。 公开号WO96 / 23607 日期1996年8月8日将作为含卤素的溶剂的二氯甲烷溶液与水的混合物放入处理槽中以产生蒸汽。 所产生的二氯甲烷蒸汽,水蒸汽和偶尔的表面活性剂蒸气渗透到废合成树脂膜(W)中。 当处理槽(T)的内部被排空时,从蒸气产生的氯离子(Cl-)和亚甲基自由基(-CH 2 - )比平常地表现出更长时间的氧化作用。 这将构成合成树脂等的长链烃分子分解成碳水化合物,醇和水,从而使废物溶解或分解。 此外,PCB的有害成分和动物,鱼等的脂肪或油成分被分解。
    • 4. 发明授权
    • Wood treating method
    • 木材处理方法
    • US5485685A
    • 1996-01-23
    • US328383
    • 1994-10-24
    • Yotaro Hashimoto
    • Yotaro Hashimoto
    • B27K5/00B27K5/02F26B3/00
    • B27K3/34B27K3/0271B27K5/02
    • There are available as chlorine base organic solvents for cleaning by vapor-defatting methylene chloride (CH.sub.2 Cl.sub.2), trichloro ethylene (CHCl.dbd.CCl.sub.2), perchloroethylene (CCl.sub.2 .dbd.CCl.sub.2), 1,1,1-trichloroethane (CH.sub.3 CCl.sub.3) and flon 113 (CCl.sub.2 FCClF.sub.2), etc., of which mainly used is a methylene chloride (CH.sub.2 Cl.sub.2) solvent. By vaporizing said methylene chloride solvent and permeating its vapor into the wood to be treated 10, to melt the tough lignin in the cell structure, thereby perforating the cell membranes, and undermine the valve action of portholes of the false vessels or vessels, fleeing of the cell water confined inside the cells and lumens is facilitated through said perforations and the porthole valves. By perforating the cells and undermining the valve action of the portholes, the fleeing of the free water confined therein, when drying the treated wood by hot air or sun's heat, is facilitated, for the benefit of very rapid drying. Besides, easy penetration of fine dye grains into the wood through said perforations and portholes enables its coloration to deep layers of wood.
    • 可通过蒸发除去二氯甲烷(CH 2 Cl 2),三氯乙烯(CHCl = CCl 2),全氯乙烯(CCl 2 = CCl 2),1,1,1-三氯乙烷(CH 3 CCl 3)和氟里昂113(CCl 2 CFClF 2)来清洗氯碱有机溶剂 )等,其中主要使用二氯甲烷(CH 2 Cl 2)溶剂。 通过蒸发所述二氯甲烷溶剂并将其蒸汽渗透到待处理的木材10中,以熔化细胞结构中的韧性木质素,从而穿孔细胞膜,并破坏假血管或血管的舷窗的瓣膜作用,逃离 限制在细胞内的细胞水和通过所述穿孔和孔眼阀促进流明。 通过穿孔细胞并破坏舷窗的阀门作用,限制在其中的自由水的逃离,当通过热空气或太阳的热量干燥经处理的木材时,有利于非常快速的干燥。 此外,通过所述穿孔和舷窗容易地将细染料颗粒渗透到木材中,使得其可以深层地涂覆木材。