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1. 发明授权

US06512152B1 Tetracyclododecene compositions and process for producing the same 有权
标题翻译：四环十二碳烯组合物及其制备方法
公开(公告)号：US06512152B1
公开(公告)日：2003-01-28
申请号：US09486388
申请日：2000-02-28
申请人： Masaki Hashizume , Tomonobu Uchida , Fuyuki Aida , Takashi Suzuki , Yoshihisa Inomata , Yasuo Matsumura
发明人： Masaki Hashizume , Tomonobu Uchida , Fuyuki Aida , Takashi Suzuki , Yoshihisa Inomata , Yasuo Matsumura
IPC分类号： C07C13615
CPC分类号： C08G61/08
摘要： The present invention is drawn to a tetracyclododecene composition having a regulated cyclopentadiene trimer content, whereby addition polymerization with the aid of a Ziegler catalyst can be carried out while preventing gelation caused by a cross-linking reaction. A tetracyclododecene composition regulated with respect to the content of a specific ingredient having a molecular weight of 188 is disclosed, whereby polymers having high glass transition temperatures can be obtained through various polymerizations. Further, the present invention is drawn to a method for producing tetracyclododecene in the presence of an aliphatic solvent having a boiling point close to that of norbornene, which solvent is effective in inhibiting the recovered norbornene from solidifying. Preferred for obtaining high purity tetracyclododecene by removing the methyltetrahydroindene contained in dicyclopentadiene feedstock is a continuous process comprising a combination of reaction, distillation, and recovery/circulation, and so forth.
摘要翻译：本发明涉及具有调节环戊二烯三聚物含量的四环十二碳烯组合物，由此可以在防止由交联反应引起的凝胶化的情况下借助齐格勒催化剂进行加成聚合。公开了相对于分子量为188的特定成分的含量调节的四环十二碳烯组合物，由此可以通过各种聚合获得具有高玻璃化转变温度的聚合物。此外，本发明涉及在沸点接近降冰片烯的脂肪族溶剂的存在下制备四环十二碳烯的方法，该溶剂有效抑制回收的降冰片烯的固化。优选通过除去二环戊二烯原料中所含的甲基四氢茚来获得高纯度四环十二碳烯是包括反应，蒸馏和回收/循环的组合等的连续方法。

2. 发明授权

US5723708A Method for producing cyclopentadienes 失效
标题翻译：环戊二烯生产方法
公开(公告)号：US5723708A
公开(公告)日：1998-03-03
申请号：US534817
申请日：1995-09-27
申请人： Yasuo Matsumura , Kazuharu Suyama , Yoshihisa Inomata
发明人： Yasuo Matsumura , Kazuharu Suyama , Yoshihisa Inomata
IPC分类号： C07C1/24 , C07C1/20 , C07C1/207 , C07C13/15 , C07C13/28
CPC分类号： C07C1/24 , C07C2101/10 , C07C2102/22 , C07C2102/24 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2521/14 , C07C2521/16 , C07C2523/02 , C07C2529/06
摘要： A method for producing cyclopentadienes which comprises the step of cyclodehydration of an unsaturated carbonyl compound having a specific chemical structure in a vapor phase in the presence of a specific solid acid catalyst. The cyclopentadienes of the invention can be produced in a high yield from inexpensive starting materials through a simplified reaction process and are useful as intermediate compounds for organic synthesis.
摘要翻译：一种制备环戊二烯的方法，其包括在特定固体酸催化剂存在下，在气相中环化脱水具有特定化学结构的不饱和羰基化合物的步骤。本发明的环戊二烯可以通过简化的反应方法从廉价的原料以高产率生产，并且可用作有机合成的中间体化合物。

3. 发明授权

US4836966A Binder for ceramics 失效
标题翻译：陶瓷粘结剂
公开(公告)号：US4836966A
公开(公告)日：1989-06-06
申请号：US168863
申请日：1988-03-16
申请人： Isoo Shimuzu , Yasuo Matsumura , Yoshihisa Inomata
发明人： Isoo Shimuzu , Yasuo Matsumura , Yoshihisa Inomata
IPC分类号： C04B35/634
CPC分类号： C04B35/63408 , C04B35/634 , C04B35/63424 , C04B35/63432 , C04B35/63444
摘要： The present invention is directed to a water-soluble organic binder suitable for a ceramic molding method in which a ceramic slurry containing water as a dispersion medium is utilized and with this binder, a ceramic sheet can be prepared which has smooth surfaces, contains no flocculating material, and possesses excellent flexibility and mechanical strength.
摘要翻译：本发明涉及一种适用于陶瓷成型方法的水溶性有机粘合剂，其中使用含有水作为分散介质的陶瓷浆料，并且该粘合剂可以制备具有光滑表面的陶瓷片，不含絮凝材料，具有优异的柔韧性和机械强度。

4. 发明授权

US5081279A Production of .alpha.-(3-benzoylphenyl)propionic acid derivative 失效
标题翻译：（ALPHA） - （3-苯甲酰基苯基）丙酸衍生物的生产
公开(公告)号：US5081279A
公开(公告)日：1992-01-14
申请号：US602240
申请日：1990-11-06
申请人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
发明人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
IPC分类号： B01J31/16 , C07B61/00 , C07C45/50 , C07C45/65 , C07C49/782 , C07C49/796 , C07C49/86 , C07C51/14 , C07C59/84 , C07C67/38 , C07C69/738 , C07C69/76
CPC分类号： C07C59/84 , C07C45/50 , C07C45/65 , C07C51/14
摘要： This invention provides a method of producing highly pure .alpha.-(3-benzoylphenyl)propionic acid derivatives, which are medicines per sec or which can easily afford the same, from readily available 3-ethylbenzophenone in a very simplified manner efficiently and economically. The method comprises dehydrogenating 3-ethylbenzophenone in vapor phase in the presence of an inert gas and carbonylating the formed 3-ethenylbenzophenone in the presence of a carbonylation catalyst comprising a transition metal complex.
摘要翻译： PCT No.PCT / JP90 / 00288 Sec。 371日期：1990年11月6日 102（e）日期1990年11月6日PCT 1990年3月6日PCT PCT。第WO90 / 10614号公报日本1990年9月20日。本发明提供了一种制备高纯度α-（3-苯甲酰基苯基）丙酸衍生物的方法，其是每秒药物或可以容易地从容易获得的3-乙基二苯甲酮得到的，方式有效和经济。该方法包括在惰性气体存在下气相中脱氢3-乙基二苯甲酮，并在包含过渡金属络合物的羰基化催化剂存在下羰基化形成的3-乙烯基二苯甲酮。

5. 发明授权

US4885419A 1,2-Di(4-isobutylphenyl)hydrocarbon and its preparation and uses as intermediate 失效
标题翻译： 1,2-二（4-异丁基苯基）烃及其制备和用途为中间体
公开(公告)号：US4885419A
公开(公告)日：1989-12-05
申请号：US190506
申请日：1988-05-05
申请人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
发明人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
IPC分类号： C07C2/86 , C07C4/00 , C07C5/03 , C07C6/04 , C07C15/18 , C07C15/52 , C07C25/18 , C07C51/14 , C07C57/30
CPC分类号： C07C57/30 , C07C15/18 , C07C15/52 , C07C2/861 , C07C25/18 , C07C4/00 , C07C5/03 , C07C51/14 , C07C6/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2527/173 , C07C2529/04 , C07C2531/025
摘要： Novel compounds of 1,2-di(isobutylphenyl)ethane and 1,2-di(isobutylphenyl)ethylene, method for producing the same and method for preparing 4-isobutylstyrene and .alpha.-(4-isobutylphenyl)propionic acid from any of these compounds. In the preparation of 4-isobutylstyrene from the former two compounds by cracking or disproportionation, the components in the resultant reaction mixture can be separated without difficulty, the formation of by-product isobutylbenzene can be avoided, and the remaining unreacted starting material can be reused for the same reaction without causing any adverse effect on a catalyst.

6. 发明授权

US4709089A Method for refining 2-(aryl substituted) propionic acid or its salt 失效
标题翻译：精制2-（芳基取代）丙酸或其盐的方法
公开(公告)号：US4709089A
公开(公告)日：1987-11-24
申请号：US011734
申请日：1987-02-06
申请人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
发明人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
IPC分类号： C07C51/487 , C07C51/42
CPC分类号： C07C51/487
摘要： An effective method for refining 2-(aryl substituted)propionic acid or its salt which is characterized in that 2-(aryl substituted)propionic acid or its salt containing halogenated by-products is brought into contact with hydrogen in a liquid phase containing water under a basic condition at temperatures in the range of 20.degree. C. to 170.degree. C. in the presence of a catalyst of transition metal of the group VIII in the periodic table, thereby dehalogenating said halogenated by-product and producing highly pure 2-(aryl substituted)propionic acid or its salt.

7. 发明授权

US4659840A Method for preparing diaryl iodonium salts 失效
标题翻译：二芳基碘鎓盐的制备方法
公开(公告)号：US4659840A
公开(公告)日：1987-04-21
申请号：US587556
申请日：1984-03-08
申请人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
发明人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
IPC分类号： C07C43/225 , C07B39/00 , C07C17/00 , C07C17/12 , C07C25/18 , C07C41/00 , C07C41/22 , C07C41/30 , C07C67/00 , C07C231/00 , C07C231/12 , C07C233/15 , C07D207/40 , C07D207/404 , C07C25/00
CPC分类号： C07D207/404 , C07C25/18 , C07C41/30
摘要： Provided is a method for preparing diaryl iodonium salts represented by the formula:[Ar.sub.1 --I.sup..sym. --Ar.sub.2 ]HSO.sub.4.sup..crclbar.wherein Ar.sub.1 and Ar.sub.2 respectively are an aryl group which may be substituted with an electron donor group and which may be the same or different which comprises subjecting a compound represented by the formula Ar.sub.1 --H wherein Ar.sub.1 is as defined above and a compound Ar.sub.2 --I wherein Ar.sub.2 is as defined above to a coupling reaction in a sulfuric acid solution containing an oxidizing agent and diluted with a diluting agent to a concentration of 85% by weight or less at a reaction temperature in the range from -20.degree. to +35.degree. C.
摘要翻译：本发明提供一种由式[Ar1-I（+）-Ar2] HSO4（ - ）表示的二芳基碘鎓盐的制备方法，其中Ar1和Ar2分别为可被电子给体基团取代的芳基，其相同或不同，其包括使式Ar1-H表示的化合物，其中Ar1如上定义，和Ar2如上定义的化合物Ar2-I在含有氧化剂的硫酸溶液中进行偶联反应，并用在-20℃〜+ 35℃的反应温度下，稀释剂浓度为85重量％以下。

8. 发明授权

US4814494A Method for producing (aryl substituted) carboxylic acid or its salt 失效
标题翻译：（芳基取代）羧酸或其盐的制备方法
公开(公告)号：US4814494A
公开(公告)日：1989-03-21
申请号：US11735
申请日：1987-02-06
申请人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
发明人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
IPC分类号： C07B61/00 , B01J23/00 , B01J23/40 , C07C51/00 , C07C51/29 , C07C51/487 , C07C57/30 , C07C59/64 , C07C59/84 , C07C67/00
CPC分类号： C07C51/29 , C07C51/487
摘要： An effective method for producing highly pure (aryl substituted)carboxylic acid or its salt which comprises the steps of:(I) oxidizing (aryl substituted)aldehyde in an acidic phase in the presence of hypohalogenite; and(II) bringing the oxidized product obtained in the preceding step into contact in a liquid phase with hydrogen in the presence of a catalyst of transistion metal of the group VIII in the periodic table.
摘要翻译：一种生产高纯度（芳基取代）羧酸或其盐的有效方法，包括以下步骤：（I）在次卤酸盐存在下，在酸性相中氧化（芳基取代的）醛; 和（II）在上述步骤中得到的氧化产物在周期表中第VIII族的转移金属的催化剂存在下，与氢气接触。

9. 发明授权

US5026939A Method for producing 4-isobutylstyrene 失效
标题翻译： 4-异丁基苯乙烯的制备方法
公开(公告)号：US5026939A
公开(公告)日：1991-06-25
申请号：US190508
申请日：1988-05-05
申请人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
发明人： Isoo Shimizu , Yasuo Matsumura , Yoshihisa Inomata
IPC分类号： C07C2/86 , C07C4/00 , C07C5/03 , C07C6/04 , C07C15/18 , C07C15/52 , C07C25/18 , C07C57/30
CPC分类号： C07C57/30 , C07C15/18 , C07C15/52 , C07C2/861 , C07C25/18 , C07C4/00 , C07C5/03 , C07C6/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2527/173 , C07C2529/04 , C07C2531/025
摘要： A method for producing alkylstyrene which is characterized in that 1,2-di(substituted phenyl)ethane is brought into contact with an acid catalyst at 200.degree. C. to 650.degree. C. in the presence of an inert gas to crack it into alkylstyrene and alkylbenzene. The method of the invention has advantages in that the operation of reaction and separation of reaction mixture are quite easy, the lowering of catalytic activity is small, and unreacted starting material can be reused.

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