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1. 发明授权

US4212712A Process for the electrolytic treatment of alkali metal halide solution using ion exchange membranes 失效
标题翻译：使用离子交换膜电解处理碱金属卤化物溶液的方法
公开(公告)号：US4212712A
公开(公告)日：1980-07-15
申请号：US905468
申请日：1978-05-12
申请人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
发明人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
IPC分类号： C08J5/22 , C25B1/46 , C25B1/16 , C25B1/26
CPC分类号： C25B1/46 , C08J5/2237 , C08J2327/18
摘要： This invention relates to an apparatus for the electrolytic treatment of alkali halide solution in a three chamber type electrolytic bath assembly comprising an anodic chamber, an intermediate chamber and a cathodic chamber arranged one after another in series. Each chamber is from its neighboring chamber by means of a cationic permselective membrane. The apparatus is characterized, according to this invention, in that the first one of the membranes separating the intermediate and anodic chambers is made of a fluorine-containing resin, while the second membrane separating the intermediate and cathodic chambers includes, as its main ion exchange radial, a pendant type phenolic radical or derivative thereof. The inventive process, which utilizes the above-described apparatus is characterized in that it utilizes a caustic alkali concentration in the intermediate chamber which ranges from about 10-20 wt.% while the output caustic alkali developed at and delivered from the cathodic chamber amounts to a concentration ranging from about 30 to 50 wt.%.
摘要翻译：本发明涉及一种用于在三室型电解槽组件中电解处理碱金属卤化物溶液的装置，其包括依次排列的阳极室，中间室和阴极室。每个室通过阳离子选择性渗透膜从其相邻的室中。该装置的特征在于，根据本发明，分离中间和阳极室的第一个膜由含氟树脂制成，而分离中间和阴极室的第二膜包括作为其主要离子交换桡骨，侧基型酚基或其衍生物。利用上述装置的本发明的方法的特征在于，其在中间室中的碱性碱浓度范围为约10-20重量％，而在阴极室处产生并输出的输出苛性碱达到浓度范围为约30至50重量％。

2. 发明授权

US4111780A Apparatus and process for the electrolytic treatment of alkali metal halide solution with ion exchange membranes 失效
标题翻译：用离子交换膜对碱金属卤化物溶液进行电解处理的装置和方法
公开(公告)号：US4111780A
公开(公告)日：1978-09-05
申请号：US743294
申请日：1976-11-18
申请人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
发明人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
IPC分类号： C08J5/22 , C25B1/46 , C25B9/00 , C25B9/08 , C25B9/10 , C25B13/08 , C25B1/16 , C25B1/26
CPC分类号： C25B1/46 , C08J5/22 , C08J5/2237 , C08J2327/12
摘要： This invention relates to an apparatus for the electrolytic treatment of alkali halide solution in a three chamber type electrolytic bath assembly comprising an anodic chamber, an intermediate chamber and a cathodic chamber arranged one after another in series. Each chamber is separated from its neighboring chamber by means of an anodic ion exchange membrane. The apparatus is characterized, according to this invention, in that the first one of the membranes separating the intermediate and anodic chambers is made of a fluorine-containing resin, while the second membrane separating the intermediate and cathodic chambers includes, as its main ion exchange radical, a pendant type phenolic radical or derivative thereof. The inventive process, which utilizes the above-described apparatus characterized in that it utilizes a caustic alkali concentration in the intermediate chamber which ranges from about 10 - 20 wt. % while the output caustic alkali developed at and delivered from the cathodic chamber amounts to a concentration ranging from about 30 to 50 wt. %.

3. 发明授权

US4455206A Shaped article of collagen and process for preparing same 失效
标题翻译：胶原的成型制品及其制备方法
公开(公告)号：US4455206A
公开(公告)日：1984-06-19
申请号：US332711
申请日：1981-12-21
申请人： Masayuki Funabashi , Yoshikazu Kokubu
发明人： Masayuki Funabashi , Yoshikazu Kokubu
IPC分类号： A22C13/00 , C08H1/00 , C25D1/18 , C25D13/06 , C25D13/12
CPC分类号： A22C13/00 , C25D1/18 , A22C2013/002
摘要： A shaped article of collagen having 5 to 20 .mu.m of thickness, the peak maximum temperature of endothermic denaturation thereof being in the range of 62.degree. to 71.degree. C., the wet tensile strength thereof being in the range of 3 to 6 kg/mm.sup.2 and the wet tear strength thereof being in the range of 25 to 150 g.multidot.cm/cm is prepared by a process comprising cross-linking a collagenous material so that the difference of the peak maximum temperatures of endothermic denaturation of the material between before and after the cross-linking falls in the range of 1.0.degree. to 10.degree. C. and the peak maximum temperature after the cross-linking falls in the range of 63.degree. to 74.degree. C., fibrating the cross-linked collagenous material to prepare an aqueous dispersion with the viscosity of 100 to 2000 cP and the spinnability of 30 to 80 mm at the concentration of 1% by weight of collagen fiber and subjecting the dispersion to electrodeposition.
摘要翻译：胶原蛋白成型体的厚度为5〜20μm，吸热变性的峰值最高温度为62〜71℃，湿拉伸强度为3〜6kg / mm2，其湿撕裂强度在25至150gxcm / cm的范围内通过包括交联胶原材料的方法制备，使得材料的吸热变性的峰值最高温度之间的差异在交联度在1.0〜10℃的范围内，交联后的峰值最高温度在63〜74℃的范围内，使交联胶原纤维成纤维化，制成水分散体粘度为100〜2000cP，纺丝性为30〜80mm，浓度为胶原纤维的1重量％，并对该分散体进行电沉积。

4. 发明授权

US4031000A Diaphragm for electrolytic production of caustic alkali 失效
标题翻译：用于电解生产苛性碱的隔膜
公开(公告)号：US4031000A
公开(公告)日：1977-06-21
申请号：US474820
申请日：1974-05-30
申请人： Tadashi Nakamura , Hisami Hagiwara , Yoshikazu Kokubu
发明人： Tadashi Nakamura , Hisami Hagiwara , Yoshikazu Kokubu
IPC分类号： C25B13/08 , C08J9/26 , C25B13/02 , C25B1/14
CPC分类号： C25B13/02
摘要： A diaphragm for electrolytic production of caustic alkali which consists of dual microporous layers provided on the anode and cathode sides, wherein the anode side microporous layer is made of an acid-resistant material 0.01 to 0.3 millimeter thick bored with micropores having a mean diameter of 0.05 to 1.5 microns, and the cathode side microporous layer is formed of an alkali-resistant material 1 to 6 millimeters thick bored with micropores having a diameter of 3 to 100 microns.
摘要翻译：用于电解生产苛性碱的隔膜，其由设置在阳极和阴极侧的双微孔层组成，其中阳极侧微孔层由0.01至0.3毫米厚的耐酸材料制成，孔径为平均直径为0.05的微孔至1.5微米，并且阴极侧微孔层由具有直径为3至100微米的微孔钻孔1至6毫米厚的耐碱材料形成。

5. 发明授权

US4211628A Electrolytic bath assembly 失效
标题翻译：电解槽组装
公开(公告)号：US4211628A
公开(公告)日：1980-07-08
申请号：US944356
申请日：1978-09-21
申请人： Kanichiro Obata , Yoshikazu Kokubu , Isao Okazaki
发明人： Kanichiro Obata , Yoshikazu Kokubu , Isao Okazaki
IPC分类号： C25B1/46 , C25B11/02 , C25B9/00 , C25B11/03
CPC分类号： C25B11/02 , C25B1/46
摘要： An electrolytic bath vessel assembly adapted for use to electrolytic treatment of salt water for the manufacture of caustic soda solution. The assembly includes a unique arrangement of bar electrodes, equidistantly positioned in parallel and at the both sides of a finely pored separating membrane.
摘要翻译：一种电解槽容器组件，适用于电解处理盐水以制造苛性钠溶液。该组件包括独立的条形电极排列，等距离地平行定位并且位于细孔分离膜的两侧。

6. 发明授权

US4310404A Electrolytic bath vessel elements 失效
标题翻译：电解槽容器元件
公开(公告)号：US4310404A
公开(公告)日：1982-01-12
申请号：US94689
申请日：1979-11-15
申请人： Hiroaki Satoh , Yoshikazu Kokubu , Kiyoshi Kitagawa , Isao Okazaki
发明人： Hiroaki Satoh , Yoshikazu Kokubu , Kiyoshi Kitagawa , Isao Okazaki
IPC分类号： C25B9/00 , C25B9/08 , C25B9/20 , C08K7/02 , C08K9/00 , H01M2/00
CPC分类号： C25B9/00
摘要： The invention resides in an electrolytic cell element representing a frame structure defining partially an anode chamber and a cathode chamber. The frame is composed of a carbon fiber-high polymer composite material.
摘要翻译：本发明涉及一种表示部分地限定阳极室和阴极室的框架结构的电解池元件。框架由碳纤维 - 高分子复合材料组成。

7. 发明授权

US3988235A Vertical diaphragm type electrolytic apparatus for caustic soda production 失效
标题翻译：用于苛性钠生产的垂直隔膜式电解设备
公开(公告)号：US3988235A
公开(公告)日：1976-10-26
申请号：US596447
申请日：1975-07-16
申请人： Hiroshi Shibata , Isao Okazaki , Yoshikazu Kokubu
发明人： Hiroshi Shibata , Isao Okazaki , Yoshikazu Kokubu
IPC分类号： C25B15/00 , C25B1/26 , C25B15/08
CPC分类号： C25B15/00
摘要： An improvement on the known brine-chlorine gas separting vessel disposed on the anode chambers of a vertical diaphragm type electrolytic cell for caustic soda production by connecting said brine-chlorine gas separating vessel to a secondary brine-chlorine gas separating vessel through a chlorine gas pipe and a brine pipe, and connecting the secondary brine-chlorine gas separating vessel to a tertially brine-chlorine gas separating vessel similarly through a chlorine gas pipe and a brine pipe.
摘要翻译：通过连接所述盐水 - 氯气分离容器与二次盐水 - 氯气分离容器，通过氯气管连接设置在用于苛性钠生产的垂直隔膜式电解池的阳极室上的已知盐水 - 氯气分离容器的改进和盐水管，并且通过氯气管道和盐水管道将次级盐水 - 氯气分离容器连接到第四盐水 - 氯气分离容器。

8. 发明授权

US3981788A Caustic alkali producing multiple vertical diaphragm type electrolytic cell admitting of easy assembly 失效
标题翻译：苛性碱生产多垂直隔膜式电解池容易组装
公开(公告)号：US3981788A
公开(公告)日：1976-09-21
申请号：US605381
申请日：1975-08-18
申请人： Yoshikazu Kokubu , Isao Okazaki , Haruo Shikano
发明人： Yoshikazu Kokubu , Isao Okazaki , Haruo Shikano
IPC分类号： G01D11/16 , C25B1/46 , C25B9/00 , C25B9/04 , C25B9/08 , G01D13/22 , G01D13/24 , C25B9/02 , C25B1/26
CPC分类号： C25B9/04
摘要： In a caustic alkali producing multiple vertical diaphragm type electrolytic cell, wherein a plurality of vertical flat box shaped unit anode chamber sets are assembled in parallel in a large cell case acting as a common cathode chamber, each said unit anode chamber set comprising an anode chamber, both main walls of which are formed of a pair of diaphragms and a pair of cathode wire nets stretched on the outside of said diaphragms, and a pair of anode plates received in said anode chamber so as to face said diaphragms, an improvement characterized in that, where the plural unit anode chamber sets are assembled in parallel in the cell case, the cathode wire nets can be electrically connected easily to the cathode bottom plate of said cell case by press-mounting the unit anode chamber sets thereon.
摘要翻译：在苛性碱生产多垂直隔膜型电解池中，其中多个垂直扁平箱形单元阳极室组平行组装在用作公共阴极室的大型电池壳体中，每个所述单元阳极室组包括阳极室其两个主壁由一对隔膜和一对在所述隔膜的外侧拉伸的阴极线网形成，一对阳极板容纳在所述阳极室中以面对所述隔膜，其特征在于：多个单元阳极室组在电池壳体中并联组装的情况下，通过在其上压装单元阳极室组件，阴极线网可以容易地电连接到电池壳体的阴极底板。

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